• Title/Summary/Keyword: Residual Mg

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Residual Patterns of Insecticides Bifenthrin and Chlorfenapyr in Perilla Leaf as a Minor Crop (소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상)

  • Jeon, Sang-Oh;Hwang, Jeong-In;Kim, Tae-Hwa;Kwon, Chan-Hyeok;Son, Yeong-Uk;Kim, Dong-Sool;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.34 no.3
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    • pp.223-229
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    • 2015
  • BACKGROUND: It is important to understand residual patterns of pesticides applied on crops for ensuring their safety in agricultural products. However, there are few studies on the residual patterns of pesticides in minor crops, which are small in cultivation area. In this study, residual amounts of bifenthrin and chlorfenapyr sprayed on perilla leaf as a minor crop were investigated to know their residual patterns. METHODS AND RESULTS: Bifenthrin and chlorfenapyr were sprayed 2 or 3 times on perilla leaves at a week interval prior to harvest, and the perilla leaves were collected at 0, 1, 3, 5 and 7 days after the final application of pesticides. Recoveries for residual analysis of pesticides spiked on perilla leaves with concentrations of 0.1 and 0.5 mg/kg were 81.9-104.8%. The residual amounts of pesticides interpreted using first order kinetics model show that dissipation constants of bifenthrin and chlorfenapyr in perilla leaves were 0.0724-0.0535 and $0.0948-0.0821day^{-1}$, respectively. In addition, the dissipation half-lives in perilla leaves were 9.6-12.9 days for bifenthrin and 7.3-8.4 days for chlorfenapyr. When pre-harvest residue limits (PHRL) of bifenthrin and chlorfenapyr at 10 days before harvest calculated on the basis of the dissipation constants and maximum residue limits of the pesticides were calculated as 17.1 for bifenthrin and 15.9 mg/kg for chlorfenapyr. CONCLUSION: Therefore, the PHRL calculated using the time-dependant residual patterns of pesticides in perilla leaves and their regression analysis may be used as experimental evidences in order to ensure the safety of pesticides in perilla leaves before harvest.

Determination of Heavy Metals, Sulfur Dioxide and Residual Pepsticides in Oriental Medical Materials at SangJi University Oriental Medical Hospital (모 한방병원 한약재내 중금속과 이산화황 함량 및 잔류농약 분석 연구)

  • Heo, Seong-Kyu;Cha, Yun-Yop;Kim, Eu-Gene;Cho, Woong-Hee;Lee, Han;Baik, Tai-Hyun;Seo, Hyung-Sik;Park, Hee-Soo;Kim, Byoung-Woo;Kwon, Ki-Rok;Lee, Seung-Gi;Yoo, Jun-Sang;Sohn, Young-Joo;Sun, Seung-Ho;Kang, Hee-Chul;Seo, Yong-Chan
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.22 no.4
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    • pp.948-953
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    • 2008
  • The purpose of this study was to analyze harmful heavy metals, sulfur dioxide and residual pesticides in 27 kinds of oriental medical materials. This study was carried out on 27 samples of oriental medical materials. The GC-ECD(Varian, CP-3800) was used to analyze residual pesticides. ICP-OES(Varian, Vista-MPX) was used to analyze lead, arsenic, cadmium. Mercury was analyzed by amalgamation method. A modified Monier-Williams method was used to analyze sulfur dioxide. Arsenic was detected less than 3(mg/kg) in 14 samples and was not detected 13 samples. Lead was detected less than 5(mg/kg) in 15 samples and was not detected 12 samples. Mercury was detected less than 0.2(mg/kg) in 15 samples and was not detected 12 samples. Cadmium was detected more than 0.3(mg/kg) in 3 samples was detected less than 0.3(mg/kg) in 16 samples and was not detected 11 samples. A few residual pesticides was detected, but all residual pesticides was safe. Sulfur dioxide was detected in all samples, but all residual sulfur dioxide was safe.

Reduction in Residual Pesticides and Quercetin Yields in Onion Peel Extracts by Washing (세척방법에 따른 양파껍질추출물의 Quercetin수율 및 잔류농약 제거효과)

  • Jeong, Eun-Jeong;Cha, Yong-Jun
    • Journal of Life Science
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    • v.22 no.12
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    • pp.1665-1671
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    • 2012
  • This study was conducted to assess the removal of residual pesticides and to obtain high amounts of quercetin in onion peel extracts (OPEs) by 4 washing treatments. Washing is one of the standard processing steps in obtaining functional food ingredients from onion peel. After a first detergent wash (0.2% w/v) (DW) and hot air drying ($80^{\circ}C$, 24 hr) (B), 4 washing treatments were tested, including a second DW (C), ultrasonication ($50^{\circ}C$, 10 min) plus DW (D), 0.3% $H_2O_2$ (v/v) plus DW (E), and blanching ($95-97^{\circ}C$, 2 min) plus DW (F). This was followed by 60% (v/v) ethanol extraction and vacuum freeze drying of the OPE. The E treatment yielded 89.04% OPE and a quercetin content of 96.84% in the OPE compared with the B treatment, and had the highest efficiency of all treatments tested. The OPE was tested for the presence of 177 residual pesticides and three compounds were detected in all treatments: cyhalothirn, fluquinconazole and procymidone. Cyhalothirn and fluquinconazole levels were below the permitted levels for fresh onion, while procymidone was present in the high level range of 128.01~133.46 mg/kg in all samples. The E treatment was a better washing method than the others for removal of residual pesticides. It could reduce the level of residual pesticides without changing the functional properties of the OPE.

Experimental Study on Reduction of Temporal Dark Image Sticking on Bright Screen in AC-PDPs Using RF-Plasma Treatment on MgO layer

  • Park, Choon-Sang;Kim, Jae-Hyun;Tae, Heung-Sik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.101-103
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    • 2009
  • Minimizing the residual impurity level on the MgO layer is the key factor for reducing temporal dark image sticking on bright screen. In this paper, to reduce the residual impurity level on the MgO layer of 50-in. full-HD ac-PDP with He (35%) - Xe (11%) contents, RF-plasma treatments on the MgO layer are adopted under various gases for plasma treatment. As a result of monitoring the difference in the display luminance between the before and after 5-min. sustain discharge with a square-type image at peak luminance, the Ar and Ar>$O_2$ plasma treatments can reduce the temporal dark image sticking on the bright screen in an ac-PDP.

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Masking Effect of Chlorine on Algae-related Taste and Odor in Drinking Water Supplies (염소의 상수원 내 조류 이취미 Masking 효과)

  • Kim, Young-il;Lee, Yu-Jeong;Shin, Heung-Sup;Bae, Byung-Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.227-232
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    • 2008
  • The masking effect of chlorine on algae-related taste and odor(T&O) compounds has long been an important issue for water suppliers. In this study, masking experiments with chlorine were performed on two kinds of treated water and one of raw water. After adding chlorine(0 to 0.8 mg/L) to water samples, odor intensity was evaluated by a newly developed sensory method(2-out-of-5 odor test) for three days along with the measurement of residual chlorine concentration. Even though the relationship between the residual chlorine concentration and odor reported by the sensory analysts was not always coincident, it was proved that residual chlorine more than a certain concentration could completely mask both added geosmin and naturally occurring T&O compounds. For the sand-filtered water spiked with 10 ng/L of geosmin, 0.12-0.18 mg/L of residual chlorine was necessary to achieve complete masking. In the case of GAC-filtered water, 10 ng/L of spiked geosmin was completely masked by 0.15-0.1 mg/L of residual chlorine. Combined ozone and GAC was not enough to treat raw water spiked with 300 ng/L of geosmin. In this experiment, sensory analysts were able to detect earthy or musty odors from the treated water. From a masking experiment with raw water taken from the Daechung Reservoir, it was found that fishy odor was more difficult to mask with chlorine than earthy odor. As the chlorine residual declined, the analysts began to notice the original odor and the fishy odor was noticed earlier than the earthy odor.

Evaluation of Probabilistic Fatigue Crack Propagation Models in Mg-Al-Zn Alloys Under Maximum Load Conditions Using Residual of Random Variable (최대하중조건에 따른 Mg-Al-Zn 합금의 확률변수 잔차를 이용한 확률론적 피로균열전파모델 평가)

  • Choi, Seon Soon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.1
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    • pp.63-69
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    • 2015
  • The primary aim of this paper is to evaluate the probabilistic fatigue crack propagation models using the residual of a random variable and to present the probabilistic model fit for the probabilistic fatigue crack growth behavior in Mg-Al-Zn alloys under maximum load conditions. The models used in this study were prepared by applying a random variable to empirical fatigue crack propagation models such as the Paris-Erdogan model, Walker model, Forman model, and modified Forman model. It was verified that the good models for describing the stochastic variation of the fatigue crack propagation behavior in Mg-Al-Zn alloys under maximum load conditions were the 'probabilistic Paris-Erdogan model' and 'probabilistic Walker model'. The influence of the maximum load conditions on the stochastic variation of fatigue crack growth is also considered.

A Study of Probabilistic Fatigue Crack Propagation Models in Mg-Al-Zn Alloys Under Different Specimen Thickness Conditions by Using the Residual of a Random Variable (확률변수의 잔차를 이용한 Mg-Al-Zn 합금의 시편두께 조건에 따른 확률론적 피로균열전파모델 연구)

  • Choi, Seon-Soon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.4
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    • pp.379-386
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    • 2012
  • The primary aim of this paper was to evaluate several probabilistic fatigue crack propagation models using the residual of a random variable, and to present the model fit for probabilistic fatigue behavior in Mg-Al-Zn alloys. The proposed probabilistic models are the probabilistic Paris-Erdogan model, probabilistic Walker model, probabilistic Forman model, and probabilistic modified Forman models. These models were prepared by applying a random variable to the empirical fatigue crack propagation models with these names. The best models for describing fatigue crack propagation behavior in Mg-Al-Zn alloys were generally the probabilistic Paris-Erdogan and probabilistic Walker models. The probabilistic Forman model was a good model only for a specimen with a thickness of 9.45 mm.

Distribution Characteristics of Pesticide Residues in the Portions of Lettuce Leaves (상추 잎의 부위별 잔류농약 분포 특성)

  • Kwon, Sun-Mok;Choi, Ok-Kyung;Kim, Ki-Cheol;Kim, Jung-Beom;Kang, Heung-Gyu;Cho, Yun-Sik;Ha, Jin-Ok;Jang, Jin-Ho;Lee, Byoung-Hun;Lee, Sung-Nam;Lee, Sun-Young;Kang, Suk-Ho;Lee, Jong-Bok
    • The Korean Journal of Pesticide Science
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    • v.18 no.2
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    • pp.53-60
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    • 2014
  • This study was conducted to investigate the changes of the residual amount in the leafstalk (end) and the fore-end (upper) portion of lettuce leaves during cultivation period to 14 days, 12 times in total (0, 1, 2, 3, 4, 5, 7, 8, 10, 12, 13 and 14 days) after spraying with boscalid and lufenuron. In the case of boscalid, the initial concentrations at 3 hours (0 day) of the leafstalk and the fore-end portion of lettuce leaves were 18.26 mg/kg and 84.97 mg/kg, respectively and the residual amounts were rapidly decreased to 0.31 mg/kg and 0.37 mg/kg at 14 days after chemical application. In the case of lufenuron, the initial concentrations at 3 hours (0 day) of the leafstalk and the fore-end portion of lettuce leaves were 0.91 mg/kg and 5.21 mg/kg, respectively and the residual amounts were rapidly decreased to 0.06 mg/kg and 0.09 mg/kg at 13 days after chemical application. The variations of the residual concentrations analyzing 12 times after spraying showed that the residual amounts of the leafstalk portion of lettuce leaves were less than its fore-end portion in boscalid and lufenuron. In additon, 9 kinds of pesticide including boscalid in 16 lettuce leaf (found to contain pesticide in 2013) showed that the residual amounts of the leafstalk portion of lettuce leaves were less than its fore-end portion as well.

Residual Effects of Coal Fly Ashes on the Growth of Rice Crop Subsequent to Malting Barley (맥주보리 후작(後作) 벼의 생육(生育)에 대한 석탄회(石炭灰) 시용잔효(施用殘效))

  • Ha, Ho-Sung;Kang, Ui-Gum
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.373-379
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    • 1998
  • Fly ash application with a rate 0, 50, 100, $150Mg\;ha^{-1}$ in clay loam paddy, which had properties of pH 5.3 and low contents of silicate, gave a positively residual effects on the growth of rice crop subsequent to malting barley. The responses of rice yields to fly ash application were in the order of bituminous coal fly ash(BCFA) 100 > 150 > 50 > anthracite fly ash(AFA) 50 > 100 > none > AFA $150Mg\;ha^{-1}$. As a result, yields responses of milled rice were ranged from $6.2(50Mg\;ha^{-1}){\sim}14.4%(100Mg\;ha^{-1})$ by BCFA and from $-0.6(150Mg\;ha^{-1}){\sim}6.6%(50Mg\;ha^{-1})$ by AFA showing maximum yields of 5.084 and $4.738Mg\;ha^{-1}$ by the former and the latter, respectively. Rice plant showed lodging indices ranging from $20(50Mg\;ha^{-1}){\sim}40%(150Mg\;ha^{-1})$ by BCFA and from $1.3(150Mg\;ha^{-1}){\sim}15%(50Mg\;ha^{-1})$ by AFA at harvesting stage. In especial, soils applicated with BCFA contained a good fertility in terms of pH, available $P_2O_5$ and $SiO_2$, and exchangeable Ca and Mg etc. so that possibly harbored 3yr-residual effects of the fly ash on crop subsequent to this rice.

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Residual Stresses Analysis due to Volumetric Changes in Long-term Autogenous Expansive Concrete (장기팽창성 콘크리트의 체적변화에 의한 잔류응력 해석)

  • Cha, Soo-Won;Jang, Bong-Seok;Oh, Byung-Hyun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.6
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    • pp.617-625
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    • 2009
  • This study is devoted to the problems of thermal and autogenous expansion stresses in order to avoid cracking using chemically prestressing method. The chemical prestress can be induced by autogenous expansion characteristics of MgO concrete made in specific burning temperature. The volume change induced cracking has great influence on the long-term durability and serviceability. To evaluate risk of cracking, the computer programs for analysis of thermal and autogenous expansion stresses were developed. In these 3-D finite element procedures, long-term autogenous expansive deformation is modeled and its resultant stress is calculated and then verified by comparison with manual calculation results. In this study, the stress development is related to thermal and autogenous expansive deformation. Using the developed program, residual stresses of MgO concrete were compared and analysed in the example From the numerical results it is found that long-term, and temperature dependent expansive concrete with light-burnt MgO is most effective in controlling the risk of cracking of mass concrete because it has high temperature for long period. The developed analysis program can be efficiently utilized as a useful tool to evaluate the thermal and autogenous expansion stresses in mass concrete structures with lightly burnt MgO.