• Journal of the Korean Ceramic Society
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• v.38 no.10
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• pp.928-935
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• 2001

In this study, two kinds of activated carbon fibers were prepared from PAN-based stabilized fibers by physical activation with steam. The variations in specific surface area, amount of iodine adsorption and pore size distribution of the activated carbon fibers after the activation process were discussed. The activated carbon fibers were prepared by two different methods, namely a 1- and 2-step method. For the 2-step method, carbonization of fibers in $N_2$ atmosphere was carried out to make carbon fibers and then activated by steam. In normal two step steam activation, BET surface area of about $1019m^2/g$ was obtained in the study. In the 1-step steam activation process, the carbonization and activation were simultaneously carried out. In the one step steam activation, BET surface area of $1635m^2/g$ was obtained after heat-treatment at $990^{\circ}C$. However, nitrogen adsorption isotherms for oxidized PAN based activated carbon fibers that were prepared by both methods were type I in the Brunauer-Deming-Deming-Teller (BDDT) classification even though they have different BET surface areas, amounts of iodine adsorption and pore size distributions.

• Journal of the Semiconductor & Display Technology
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• v.4 no.4 s.13
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• pp.19-26
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• 2005

The process optimization of ozone concentration and half life time was investigated in ultra pure water and alkaline solutions for the wet cleaning of silicon wafer surface at room temperature. In the ultra pure water,. the maximum concentration (35 ppm) of ozone was measured at oxygen flow rate of 3 liters/min and ozone generator power over 60%. The half life time of ozone increased at lower power of ozone generator. Additive gases such as $N_2$ and $CO_2$ were added to increase the concentration and half life time of ozone. Although the maximum ozone concentration was higher with the addition of $N_2$ gas, a longer half life time was observed with the addition of $CO_2$. When $NH_4OH$ of 0.05 or 0.10 vol% was added in DI water, the pH of the solution was around 10. The addition of ozone resulted in the half life time less than 1 min. In order to maintain high pH and ozone concentration, ozone was continuously supplied in 0.05 vol% ammonia solutions. 3 ppm of ozone was dissolved in ammonia solutions. The static contact angle of silicon wafer surface became hydrophilic. The particle removal was possible alkaline ozone solutions. The organic contamination can be removed by ozonated ultra pure water and then alkaline solution containing ozone can remove the particles on silicon surface at room temperature.

• Clean Technology
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• v.5 no.1
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• pp.49-61
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• 1999

Fenton's oxidation can improve the biodegradability of refractory organic wastewater by generating $OH{\cdot}$ which is one of the most reactive species. Fenton's reagent is used to treat a variety of industrial waste containing a range of toxic organic compounds. But this process cannot be economical because of high chemical cost of $H_2O_2$, ferrous ion solution and high sludge disposal cost. In this study, we proposed a modified Fenton's oxidation process which can reduce the reagent cost and obtain better removal efficiencies with less Fenton's reagents, and have a good potential of sludge recycling. In modified Fenton reaction, ferrous ion solution is adjusted to optimal pH with NaOH. Then it added to the sample and reacted to $H_2O_2$. For the experiment, synthetic wastewater made of phenol, which is one of the typical water pollutants, was used and the ionic strength of this wastewater was controlled by adding $NaHCO_3$. The effects of DO, ionic strength, and $H_2O_2$ dosing methods were investigated. As a result, modified Fenton's treatment efficiencies are better than conventional Fenton's reaction treating leachate and dyeing wastewater. And modified Fenton's treatment efficiencies combined to the sludge recycling for a half of Iron dosage are as good as the conventional Fenton's for a normal Iron dosage.

• Journal of Korean Society on Water Environment
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• v.28 no.5
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• pp.704-716
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• 2012

This paper provides a detailed account of pilot testing conducted at South Lake Tahoe (California), the Ddukdo (Seoul) water treatment plant (WTP) and the Bokjung (Seongnam) WTP between February, 2010, and February, 2012. The objectives were first, to characterize the reactions of ozone with hydrogen peroxide (Peroxone) for Han River water following sand filtration, second to determine empirical ozone and hydrogen peroxide doses to remove a taste-and-odor surrogate 2-methylisoborneol (MIB) using an advanced oxidation process (AOP) configuration and third, to determine the optimum dosing configuration to reduce residual ozone to a safe level at the exit of the process. The testing was performed in a real-time plant environment at both low- and high seasonal water temperatures. Experimental results including ozone decomposition rates were dependent on temperature and pH, consistent with data reported by other researchers. MIB in post-sand-filtration water was spiked to 40-50 ng/L, and in all cases, it was reduced to below the specified target level (7 ng/liter) and typically non-detect (ND). It was demonstrated that Peroxone could achieve both MIB removal and low effluent ozone residual at ozone+hydrogen peroxide doses less than those for ozone alone. An empirical predictive model, suitable for use by design engineers and operating personnel and for incorporation in plant control systems was developed. Due to a significant reduction in the ozone reaction/decomposition at low winter temperatures, results demonstrate the hydrogen peroxide can be "pre-conditioned" in order to increase initial reaction rates and achieve lower ozone residuals. Results also indicate the method, location and composition of hydrogen peroxide injection is critical to successful implementation of Peroxone without using excessive chemicals or degrading performance.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.7
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• pp.697-703
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• 2006

Endocrine disruptors were measured with GC/MS in effluents discharged from sewage treatment processes in pilot scale for the purpose of water reuse. From that analysis, we compared the removal rate of them by treatment processes. Nonylphenol was mainly detected in effluents and high concentration from 0.36 to 0.94 ${\mu}g/L$. $17{\beta}$-estradiol(E2) and $17{\alpha}$-ethynylestradiol(EE2) were detected as below the limit of detection in effluent. Endocrine disruptors were removed effectively in the range from 50 to 100% by treatment process. EC50 value($9.0{\times}10^{-3}$ M) of $17{\beta}$-estradiol(E2) by dose response curve of E-screen assay has higher than that of bisphenol A($2.736{\times}10^{-5}M$) and p-octylphenol($9.760{\times}10^{-6}$ M). These results showed that alkylphenols have lower relative estrogen potency than other estrogens such as $17{\beta}$-estradiol(E2). Calculated estrogenic activity(ng-EEQ/L) was 2 times higher than measured total estrogenic activity which estimated by E-screen assay. Moreover estrogenic activity of effluent by treatment process showed very low as below 1 ng-EEQ/L.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.17 no.5
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• pp.398-404
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• 1984

This study was attempted to investigate variation of the bacterial flora in waste water treatment of fish meat paste plant by batch and continuous culture. The results of the experiment are as follows : 1. The removal rate of BOD in waste water treatment by activated sludge of continuous culture was above $90\%$. 2. In the process of nitric acidification of protein waste water, $NH_4-N\;and\;NO_2-N$ increased untill the lapse of 48 hours from culture, but $NO_3-N$ showed little change. 3. In activated sludge obtained from acclimation by batch culture for 10 days, bacteria good in capacity of nitric acidification were not appeared. 4. Among 120 strains of isolated bacteria, the most predominantly appeared bacterial flora were Enterobacteriaceae ($28\%$) and Pseudomonas spp. ($25\%$), In the latter term of aeration during which ammonia originates in abundance, Pseudomonas spp. was decreased but Enterobarteriaceae was increased. 5. Fifty percent of the isolated strains were able to grow in $0\%,\;3\%$ NaCl and $75\%$ artificial sea water, Therefore, it is suggested that sea water can be used as dilution water instead of tap water during the treatment of waste water.

• Korean Chemical Engineering Research
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• v.55 no.2
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• pp.141-155
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• 2017

In the present paper, we investigated the development status of precipitated calcium carbonate (PCC) production using steel slag, which is one of mineral carbonation (MC) technologies, from the standpoint of $CO_2$ utilization. Principle, feature, and global and domestic development status of the mineral carbonation technology were discussed together with the overview of the production method and market of PCC. Mineral carbonation is known as stable and environmentally-friendly technology enabling economical treatment of industrials wastes. Typically, PCC is produced by the reaction of $CO_2$ with supernatant solution after Ca extraction from steel slag followed by the separation of solid and liquid. The development status of MC using steel slag is at the pilot stage (Slag2PCC at Aalto University), and there remains the process economics improvement for commercialization. Key technologies for the further development are efficient extraction of Ca ions from steel slag including impurities removal, valorization of PCC via shape and size control, usage development and value-addition of residual slag, and optimization of reaction conditions for continuous process setup, etc.

• Korean Journal of Construction Engineering and Management
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• v.7 no.5
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• pp.159-166
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• 2006

It was found that Korean Standard of Estimate which has been used as the only basis of cost estimate of public construction projects had some side effects such as jerry-build construction and over-estimation because it failed to reflect the current price and the state-of-the-art construction methods in a changing construction environment. Therefore, the government decided to gradually introduce historical construction cost into cost estimate of public construction projects from 2004. This paper presents analytic criteria and a process model for deducing more current and reasonable historical construction cost for contract items from not only previous contract prices but also all of the other bid prices that were not contracted. The procedure of estimating actual unit cost proposed in this paper focuses on the removal of abnormal values including strategically too low or high prices and the time correction. In addition, basic research is conducted for the correction of actual unit cost through the analysis of fluctuation of bid price depending on bidding types and rates of successful bid. It is anticipated that the effective use of the proposed process model for estimating actual unit cost would make the cost estimation more current and reasonable.

• KSBB Journal
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• v.22 no.2
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• pp.97-101
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• 2007

This study was performed to examine the availability of anaerobic digestion of the remainders caused by bacterial cellulose production process using food wastes. They maybe to be considered as others second pollution sources. Thus, this study was targeted to minimize content of organic material and to obtain more energy in those remnants using two-phase UASB reactor. The working volume of first hydrolysis fermentor was 35 L (total 55 L) and the second methane fermentor was 40 L (total 50 L). The organic loading rate of hydrolysis fermentor was 3 g-VS/L${\cdot}$day and 25,000 ppm of $COD_{cr}$ for methane fermentor. The hydraulic retention time was 18 days for hydrolysis reactor and 33 days for methane reactor. The hydrolysis reactor and methane reactor were performed at 35, 40$^{\circ}C$ respectively. For the efficient stable performance, the composition of organic wastes at each stage was as follow; Food waste with bacterial culture remnants (1 : 1), bacterial cellulose remnants, bacterial cellulose culture remnants with food wastes saccharified solids (1 : 1). When the anaerobic digestion was performed stably at each stage, the COD removal efficiency was 88, 90, 91 % respectively. At this time, methane production rate was 0.26, 0.34, $0.32m^3\;CH_4/kg-COD_{remove}$. As well as the values of anaerobic digestion at third stage were more higher than values of anaerobic digestion using food wastes. It is clearly to say that the food wastes zero-emission system constructed in our lab is more efficient way to treat and reclaim food wastes.

• Journal of the Korean Chemical Society
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• v.55 no.2
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• pp.208-217
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• 2011

The effects of pH and temperature on the removal of two dyes (neutral red; NR and malachite green oxalates; MG) from aqueous effluents using Maghnia montmorillonite clay in a batch adsorption process were investigated. The results showed the stability of the optical properties of MG in aqueous solution and adsorbed onto clay under wide range of pH 3-9. However, the interaction of NR dye with clay is accompanied by a red shift of the main absorption bands of monomer cations under pH range of 3-5, whereas, those of neutral form remains nearly constant over the pH range of 8-12. The optimal pH for favorable adsorption of the dyes, i.e. ${\geq}$90% has been achieved in aqueous solutions at 6 and 7 for NR and VM respectively. The most suitable adsorption temperatures were 298 and 318 K with maximum adsorption capacities of 465.13mg/g for NR and 459.89 mg/g for MG. The adsorption equilibrium results for both dyes follow Langmuir, Freundlich isotherms. The numerical values of the mean free energy $E_a$ of 4.472-5.559 kj/mol and 2.000-2.886 kj/mol for NR and MG respectively indicated physical adsorption. Various thermodynamic parameters, such as ${\Delta}H^{\circ}$, ${\Delta}S^{\circ}$, ${\Delta}G^{\circ}$ and Ea have been calculated. The data showed that the adsorption process is spontaneous and endothermic. The sticking probability model was further used to assess the potential feasibility of the clay mineral as an alternative adsorbent for organic ion pollutants in aqueous solution.