• 제목/요약/키워드: Residual Safety Assessment

검색결과 117건 처리시간 0.03초

소화약제 잔류물질에 대한 공기 중 노출평가 사례 (Example of Air Exposure Assessment for Fire Extinguishing Agent Residues)

  • 임대성
    • 한국산업보건학회지
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    • 제34권1호
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    • pp.14-17
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    • 2024
  • Objectives: This is a case of air exposure assessment conducted after researchers complained of headaches and odor due to residual substances from fire extinguishing agents spread throughout the laboratory due to a malfunction of the fire extinguishing facility. Methods: A component analysis was conducted on the residual substances of a fire extinguishing agent spread in a laboratory using Py-GC-MS (pyrolysis gas chromatography mass spectrometry) at the research institute's own central equipment research center. As a result of the component analysis, several types of substances were detected. Among these, five types of substances subject to work environment measurement in the aromatic hydrocarbon series, which can affect headaches and odor, were selected as substances subject to exposure assessment in the air, and the measurement and analysis methods of the target substances were conducted in accordance with the KOSHA Guide for each substance. Conclusions: The measurement results showed that all 5 types of substances were not detected at locations A, B, and C. This is believed to be the result of the residual substances in the fire extinguishing agent being measured when approximately two months had elapsed after being exposed to the test bench, and the substances already exposed had volatilized and disappeared. In this survey, it is believed that the measurement process is more important than the measurement results.

Effects of Surface Machining by a Lathe on Microstructure of Near Surface Layer and Corrosion Behavior of SA182 Grade 304 Stainless Steel in Simulated Primary Water

  • Zhang, Zhiming;Wang, Jianqiu;Han, En-hou;Ke, Wei
    • Corrosion Science and Technology
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    • 제18권1호
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    • pp.1-7
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    • 2019
  • To find proper lathe machining parameters for SA182 Grade 304 stainless steel (SS), six kinds of samples with different machining surface states were prepared using a lathe. Surface morphologies and microstructures of near surface deformed layers on different samples were analysed. Surface morphologies and chemical composition of oxide films formed on different samples in simulated primary water with $100{\mu}g/L\;O_2$ at $310^{\circ}C$ were characterized. Results showed that surface roughness was mainly affected by lathe feed. Surface machining caused grain refinement at the top layer. A severely deformed layer with different thicknesses formed on all samples. In addition to high defect density caused by surface deformation, phase transformation, residual stress, and strain also affected the oxidation behaviour of SA182 Grade 304 SS in the test solution. Machining parameters used for # 4 (feed, 0.15 mm/r; back engagement, 2 mm; cutting speed, 114.86 m/min) and # 6 (feed,0.20 mm/r; back engagement, 1 mm; cutting speed, 73.01 m/min) samples were found to be proper for lathe machining of SA182 Grade 304 SS.

시설재배 부추(Allium tuberosum R.)와 쪽파(Allium wakegi Araki) 중 α-Cypermethrin과 Deltamethrin의 잔류특성 및 안전성 평가 (Study on Residual Properties and Risk Assessment of α-Cypermethrin and Deltamethrin in the Chives (Allium tuberosum R.) and Spring onion (Allium wakegi Araki))

  • 조영주;최정윤;함헌주;허장현
    • 한국환경농학회지
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    • 제41권1호
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    • pp.55-64
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    • 2022
  • BACKGROUND: This study was conducted to evaluate the residual characteristics and safety assessment of αcypermethrin and deltamethrin in minor crops, chives and spring onion cultivated in greenhouse. METHODS AND RESULTS: The insecticides α-cypermethrin 2% EC and deltamethrin 1% EC used in the experiment were diluted 1,000 times and then sprayed on chives and spring onion twice with 1-week intervals at 0, 7, 14, and 21 days before harvest. The residual insecticides were extracted from the minor crops using QuEchERS method and analyzed by GC-MS/MS. The average initial residues of α-cypermethrin and deltamethrin in chives after 21 days decreased from 2.74 to 0.82 mg/kg and 1.12 to 0.16 mg/kg, respectively. Similarly, in spring onion the residues after the same periods decreased from 0.26 to <0.01 mg/kg for α-cypermethrin and from 0.07 to <0.01 mg/kg for deltamethrin. CONCLUSION(S): The PHIs (pre-harvest intervals) for α-cypermethrin and deltamethrin in chives are recommended as 14 days before harvest with twice applications of the pesticides, whereas for α-cypermethrin in spring onion PHI of 7 days before harvest is recommended with 3 times of applications and PHI of 21 days for deltamethrin. The theoretical maximum daily intakes of cypermethrin and deltamethrin were 68.8% and 64.2%, respectively, indicating that residues of both compounds did not pose considerable health risks to consumers.

국내 유통 농산물의 잔류농약 모니터링 및 위해평가-2013년 (Monitoring and Risk Assessment of Pesticide Residues for Circulated Agricultural Commodities in Korea-2013)

  • 김재영;이상목;이한진;장문익;강남숙;김남선;김희정;조윤제;정지윤;김미경;이규식
    • Journal of Applied Biological Chemistry
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    • 제57권3호
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    • pp.235-242
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    • 2014
  • 본 연구는 국내 유통 농산물의 잔류농약 실태를 조사파악하고, 위해평가 등의 안전성 평가를 수행한 후 정부차원에서의 식품 위생/안전 정책 수립의 과학적 근거를 마련하고자 수행되었다. 시료 수거는 인구 백만 이상의 전국 9개 지역(서울, 부산, 인천, 대구, 대전, 광주, 울산, 창원 및 수원)을 선정한 후, 다소비 식품 중 대표적인 농산물 15품목(쌀, 감자, 대두, 사과, 배, 오렌지, 복숭아, 딸기, 바나나, 수박, 토마토, 오이, 애호박, 깻잎 및 무)을 선별하여 총 232건의 농산물을 수거하였다. 대상 농약은 단성분 분석으로 가능한 생장조정제 3종(dichlorprop, ethychlozate 및 6-benzylaminopurine) 및 다종다성분 분석 농약 280종, 총 283종을 선정하여 잔류농약 모니터링을 수행하였다. 분석 대상 농약들은 모니터링에 앞서 분석법을 개선하고 분석검체를 대표할 수 있는 농산물에 적용하여 국제적 기준인 CODEX 분석법 가이드라인에 준하여 분석법 검증을 수행한 후, 잔류농약 모니터링 분석법으로 사용하였다. 또한 모니터링에서 검출된 잔류농약을 대상으로 1일 섭취허용량(acceptable daily intake, ADI) 대비 1일 추정섭취량(estimated daily intake, EDI) 값으로 위해 평가를 수행하였다. 잔류농약 모니터링을 수행한 결과, 수거된 농산물 총 232건 중 163건(70.3%)에서는 농약이 검출되지 않았으며, 69건(29.7%)에서 잔류농약이 검출되었다. 검출된 농약 중 2건은 MRL을 초과하여 0.9%의 부적합률을 나타내었다. MRL을 초과한 잔류농약은 깻잎에서 검출된 chlorpyrifos와 복숭아에서 검출된 picoxystrobin이었으며, 부적합으로 나타난 chlorpyrifos 및 picoxystrobin을 포함한 검출 농약 33종에 대해 위해평가를 수행한 결과, ADI 대비 EDI는 0.00087~0.902%의 범위를 나타내었다. 이러한 결과를 통해 검출된 모든 농약은 위해도가 매우 낮은 것으로 판단됐으며, 유통되는 농산물은 잔류농약 측면에서 안전한 수준임을 확인하였다.

FMEDA 기법을 적용한 SIL 등급 판정에 관한 사례연구 (Case Study on the Assessment of SIL Using FMEDA)

  • 김병철;김영진
    • 산업공학
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    • 제25권4호
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    • pp.376-381
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    • 2012
  • As the number, complexity and interaction of electrical, electronic and programmable electronic (E/E/PE) systems increase, a growing emphasis has been placed on the concept of functional safety during product development. IEC 61508 provides guidelines and standardized procedures in the development of reliable and dependable E/E/PE systems to assure functional safety. Determining risk classes (i.e., safety integrity levels, SILs) associated to a specific E/E/PE item may be recognized as one of the most crucial activities in the product development per IEC 61508 since SILs are used to specify necessary safety requirements for achieving an acceptable residual risk. This article presents a case study on the assessment of SILs applying failure modes, effects and diagnostic analysis (FMEDA) from which failure rates may be derived for each important failure category by combining a standard FMEA with online diagnostic techniques.

스테인레스강 용접부의 피로균열 전파속도 예측에 관한 연구 (A Study on the Prediction of Fatigue Crack Growth Rate in Stainless Steel Weldments)

  • 이용복
    • 한국생산제조학회지
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    • 제7권3호
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    • pp.68-78
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    • 1998
  • Welding structure contains residual stress due to thermal-plastic strain during welding process, and its magnitude and distribution depend on welding conditions. Cracks initiate from various defects of the weldment, propagate and lead to final fracture, The crack initiation and propagation processes are affected by the magnitude and distribution. Therefore, the magnitude and distribution of weldment residual stress should be considered for safety design and service of welding structures. Also it is very important that more accurate assessment method of fatigue crack growth must take into account the redistributing the residual stress quantitively. because the residual stress in weldment has characteristics of its redistribution with loading magnitude, number of cycles and fatigue crack propagation. In this study fatigue crack behavior of STS-304 weldment was investigated during crack propagation into tensile residual stress region or compressive residual stress region. Crack growth rates were predicted and compared with experimental results.

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군 식품 안전성 확보를 위한 농산물 잔류농약 위해도 평가 연구 (A Study on the Risk Assessment of Pesticide Residues of Agricultural to Ensure Military Food Safety)

  • 조성용;서준호
    • 한국산학기술학회논문지
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    • 제21권10호
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    • pp.137-143
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    • 2020
  • 본 연구에서는 군 식품의 안전성 확보를 위해 경인·강원 소재의 9개 업체에서 사용하는 총 36건의 농산물을 대상으로 잔류농약 모니터링 및 위해도 평가를 실시하였다. 대상 시료는 대두, 밀가루, 밀쌀, 건조양파, 냉동딸기, 양파, 녹색콩, 땅콩, 아몬드, 참깨, 팥, 황색콩, 흑색콩, 당근, 대파, 마늘, 쌀가루, 고춧가루였으며 총 142종의 농약에 대해 식품공전의 다종농약다성분 분석법에 따라 잔류농약을 분석하였다. 분석결과 36건의 농산물 중 7건에서 잔류농약이 검출되어 19.4 %의 검출률을 나타내었다. 땅콩, 대파, 고춧가루에서 단성분 잔류농약이 각 1건씩 검출되었으며 고추장 및 전투식량에 사용된 고춧가루에서 다성분 잔류농약이 20종 검출되었으나 전부 잔류허용기준치 미만으로 확인되었다. 또한 검출된 잔류농약 중 가장 높은 농도를 보인 Cypermethrin, Tebuconazole, EPN 3종의 농약에 대한 위해도 평가 결과 섭취허용량 대비 섭취추정량은 100 %이하로 안전한 수준으로 판단된다. 본 연구에서 20대 성인 남성 위주로 구성된 군 집단의 특성을 반영한 잔류농약 위해평가 연구가 처음으로 수행되었다면, 향후에는 위해물질 저감화 등 응용연구를 지속할 수 있을 것으로 기대한다.

주철관의 잔존강도 평가에 관한 연구 (Assessment of Residual Tensile Strength on Cast Iron Water Pipes)

  • 배철호;김주환;김정현;홍성호
    • 상하수도학회지
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    • 제20권6호
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    • pp.867-874
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    • 2006
  • The goal of this study is to assess cast iron pipes (CIPs) and present a residual tensile strength prediction model using pit characteristics and fracture toughness. The results is the followings. First, average pit depths of collected CIPs were in the range from 0.63 to 6.49 mm, loss of tensile strength compared with net metallic tensile strength were from -7.06 to 67.91 percent. Second, fracture toughness for NS-CR-1, NS-CR-2, and NS(2)-CR-1 were in the range from 62.85 to $89.39kgf/mm^2{\sqrt{mm}}$, and average of those samples was $73.69kgf/mm^2{\sqrt{mm}}$ on CIPs. Third, the models developed in this study by using pit characteristics and fracture toughness showed a little good correlation for measured residual tensile strength, and the results will be expected to help for water utilities to manage CIPs in the aspect of rehabilitation and assessment of structural safety on CIPs.