• Title/Summary/Keyword: Residence Time

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Effect of reaction temperature on synthesis of heptafluoropropane over activated carbon (활성탄상의 heptafluoropropane 합성에서 반응온도의 효과)

  • 김재덕;이윤우;임종성;이경환;이윤용
    • Fire Science and Engineering
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    • v.12 no.1
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    • pp.9-14
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    • 1998
  • The hepatfluoropropane(HFC-227ea) synthesis by fluorinatino of hepafluoroproylene(HFP) over activated carbon has been studied. The reaction temperature was varied from 5$0^{\circ}C$ to 40$0^{\circ}C$ at a constant feed mole ration and a residence time. The optimized reaction temperature was found to be about 20$0^{\circ}C$ at 2.5HF/HFP mole ratio and 238 sec. residence time. From these reaction conditions, the yield of HFC-227ea was obtained above 99% and the deactivation of activated carbon was not appeared. Accordingly, the activated carbon showed good performance to obtain heptafluoropropane by fluorinatin of hexafluoropropylene.

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Removal of #NH_3-N$ by using Immobilized Nitrifier Consortium in Polyvinyl Alcohol (PVA에 고정화된 질화세균에 의한 암모니아성 질소제거)

  • 서근학;김용하;조진구;김병진;서재관;박은주;김성구
    • Journal of Environmental Science International
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    • v.8 no.4
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    • pp.479-483
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    • 1999
  • Nitrifier consortium immobilized in polyvinyl alcohol was used for the removal of ammonia nitrogen from synthetic aquaculture water in the airlift bioreactor. At the aeration rate fo 0.15 vvm and bead packing volume fraction of 20%, airlift bioreactor was operated effectively for a removal of ammonia nitrogen and for a stability of operation. Ammonia nitrogen removal rate by airlift bioreactor was continuously increased with decreasing hydraulic residence time. At the HRT(hydraulic residence time) of 0.3 hour, ammonia nitrogen removal rate was 84.3 g/$m^3$.d and the highest ammonia nitrogen removal rate was 130.8 g/$m^3$.d when HRT was 0.1 hour.

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The numerical simulation on variation of phytoplankton maximum region in the estuary of Nakdong river -I. The state of variation of phytoplankton maximum region- (낙동강 하구해역의 식물플랑크톤 극대역 변동에 관한 수직시뮬레이션 -I. 식물플랑크톤 극대역 변동 현황-)

  • 이대인
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.369-374
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    • 2000
  • The estuary of Nakdong river is very influenced by the freshwater contained nutrients and organic materials. The response results of these influences are eutrophication and red tide outbreak in this region. Concentration of chlorophyll a was 0.78~62.55$\mu\textrm{g}$/L in February 1.20~21.29$\mu\textrm{g}$/L in April 1.88~188.35$\mu\textrm{g}$/L in June and 0.78~11.21$\mu\textrm{g}$/L in August respectively. The decrease of chlorophyll a is considered that residence time is shorten by increase of freshwater discharge and unfavorable growth condition of phytoplankton is created by diffusion of low salinity and increase of turbidity. The phytoplankton maximum region located inner side of this estuary during winter season whereas it was moved to outer side when mean discharge of the Nakdong risver was increased, Therefore the variation of phytoplankton maximum region was affected by input discharge from the Nakdong river basin.

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Evaluation of Soft Nip Calendering Characteristics of Newsprints (신문용지의 소프트닙 캘린더링 특성 평가)

  • 문성호;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.2
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    • pp.16-25
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    • 2000
  • The influence of four process parameters of soft nip calendering including calendering pressure, temperature, moisture content and nip residence time on bulk, smoothness and tensile strength of newsprints has been investigated. In addition, the effect of basis weights on calendering responses has been examined. Bulk of newsprints decreased and smoothness increased with the increase of the calendering pressure, temperature, moisture content of the sheets and nip residence time. Improvement in tensile strength was observed when low calendering pressure and high temperature of heat-ing roll were employed. Tensile strength of the newsprint, however, decreased abruptly when the calendering temperature and pressure increased above certain levels due to the rupture of sheet structure, which has been verified by SEM. SEM micrographs also showed that it would be possible to maintain the inner bulk while densifying the fibers on the outer surface of newsprint by adjusting the soft nip calendering variables properly.

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The Effect of Flame Radiation on NOx Emission Characteristic in Hydrogen Turbulent Diffusion Flames (수소 난류확산화염에서 NOx 생성특성에 대한 복사분율의 영향)

  • Kim, Seung-Han;Kim, Mun-Ki;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.47-58
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    • 2000
  • The relationship among the flame radiation, NOx emissions, residence time, and global strain rate are examined for turbulent non-premixed jet flames with wide variations in coaxial air conditions. Measurements of NOx emission, flame geometry and flame radiation were made to explain the NOx emission scaling based on global parameters such as flame residence time, global strain rate, and radiant fraction. The overall 1/2-power scaling is observed in coaxial air flames, irrespective of coaxial air conditions, but the degree of deviation from the l/2-slope curve in each case differs from one another. From the comparison between the results of pure hydrogen flames and those of helium diluted hydrogen flames, it is observed that flame radiation plays a significant role in pure hydrogen flames with coaxial air and the deviation from 1/2-power scaling may be explained in two reasons: the difference in the flame radiation and the difference in jet similarity in coaxial air flames. From the radiation measurements, more detailed explanations on these deviations were suggested.

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Powder Characteristics of $n-TiO_2$ Powder Synthesized by Chemical Vapor Synthesis (화학기상합성에 의해 제조된 $n-TiO_2$ 분말의 분말특성)

  • 김혜경
    • Journal of Powder Materials
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    • v.6 no.3
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    • pp.238-245
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    • 1999
  • The preparation of $n-TiO_2$ powder by the Chemical Vapor Synthesis process (CVS) was studied using the liquid metal organic precursor (TTIP). The residence time and the collection methods were considered as main processing variables through the experiments. The CVS equipment consisted of a micropump and a flashvaporizer, a tube furnace and a tubular collection device. The synthesis was performed at $1000^{\circ}C$ with various sets of collection zone. The residence time and the total system pressure were controlled in the range of 3~20 ms and 10 mbar, respectively. Nitrogen adsorption, X-ray diffraction and electron microscopy were used to determine particle size, specific surface area and crystallographic structure. The grain size of the as-prepared $n-TiO_2$ powder was in the range of 2~8 nm for all synthesis parameters and the powder exhibited only little agglomeration. The relationship between particle characteristics and the processing variables is reviewed based on simple growth model.

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NO Removal Efficiency by Pulsed Corona Discharge Process at Room Temperature (상온 펄스 코로나 방전 공정에 의한 NO 제거 효율)

  • 김동주;박정환;김교선
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.337-344
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    • 2002
  • In this study, we analyzed the NO removal efficiency by the pulsed corona discharge process and investigated the effects of several process variables such as initial concentrations of NO, $H_2O$, and NH$_3$, applied voltage, pulse frequency, diameter of the discharge electrode, and residence time. The removal efficiency of NO increased by the addition of $H_2O$ or NH$_3$, but the changes of initial NH$_3$ and $H_2O$ concentrations did not affect the removal efficiency of NO significantly. With the increases of the applied voltage or the residence time, the removal efficiency of NO increased. In addition, with the increases of the pulse frequency of applied voltage, or the diameter of the discharge electrode, the removal efficiency of NO increased. The experimental results can be used as a basis to design the pulsed corona discharge process to remove NO$_{x}$, SO$_{x}$ and VOCs.OCs.

Experimental Study of Collision Angle Effects on Heat Transfer During Droplet-wall Collision in Film Boiling Regime (막비등 영역에서 액적-벽면 충돌 시 충돌각도가 열전달에 미치는 영향에 관한 실험적 연구)

  • Park, Junseok;Kim, Hyungdae
    • Journal of ILASS-Korea
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    • v.22 no.3
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    • pp.129-136
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    • 2017
  • Effects of collision angle on heat transfer characteristics of a liquid droplet impinging on a heated wall above the Leidenfrost point temperature were experimentally investigated. The heated wall and droplet temperatures were $506^{\circ}C$ and $100^{\circ}C$, respectively, and the impact angle varied from $20^{\circ}$ to $90^{\circ}$ while the normal collision velocity was constant at 0.27 m/s. The droplet collision behaviors and the surface temperature distribution were measured using synchronized high-speed video and infrared cameras. The major physical parameters influencing upon droplet-wall collision heat transfer, such as residence time, wall heat flux, effective heat transfer area, heat transfer amount, were analyzed. It was found at the constant normal collision velocity that the residence time, wall heat flux and effective heat transfer area were hardly not changed, resulting in the almost constant heat transfer amount.

Analysis of Residence Time Distribution in Extrusion Process Including the Effect of 3-D Circulatory Flow (3차원 순환 유동효과를 고려한 압출공정에서의 체류시간 분포해석)

  • 권태헌
    • The Korean Journal of Rheology
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    • v.3 no.2
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    • pp.135-147
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    • 1991
  • 압출공정 중에 화학반응이 수반되는 경우에 화확반응은 온도와 체류시간분포 (Residence Time Distribution (RTD))에 의해 결정되므로 압출기의 설계 및 공정조건의 확 립에 있어서 RTD를 정확히 측정하거나 예측하는 것은 매우 중요하다. RTD를 예측하기 위 해 제안된 종래의 방법은 압출기내에서의 유동을 2차원으로 단순화하여 RTD와 체류시간분 포함수 f(T)와 누적 체류시간 분포함수 F(T)를 해석적으로 구하였다. 그러나 이러한 종래의 RTD에 관한 해석방법은 실제압출기 내부에서 일어나는 3차원적 순환유동(Circulatory Flow)을 정확하게 고려하지 못하는 문제점을 갖고 있다. 본논문에서는 RTD를 정확하게 예 측하기 위하여 3차원 순환유동을 고려한 RTD를 구하는 방식을 제시하고 f(T)에 관한 새로 운 공식을 유도하였다. 새로운 방식을 적용하기 위해서 유사 3차원(Quasi-3-Dimensional) 유한요소 해석법을 이용하여 속도분포를 구한 후에 순환유동을 고려한 RTD 및 f(T), F(T) 를 계산하였다. 순환유동이 고려안된 종래의 방법에 따른 계산 결과와 비교한 결과로서 종 래의 방식은 순환유동이 고려안되었기 때문에 RTD를 과소평가하는 경향이 있음을 알수 있 었다.

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Study on the flow inside an annular pipe with a periodic obstacle (주기적인 장애물을 가지는 환형 도관 내의 유동장에 대한 연구)

  • Ahn, Young-Kyoo;Choi, Hyoung-G.;Yong, Ho-Taek
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.209-211
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    • 2008
  • In this paper, a segregated finite element program for the analysis of an axisymmetric steady flow has been developed in order to investigate the flow inside an annular pipe with a periodic obstacle. For the verification of the developed code, a developing pipe flow has been solved and the solution is in a good agreement with the existing results. For the analysis of the flow inside an annular pipe with a periodic obstacle, three types of periodic obstacle are considered. From the present numerical analysis, various physical variables including flow pattern, pressure distribution and residence time are investigated as a preliminary study to the heat transfer analysis of an annular pipe flow with a periodic obstacle.

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