• Title/Summary/Keyword: Relaxation properties

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Magnetic Properties and Relaxation of Vanadium Monolayer on Pd(001) Surface

  • Landge, Kalpana K.;Bialek, Beata;Lee, Jae-Il
    • Journal of Magnetics
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    • v.15 no.2
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    • pp.45-50
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    • 2010
  • We investigated the magnetism of vanadium monolayers on a Pd(001) surface. The electronic structure and the magnetic properties of the V/Pd(001) system were determined with the use of the full-potential linearized augmented plane-wave method within the general gradient approximation. Three magnetic configurations were studied: non-, ferro-, and antiferromagnetic. From the total energy calculations, we found that the V/Pd(001) system is the most stable in the antiferromagnetic configuration. The importance of relaxation on the magnetic properties of the systems was also studied. It was found that the Pd(001) surface covered with a V monolayer undergoes considerable relaxation in which the spacing between Pd layers increases in all three magnetic configurations. Contrary to the Pd interlayer spacing, the distance between the V overlayer and the topmost Pd layer is reduced. The interlayer spacing between the V overlayer and the Pd surface layer is the largest for the antiferromagnetic configuration. In the relaxed antiferromagnetic structure, the magnitude of the calculated magnetic moments on the V atoms was $1.31\;{\mu}_B$. The presence of the vanadium monolayer does not affect the paramagnetic properties of the Pd(001) surface.

Dielectric properties of 70/30 mol% P(VDF-TrFE) copolymer thin films with freqeuncy (70/30 mol% P(VDF-TrFE) 공중합체 박막의 주팍수에 따른 유전특성)

  • 윤종현;정무영;박수홍;임응춘;이상희;박상현;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.470-473
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    • 2001
  • In this study, 70/30 mol% P(VDF-TrFE) copolymer thin films were prepared by physical vapor deposition, and dielectric properties with frequency were investigated. From results of TA(Thermal Analysis), the Curie transition temperature and melting temperature were observed at 118.8$^{\circ}C$ and 146$^{\circ}C$, respectively. Therefore, while thin films were prepared, the substrate temperature was varied from 30$^{\circ}C$ to 90$^{\circ}C$. The dielectric constant decreased with increasing frequency. At measuring frequency of 1kHz, the relative dielectric constant increased from 3.643 to 23.998 with increasing substrate temperature from 30$^{\circ}C$ to 90$^{\circ}C$. As a result of dielectric loss factor, ${\alpha}$-relaxation and ${\beta}$-relaxation were observed near at 100Hz and 1MHz, respectively. And the magnitude of ${\alpha}$-relaxation decreased and that of ${\beta}$-relaxation increased with increasing substrate temperature.

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Dielectric Relaxation and Electrical Conduction Properties of La2NiO4+δ Ceramics (La2NiO4+δ세라믹스의 유전이완 및 전기전도특성)

  • Jung, Woo-Hwan
    • Korean Journal of Materials Research
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    • v.21 no.7
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    • pp.377-383
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    • 2011
  • Thermoelectric power, dc conductivity, and the dielectric relaxation properties of $La_2NiO_{4.03}$ are reported in the temperature range of 77 K - 300 K and in a frequency range of 20 Hz - 1 MHz. Thermoelectric power was positive below 300K. The measured thermoelectric power of $La_2NiO_{4.03}$ decreased linearly with temperature. The dc conductivity showed a temperature variation consistent with the variable range hopping mechanism at low temperatures and the adiabatic polaron hopping mechanism at high temperatures. The low temperature dc conductivity mechanism in $La_2NiO_{4.03}$ was analyzed using Mott's approach. The temperature dependence of thermoelectric power and dc conductivity suggests that the charge carriers responsible for conduction are strongly localized. The relaxation mechanism has been discussed in the frame of the electric modulus and loss spectra. The scaling behavior of the modulus and loss tangent suggests that the relaxation describes the same mechanism at various temperatures. The logarithmic angular frequency dependence of the loss peak is found to obey the Arrhenius law with activation energy of ~ 0.106eV. At low temperature, variable range hopping and large dielectric relaxation behavior for $La_2NiO_{4.03}$ are consistent with the polaronic nature of the charge carriers.

Non-linear rheology of tension structural element under single and variable loading history Part I: Theoretical derivations

  • Kmet, S.
    • Structural Engineering and Mechanics
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    • v.18 no.5
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    • pp.565-589
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    • 2004
  • The present paper concerns the macroscopic overall description of rheologic properties for steel wire and synthetic fibre cables under variable loading actions according to non-linear creep and/or relaxation theory. The general constitutive equations of non-linear creep and/or relaxation of tension elements - cables under one-step and the variable stress or strain inputs using the product and two types of additive approximations of the kernel functions are presented in the paper. The derived non-linear constitutive equations describe a non-linear rheologic behaviour of the cables for a variable stress or strain history using the kernel functions determined only by one-step - constant creep or relaxation tests. The developed constitutive equations enable to simulate and to predict in a general way non-linear rheologic behaviour of the cables under an arbitrary loading or straining history. The derived constitutive equations can be used for the various tension structural elements with the non-linear rheologic properties under uniaxial variable stressing or straining.

The magnetic properties in Bi$_2$Sr$_2$CaCu$_2$O$_8$ single crystal with columnar defects

  • Lee, C.W.;Shim, S.Y.;Ha, D.H.;Kim, D.H.;Lee, T.W.
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.103-106
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    • 2000
  • We have studied the magnetic properties in Bi$_2$Sr$_2$CaCu$_2$O$_8$ single crystal with columnar defects using micro Hall-probe array. We found that fold profiles inside sample were similar to the Bean's critical state model from the magnetic hysteresis measurement. In the magnetic relaxation measurement, the normalized relaxation rates were maximum near the center and decreased toward the edge of the sample expect zero gauss. The relaxation rates as a function of the temperature were maximum near the 40K and rapidly decreased both sides of the peak.

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Dielectric relaxation properties in the lead scandium niobate

  • Yeon Jung Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.4
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    • pp.227-232
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    • 2023
  • In this study, complex admittance as a function of temperature and frequency was measured to analyze the important relaxation properties of lead scandium niobate, which is physically important, although it is not an environmentally friendly electrical and electronic material, including lead. Lead scandium niobate was synthesized by heat treating the solid oxide, and the conductance, susceptance and capacitance were measured as a function of temperature and frequency from the temperature dependence of the RLC circuit. The relaxation characteristics of lead scandium niobate were found to be affected by contributions such as grain size, grain boundary characteristics, space charge, and dipole arrangement. As the temperature rises, the maximum admittance and susceptance increase in one direction, but the resonance frequency decreases below the transition temperature but increases after the phase transition.

Characterizing Viscoelastic Property of Soft Tissue Over the Hip as a Risk Factor of Pressure Ulcer

  • Lim, Kitaek;Kim, Seung-su;Choi, Woochol Joseph
    • Physical Therapy Korea
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    • v.28 no.1
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    • pp.72-76
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    • 2021
  • Background: A pressure ulcer is common in soft tissue over the greater trochanter (GT) in side-lying position, and sustained tissue deformation induced by the prolonged external force is a primary cause, which can be discussed with soft tissues' viscoelastic properties (i.e., stress relaxation, creep response). Objects: Using an automated hand-held indentation device, we measured the viscoelastic properties of soft tissue over the hip area, in order to examine how the properties are affected by site with respect to the GT. Methods: Twenty participants (15 males and 5 females) who aged from 21 to 32 were participated. An automated hand-held indentation device was used to measure the stress relaxation time and creep response. Trials were acquired for three different locations with respect to the GT (i.e., right over the GT, 6 cm anterior or posterior to the GT). For each location, five trials were acquired and averaged for data analyses. Results: Soft tissues' stress relaxation time and creep response were associated with site (F = 23.98, p < 0.005; F = 24.09, p < 0.005; respectively). The stress relaxation time was greatest at posterior gluteal region (19.22 ± 2.49 ms), and followed by anterior region (15.39 ± 2.47 ms) and right over the GT (14.40 ± 3.18 ms). Similarly, creep response was greatest at posterior gluteal region (1.16 ± 0.14), and followed by anterior region (0.95 ± 0.14) and right over the GT (0.89 ± 0.18). Conclusion: Our results showed that the stress relaxation and creep were greatest at the posterior gluteal region and least at right over the GT, indicating that the gluteal soft tissue is more protective to the prolonged external force, when compared to the trochanteric soft tissue. The results suggest that a risk of pressure ulcer over the GT may decrease with slightly posteriorly rotated side-lying position.

Viscoelastic Properties of Fruit Flesh(I) - Stress Relaxation Behavior - (과실(果實)의 점탄성(粘彈性) 특성(特性)(I) - 응력이완거동(應力弛緩擧動) -)

  • Kim, M.S.;Park, J.M.;Choi, D.S.
    • Journal of Biosystems Engineering
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    • v.17 no.3
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    • pp.260-271
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    • 1992
  • Fruits are generally subjected to mechanical forces during harvesting, handling, and transportation that may cause damage in the form of bruises, punctures, and cracks. In order to prevent damage, and insure better quality fruits for consumers, it is very essential to study physical properties of these materials. The studies were conducted to examine the effect of storage period, storage condition, and other factors, such as loading rate and initial strain, on the stress relaxation behavior of the fruit flesh, and develop nonlinear viscoelastic models to represent its stress relaxation behavior. The following results were obtained from the study : 1. Since the viscoelastic behavior of the fruits flesh was nonlinear, the behavior was satisfactorily modelled as follows ; $${\delta}({\varepsilon},\;t)={\varepsilon}^A[B\;{\exp}(-Ct)+D\;{\exp}(-Ft)+G(-Ht)]$$ But, for the every strain applied, the stress relaxation behavior of the fruit flesh, such as apple and pear, could be well described by the Generalized Maxwell model, respectively. 2. The effect of loading rate on the stress relaxation behavior was remarkable. The higher loading rate resulted in the higher initial stress, and the faster stress relaxation. 3. The higher initial strain resulted in the higher initial stress, and stress relaxed at the large initial strain was also much higher than at the small initial strain. 4. Stress relaxation rate and quantity stored in the fruits at the low temperature storage were much higher than those at the normal temperature storage in the same storage period. Also, in all fruits tested, the longer storage period was the more relaxation rate and quantity were shown. These trends in the normal temperature condition was the more significant than in the low temperature condition.

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The Electrical Characterization and Relaxation Behavior of Ag(Ta0.8Nb0.2)O3 Ceramics

  • Kim, Young-Sung;Kim, Jae-Chul;Jeong, Tae-Hoon;Nam, Sung-Pill;Lee, Seung-Hwan;Kim, Hong-Ki;Lee, Ku-Tak
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.100-102
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    • 2014
  • $Ag(Ta,Nb)O_3$ materials have a perovskite structure with a low loss tangent. These materials have been widely researched for their applications as high-frequency, passive components. Also, $Ag(Ta,Nb)O_3$ materials have weak frequency dispersion with high dielectric permittivity which gives them enormous potential for use in electronic components, including the filters, and embedded capacitors. Therefore, our research will discuss the structural and electrical relaxation properties of $Ag(Ta_{0.8}Nb_{0.2})O_3$ ceramics for device applications. We will investigate using X-ray diffraction to understand their structural properties and will analyze voltage dependent leakage current and timedependent relaxation behavior to understand their material properties.

A Study on The Relationship between TSC Properties and Structural Changes of Epoxy Composites Materials (에폭시 복합체의 TSC특성파 구조변화사이의 상관성 연구)

  • 왕종배;박준범;박경원;신철기;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.75-79
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    • 1993
  • The Thermally Stimulated Current(TSC) method has been allied to study the influence of the structural change and interface on the electrical properties of epoxy composites. Three DGBA- MeTHPA matrix model samples mixed different ratios arts silica(SiO$_2$) filled sample and silaln treating-filled sample have been studied. Above room temperature, the relaxation mode ${\alpha}$ peak associated with T$\_$g/ has been located at 110$^{\circ}C$. Below glass transition temperature(T$\_$g/), three relaxation modes are observed in all samples : a ${\beta}$ mode situated at 10$^{\circ}C$, a ${\gamma}$ mode located at -40$^{\circ}C$ and a $\delta$mode appeared in -120$^{\circ}C$, which may be due to segmental motion, side chains, substitution and terminal groups. The analysis of its fine structure indicates that constitution of elementary processes is characterized by the activation energy and relaxation time. Also the change of the molecular structure and their thermal motion are compared with the relaxation mode and conduction mechanism in TSC spectra through the dielectric properties and FTIR measurements.

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