• Title/Summary/Keyword: Residual water

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Establishment of the Analytical Method for Residual Pharmaceuticals in Raw Water Using Online Sample Preparation and High Resolution Orbitrap LC/ESI-MS (온라인 자동화 시료 전처리 및 HR Orbitrap LC/ESI-MS를 이용한 환경시료 중 잔류 의약물질 분석방법 확립)

  • Hwang, Yoonjung;Sin, Sanghee;Park, Jongsuk
    • Journal of Korean Society on Water Environment
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    • v.29 no.3
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    • pp.409-419
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    • 2013
  • In this study, the analytical method for 27 residual pharmaceuticals in raw water was developed. Online sample preconcentration/extraction and analysis with high resolution Orbitrap mass spectrometry (LC-ESI/Orbitrap MS) were performed. The calibration curves showed good linearities (above $r^2$ = 0.998) in the range of 5 ~ 1,000 ng/L. The method detection limit and the limit of quantification were 1.1 ~ 10.0 ng/L and 3.4 ~ 31.7 ng/L, respectively. Recoveries of the target compounds were between 70.1% and 115.8% (except cefadroxil, cefradine, vancomycin, and iopromide (50.2 ~ 67.0%)). The optimized analytical method can be useful to determine the residual pharmaceuticals in raw water.

A study for application plan of rational residual water pressure on the tunnel linings (터널 라이닝에 작용하는 합리적인 잔류수압 적용방안 검토)

  • Jung, Kuk-Young;Kim, Ji-Yeop;Kim, Ji-Hun;Moon, Hoon-Ki
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.6
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    • pp.463-499
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    • 2011
  • Control of ground water is one of the most important factors for long-term operation of tunnel because most tunnels are located under the ground water level. In case of a drainage tunnel, there is no pore water pressure on the lining when the drainage system is properly working. After long-term operation, however, residual pore water pressure can be developed on the lining due to the deterioration of the drainage system. In this study, the water pressure distribution under obstruction condition of drainage material and conduit on the tunnel is numerically investigated using the ICFEP program and compared with the current value being applied to the residual water pressure for rational application plan of residual water pressure on the tunnel linings.

A Study on the Stress Distribution of Steel Water Pipes(I) - Characteristics of Residual Stress Distribution by PWHT - (상수도용 도복장강관의 용접 및 외부하중에 의한 응력 특성에 관한 연구(I) - 후열처리에 의한 용접부의 잔류응력 특성 -)

  • 윤석환;이승기;나석주;고명환
    • Journal of Welding and Joining
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    • v.19 no.3
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    • pp.285-291
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    • 2001
  • Large steel water pipes are joined prevalently by the bell end method, and are welded both at inside and outside of lapped parts. In practice, welded joints of water pipes are very critical, because in most cases failure of pipes causing leakage occurs at the welded joint. Therefore some methods have been developed to ensure the soundness of welded joints of water pipes, like leakage tests and nondestructive tests (NDTs). But one of the major characteristics that affects the soundness of welded Joints is the stress distribution caused by welding and external forces. Some studies have been carried out on the residual stress of steel water popes, but complex stress distributions by welding and external forces are rarely studied. In this study, temperature and stress distributions in steel water pipes produced by welding are predicted by a three-dimensional finite element method(FEM). Also, stress values are measured from real steel water pipes by the hole-drilling methods, and compared with predicted ones. The influence of some typical post weld treatments on residual stress distribution was also investigated by residual stress measurements.

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Masking Effect of Chlorine on Algae-related Taste and Odor in Drinking Water Supplies (염소의 상수원 내 조류 이취미 Masking 효과)

  • Kim, Young-il;Lee, Yu-Jeong;Shin, Heung-Sup;Bae, Byung-Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.227-232
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    • 2008
  • The masking effect of chlorine on algae-related taste and odor(T&O) compounds has long been an important issue for water suppliers. In this study, masking experiments with chlorine were performed on two kinds of treated water and one of raw water. After adding chlorine(0 to 0.8 mg/L) to water samples, odor intensity was evaluated by a newly developed sensory method(2-out-of-5 odor test) for three days along with the measurement of residual chlorine concentration. Even though the relationship between the residual chlorine concentration and odor reported by the sensory analysts was not always coincident, it was proved that residual chlorine more than a certain concentration could completely mask both added geosmin and naturally occurring T&O compounds. For the sand-filtered water spiked with 10 ng/L of geosmin, 0.12-0.18 mg/L of residual chlorine was necessary to achieve complete masking. In the case of GAC-filtered water, 10 ng/L of spiked geosmin was completely masked by 0.15-0.1 mg/L of residual chlorine. Combined ozone and GAC was not enough to treat raw water spiked with 300 ng/L of geosmin. In this experiment, sensory analysts were able to detect earthy or musty odors from the treated water. From a masking experiment with raw water taken from the Daechung Reservoir, it was found that fishy odor was more difficult to mask with chlorine than earthy odor. As the chlorine residual declined, the analysts began to notice the original odor and the fishy odor was noticed earlier than the earthy odor.

A Study on the Factors to Minimize the Residual Aluminum in Filtered Water (정수처리시 잔류알루미늄 농도를 최소화하기 위한 영향인자 고찰)

  • 고영송;우달식;남상호
    • Journal of Environmental Health Sciences
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    • v.19 no.2
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    • pp.1-9
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    • 1993
  • In public water supply systems, Alum and/or PAC being used as a coagulant. It is well known that their use increased frequently the concentration of residual aluminum in filtered water upon operating conditions. This study was conducted to find the optimum conditions that both the concentration of residual aluminum and turbidity are minimized by changing such factors as pH, temperature, alum dosage, mixing rate, alkalinity and hardness. The results can be summarized as follows: The pH values for the minimum concentration of residual aluminum and turbidity as a given experimental condition were found at pH 6 and pH 7 respectively, the apparent clarity was best at pH 8. The floc settling rate was the greatest at pH 6.5, but the turbidity was high at the same condition. The more alum dosage, the higher the concentration of residual aluminum. However the alum dosage less than 15 mg/l tend to decrease in turbidity. Restabilization and enmeshment occurred near 15 mg/l and 20 mg/l of alum dose respectively. With the increase of mixing rate (rapid and slow), the concentration of residual aluminum and turbidity are increased and the same trend was found in increment of mixing time. At low water temperature, the concentration of residual aluminum was decreased, but turbidity was increased. It was confirmed that alkalinity had an effect on the coagulation efficiency, but hardness did not.

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A Study about Applicability of Treatment for Water Treatment Residual Sludge Using Crossflow Tubular Membrane System (정수장 배출수 처리를 위한 Crossflow 관형막 여과 공정의 운전 적용에 관한 연구)

  • Kim, Young Hoon;Kim, Kwan Yeop;Kim, Ji Hoon;Lee, Yong Soo;Lee, Eui Jong;Eom, Jung Yeol;Kim, Hyung Soo;Hwang, Sun Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.4
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    • pp.499-505
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    • 2009
  • Many other countries have investigated the residual sludge treatment process to save the existing water resource and produce the high suspended solid concentration sludge. There are various methods for concentrating residual sludge, but the membrane system has received the most interest for its efficiency. The objective of this study was to evaluate the application of membrane filtration system for the residual sludge treatment. The experiment equipment was composed of Lab scale Crossflow tubular membrane filtration system. Generally, crossflow operation mode demands high electric cost mainly for the pump energy. So to cut off electric cost, very low Crossflow velocity was used in this experiment. Results confirmed that suspended solid concentration of residual sludge could be concentrated to 57,000mg/L in low Crossflow velocity tubular membrane system,. This concentration can be directly injected into the dehydrator. Based on the results, we know that the Crossflow tubular membrane system should be replaced conventional residual sludge treatment system.

Simulation for Chlorine Residuals and Effect of Rechlorination in Drinking Water Distribution Systems of Suwon City (수원시 상수관망에서 잔류염소와 재염소주입의 효과 예측)

  • Kim, Kyung-Rok;Lee, Byong-Hi;Yoo, Ho Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.108-116
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    • 2000
  • Chlorine is widely used as a disinfectant in drinking-water systems throughout the world. Chlorine residual was used as an indicator for prediction of water quality in water distribution systems. The variation of chlorine residual in drinking water distribution systems of Suwon city was simulated using EPANET. EPANET is a computerized simulation model which predicts the dynamic hydraulic and water quality behavior within a water distribution system operating over an extended time period. Sampling and analysis were performed to calibrated the computer model in 1999 (Aug. Summer). Water quality variables used in simulations are temperature, roughness coefficient, pipe diameter, pipe length, water demand, velocity and so on. Extended water residence time affected water quality due to the extended reaction time in some areas. All area showed the higher concentration of chlorine residual than 0.2mg/l(standard). So it can be concluded that any area in Suwon city is not in biological regrowth problem. Rechlorination turned out to be an useful method for uniform concentration of free chlorine residual in distribution system. The cost of disinfectant could be saved remarkably by cutting down the initial chlorine concentration to the level which guarantees minimum concentration (0.2mg/l) throughout the distribution system.

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Reaction coefficient assessment and rechlorination optimization for chlorine residual equalization in water distribution networks (상수도 잔류염소농도 균등화를 위한 반응계수 추정 및 염소 재투입 최적화)

  • Jeong, Gimoon;Kang, Doosun;Hwang, Taemun
    • Journal of Korea Water Resources Association
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    • v.55 no.spc1
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    • pp.1197-1210
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    • 2022
  • Recently, users' complaints on drinking water quality are increasing according to emerging interest in the drinking water service issues such as pipe aging and various water quality accidents. In the case of drinking water quality complaints, not only the water pollution but also the inconvenience on the chlorine residual for disinfection are included, thus various efforts, such as rechlorination treatment, are being attempted in order to keep the chlorine concentration supplied evenly. In this research, for a more accurate water quality simulation of water distribution network, the water quality reaction coefficients were estimated, and an optimization method of chlorination/ rechlorination scheduling was proposed consideirng satisfaction of water quality standards and chlorine residual equalization. The proposed method was applied to a large-scale real water network, and various chlorination schemes were comparatively analyzed through the grid search algorithm and optimized based on the suitability and uniformity of supplied chlorine residual concentration.

A Review Study on Major Factors Influencing Chlorine Disappearances in Water Storage Tanks (저수조 내 잔류염소 감소에 미치는 주요 영향 인자에 관한 문헌연구)

  • Noh, Yoorae;Kim, Sang-Hyo;Choi, Sung-Uk;Park, Joonhong
    • Journal of Korean Society of Disaster and Security
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    • v.9 no.2
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    • pp.63-75
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    • 2016
  • For safe water supply, residual chlorine has to be maintained in tap-water above a certain level from drinking water treatment plants to the final tap-water end-point. However, according to the current literature, approximately 30-60% of residual chlorine is being lost during the whole water supply pathways. The losses of residual chlorine may have been attributed to the current tendency for water supply managers to reduce chlorine dosage in drinking water treatment plants, aqueous phase decomposition of residual chlorine in supply pipes, accelerated chlorine decomposition at a high temperature during summer, leakage or losses of residual chlorine from old water supply pipes, and disappearances of residual chlorine in water storage tanks. Because of these, it is difficult to rule out the possibility that residual chlorine concentrations become lower than a regulatory level. In addition, it is concerned that the regulatory satisfaction of residual chlorine in water storage tanks can not always be guaranteed by using the current design method in which only storage capacity and/or hydraulic retention time are simply used as design factors, without considering other physico-chemical processes involved in chlorine disappearances in water storage tank. To circumvent the limitations of the current design method, mathematical models for aqueous chlorine decomposition, sorption of chlorine into wall surface, and mass-transfer into air-phase via evaporation were selected from literature, and residual chlorine reduction behavior in water storage tanks was numerically simulated. The model simulation revealed that the major factors influencing residual chlorine disappearances in water storage tanks are the water quality (organic pollutant concentration) of tap-water entering into a storage tank, the hydraulic dispersion developed by inflow of tap-water into a water storage tank, and sorption capacity onto the wall of a water storage tank. The findings from his work provide useful information in developing novel design and technology for minimizing residual chlorine disappearances in water storage tanks.

Study on the Chlorine-Resistant Bacteria Isolated from Water Pipe Network (상수도관망에서 분리한 잔류염소 내성균에 관한 연구)

  • Hyun, Jae-Yeoul;Yoon, Jong-Ho
    • Journal of Korean Society on Water Environment
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    • v.27 no.3
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    • pp.334-341
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    • 2011
  • The free residual chlorine of tap water samples, collected from 266 faucets on the water pipe network in Daegu City, was between 0.1 and 0.79 mg/L. On microorganic tests, general bacteria and the coliform goup were not detected and thus the tap water was turned out to be fit to drink. In particular, samples of which free residual chlorine was 0.1 mg/L and over were cultured in R2A agar media at $25^{\circ}C$ for 7 days, and as a result heterotrophic bacteria were detected in 65.9% of samples; (1). The closer tap water got to the faucet from the stilling basin, the lower residual chlorine concentration became but the more the bacterial count became. And, more bacteria were detected in the R2A agar medium than in the PCA medium. (2). In the case of separated strains, most colonies were reddish or yellowish. 16S rRNA sequence was identified as Methylobacterium sp. and Williamsia sp., and yellow strain was identified as Sphingomonas sp., Sphingobium sp., Novosphingobium sp., Blastomonas sp., Rhodococcus sp. and Microbacterium sp. White strain was identified as Staphylococcus sp. (3). Sterilized tap water in polyethylene bottles was inoculated with separated strain and was left as it was for 2 months. As a result, bio-film was observed in tap water inoculated with Methylobacterium sp. and Sphingomonas sp. It was found that heterotrophic bacteria increased when free residual chlorine was removed from tap water in the water pipe network. Thus, there is a need to determine a base value for heterotrophic bacteria in order to check the cleanliness of tap water in the water pipe network.