• Title/Summary/Keyword: Residual amount

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Study on the chemical forms of heavy metals in the surface sediments of Ulsan Bay

  • Young Bok Kim;Sun
    • Journal of Environmental Science International
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    • v.2 no.1
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    • pp.69-78
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    • 1993
  • Contents of heavy metals (Cr, Cu, Zn, Cd, and Pb) in the sediments of Ulsan Bay were investigated by the sequential extraction methods that classifies heavy metals into five types of chemical forms: exchangeable, bound to carbonates, bound to Fe-Mn oxides, bound to organic matter and residual. The analyses were determined by using an ICP-MS. Total Cr concentrations in the sediments were in the range of 41.6-96.4, Cu 60.7-680, Zn 189-1954, Cd 33.1-83.4, and Pb 138-567 mg/kg. Results of sequential fractionation indicates that relatively high proportion ( ~44%) of Cu is associated with organic matter. A large proportion of Pb is associated with three types of chemical forms: Fe-Mn oxides, organic matter, and residual. There were significant correlation in concentrations between the exchangeable components and total organic carbons. The heavy metals In the residual phase cannot be easily released to the environment since these are bound to the crystal lattice. But, reducible and organic Phases con a significant amount of most heavy metals. Therefore, there is Potential dancer of a substantial amount of metals becoming chemically mobile with environmental changes.

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Process Design, Fabrication, and Evaluation of Cold Drawn SUS304N Coil Wedge (SUS304N 코일 웨지 인발 공정의 설계, 제조 및 평가)

  • Jung, J.E.;Kim, S.J.;Bae, S.;Namkung, J.;Kim, S.M.;Kim, S.I.;Lee, K.S.
    • Transactions of Materials Processing
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    • v.28 no.4
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    • pp.212-218
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    • 2019
  • In this study, the first drawing die for the production of coil wedge is redesigned in order to enhance properties such as dimensional accuracy, dimensional uniformity, non-magnetism, and residual stress. The equivalent strain distribution is observed to be asymmetric at certain corners of the product and un-filling of material is also observed at the same location, based on the results of FEM simulation for the current drawing process. Additionally, a relatively huge amount of deformation is concentrated on the surface of the reference product leading to an increase in magnetic component and surface residual stress. After re-designing the cross-section of the first drawing step process conformed to relatively higher amount of reduction ratio, reduction of both surface residual stress and the volume fraction of magnetic component could be achieved for the finally-drawn coil wedge product.

Characterization of Residual Lignins from Chemical Pulps of Spruce (Picea abies) and Beech (Fagus sylvatica) by KMnO4 Oxidation

  • Choi, J.-W.;Faix, O.
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.6
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    • pp.31-39
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    • 2003
  • The enzymatic isolation of residual lignins obtained from spruce and beech pulps (obtained by sulfite, kraft, ASAM and soda/AQ/MeOH pulping processes) and their characterization was described in previous publications. Here, the residual lignins have been submitted to potassium permanganate oxidation (KMnO4 degradation), and 9 aromatic carboxylic acids (3 of them are dimeric) were identified after methylation with diazomethane by GC/MS. The analytical challenge during qantification by the internal standard methods was the partly high protein content of the samples, which resulted in elevated anisic acid yields in the degradation mixture of sulfite residual lignins. The results are compared with the KMnO4 degradation of the corresponding MWLs and discussed in terms of S/G ratios and degrees of condensation. The latter was calculated as a quotient between the aromatic carboxylic acids derived from condensed and non-condensed lignin structures. Typical degradation patterns for the various processes have been observed. Among other parameter, the relative compositions between iso-hemipinic acid (which is for condensation in pos. 5 of the aromatic ring) and meta-hemipinic acid and 3,4,5-trimethoxyphthalic acid (both are for condensation in pos. 6 of the aromatic ring) was found to be process specific. Kraft and soda/AQ/MeOH residual lignins yielded higher amounts of iso-hemipinic acid. In contrast, the relative yields of meta-hemipinic acid and 3,4,5-trimethoxyphthalic acid (the latter in beech lignins) are higher in sulfite and particularly in ASAM residual lignin. In case of beech residual lignins the amount of acids originated from non-condensed syringyl type lignin units was surprisingly high. The condensation degree of residual lignins was shown to be generally higher than that of MWLs. This was especially true for the G units. ASAM residual lignin exhibited very high S/G ratios and degrees of polymerization. Causality between condensation degree and total yield of degradation products was demonstrated.

Property changes of GDLs and water behaviors in PEFCs (고분자전해질 연료전지 체결조건에서 기체확산층의 특성변화 및 물거동 확인)

  • Park, Gu-Gon;Lim, Nam-Yun;Ahn, Eun-Jin;Park, Jin-Soo;Yoon, Young-Gi;Lee, Won-Yong;Lim, Tae-Won;Kim, Chan-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.313-315
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    • 2006
  • Proper water management is important to achieve high performance and durability of Polymer electrolyte fuel cell (PEFC). Among various stack components, gas diffusion layer (GDL) is considered as a core part to determine the gas and water transportation in a cell. To optimize the water management, the changes of properties as well as basic properties of GDLs were investigated before and after clamping of colls. Thickness, electric conductivity, porosity, hydroppobicity etc. were characterized by the same criteria. The amount of residual water after cell operation also was compared by direct measuring of weight. Based on the amount of residual water the endurance on the freeze condition was evaluated.

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A Study on Expansion of Back Fire Limit Equivalence Ratio of the Hydrogen Fueled Engine (수소기관의 역화한계당량비 확장에 관한 연구)

  • Paik, Sung Ho;Park, Jae Bum;Kim, Yun Young;Lee, Jong Tae
    • Journal of Hydrogen and New Energy
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    • v.8 no.3
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    • pp.111-119
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    • 1997
  • In this study, feasibility of expansion of BFL equivalence ratio are examined with change of injection location of hydrogen gas in intake pipe, coolant temperature, spark timing and amount of residual gas. As the results, BFL equivalence ratio is increased when injection location has some distance from intake valve. And it is decreased in accordance with increasing of coolant temperature and advance of spark timing. The amount of residual gas has little effect on BFL equivalence ratio.

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A Study on the Grinding Characteristics According to Cooling Methods (대체냉각 기술을 이용한 환경친화 연삭가공 기술)

  • Lee, S.W.;Choi, H.Z.;Heo, N.H.;Lee, J.H.
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.962-967
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    • 2003
  • Recently, environmental pollution has become a serious problem in industry, and many researches have been done in order to preserve the environment. The coolant, which promotes lubrication, cooling and penetration, contains chlorine, sulfur and phosphorus to improve the machining efficiency. These additives, which move around into the air during machining, pollute working. Therefore, many researches on how to reduce the amount of coolant during machining have been carried out. However, to reduce even small amount of coolant causes high temperature of a workpiece and it brings thermal defects. In this study, the experiments of wet & dry grinding using cooling methods (using coolant only, mist and compressed cold air only) are performed to solve the problem of environmental contamination and to get a better surface integrity of a workpiece by comparing surface roughness, roundness and residual stress.

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Fabrication of in-situ Formed Namo-Composite Using Polymer Precursor : I. Adsorption Behavior of Polymer Followed $SiO_2$ Surface formation onto Silicon Nitride Surface (폴리머 Precursor를 이용한 in-situ 나노 복합체의 제조 : I. 질화규소 표면에서의 $SiO_2$ 피막형성에 따른 폴리머의 흡착거동)

  • 정연길;백운규
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.280-287
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    • 2000
  • Adsorption behavior and amount of phenolic resin followed silica (SiO2) formation onto silicon nitride(Si3N4) surface were investigated using electrokinetic sonic amplitude (ESA) technique and with UV spectrometer, to fabricate Si3N4/SiC nano-composite based on reaction between SiO2 formed and phenolic resin absorbed onto Si3N4 particle. The amount of SiO2 formed and carbon from phenolic resin absorbed onto Si3N4 surface were calculated quantitatively to adjust the reaction between SiO2 and phenolic resin, resulting in no residual SiO2 and carbon. As a result, pre-heated tempeature for optimized reaction was below 25$0^{\circ}C$, in which there was no residual SiO2 and carbon.

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Electro-optic Characteristic of Twisted Nematic Mode using a Liquid Crystal Dispersed Carbon Nanotubes (탄소 나노 튜브가 분산된 액정을 이용한 TN 모드의 전기 광학 특성 연구)

  • Baik, In-Su;Jeon, Sang-Youn;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.114-117
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    • 2005
  • We have fabricated twisted nematic (TN) cell doped by carbon nanotubes (CNTs). The CNTs with a minute amount of doping do not perturb the liquid crystal orientation in the off- and on-state. The hysteresis studies of voltage-dependent transmittance and capacitance under ac and dc electric field show that the amount of residual dc, which is related to image sticking problem in liquid crystal displays, is greatly reduced due to ion trapping by CNTs.

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Adaptive Data Aggregation and Compression Scheme for Wireless Sensor Networks with Energy-Harvesting Nodes

  • Jeong, Semi;Kim, Hyeok;Noh, Dong Kun;Yoon, Ikjune
    • Journal of the Korea Society of Computer and Information
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    • v.22 no.3
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    • pp.115-122
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    • 2017
  • In this paper, we propose an adaptive data aggregation and compression scheme for wireless sensor networks with energy-harvesting nodes, which increases the amount of data arrived at the sink node by efficient use of the harvested energy. In energy-harvesting wireless sensor networks, sensor nodes can have more than necessary energy because they harvest energy from environments continuously. In the proposed scheme, when a node judges that there is surplus energy by estimating its residual energy, the node compresses and transmits the aggregated data so far. Conversely, if the residual energy is estimated to be depleted, the node turns off its transceiver and collects only its own sensory data to reduce its energy consumption. As a result, this scheme increases the amount of data collected at the sink node by preventing the blackout of relay nodes and facilitating data transmission. Through simulation, we show that the proposed scheme suppresses the occurrence of blackout nodes and collect the largest amount of data at the sink node compared to previous schemes.

A study on method for reducing haze defects of head lamp for automobiles (자동차용 헤드램프의 플라스틱 소재 Haze 저감 방법에 관한 연구)

  • Lee, Seung-Wook;Lee, Chun-Kyu
    • Design & Manufacturing
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    • v.15 no.4
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    • pp.32-36
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    • 2021
  • In this study, the cause of the decrease in transmittance of the outer lens among the causes of the decrease in the amount of light in the automobile headlamp was identified, and the improvement method was selected to determine the effect. The causes of defects that lower the transmittance of the outer lens are divided into a moisture problem and a haze problem. The moisture problem is caused by the temperature difference between the inside and the outside of the head lamp, and the haze problem occurs when the heat inside the head lamp evaporates the haze component contained in the plastic material and attaches it to the outer lens. In order to improve the haze problem that occurs in plastic raw materials, the structures of the bulb light source type headlamp and the LED chip light source type headlamp were analyzed. Among them, the housing material of the LED chip light source type headlamp, which is structurally prone to haze gas, was selected as the test target. In the mass-production injection process of the housing, the drying process was selected as a method to minimize haze gas without adding a separate production process. After extracting a sample every drying time at a constant drying temperature, the sample was put into a haze tester and the residual amount of haze gas was measured. As a result, it was confirmed that the residual amount of Haze gas in the material decreased as the drying time increased.