• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1527-1527
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• 2001

Glucose, fructose and sucrose being the main sugars that can be found in natural fruit juice. Many instrumental methods, such as GC, LC, electrochemical or spectrometric methods provide information about both the total content of sugars and the specific concentration of each carbohydrate[1]. The simplicity of sample handling and measurement in the near IR(NIR) wavelength region, which allows the use of long pathlength, optical glass cells and optical fibers, makes NIR a good alternative for sugar determination [2]. In the present study, six varieties of persian grapes were harvested at intervals through august to october and analysed for sugars by NIR. The results were processed by principal component regression (PCR) and partial least squares (PLS) analysis. Sample juice was prepared by squeezing through gauze from crashed grape. This solution was treated by zinc ferrocyanide prior to analysis in order to eliminate colored compounds and all optically active nonsugar substances. For glucose and fructose the most characteristic wavelengths were 1456nm corresponding to the first harmonic O-H stretching and the second at 2062nm corresponding to O-H stretching and deformation; secondary characteristic combination bands were also seen at 2265 nm (O-H and C-C stretching) and at 2240 nm (C-H and C-C stretching). However these spectra were taken over a wavelength range from 1100-2500nm at room temperature of 25-$30^{\circ}C$. To test the accuracy of the described procedure, samples of six varieties of grape were analysed by the proposed NIR and a standard method[2]. Good agreement were found between these two sets of the results. To perform the recovery studies , samples of grape juices previously analysed by the proposed method, were spiked with known amounts of each individual sugars and then analysed again. Relative standard deviations varied from 1.4 to 1.8% for six independent measurements of individual and total sugar concentration. In the analysis of real and synthetic samples, precise and accurate results were obtained , providing accuracy errors lower than 1.9% in all cases. Average recoveries of ${97}{\pm}{4%}$ for total sugar and between ${95}{\pm}{5%}$ and ${99}{\pm}{2%}$ for sing1e sugars demonstrate the applicability of the methodology developed to the direct analysis of grape Juice.

• Journal of the Korea Concrete Institute
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• v.13 no.5
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• pp.476-483
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• 2001

초유동콘크리트는 유동성 증진 및 충전성 향상을 위해 단위분체량을 크게하기 때문에 콘크리트의 고강도화와 수화발열량을 증가시키는 문제점을 가지고 있다. 이에 본 연구는 초유동콘크리트의 강도조절과 수화열 저감을 위해 쇄석분을 이용하여 초유동콘크리트의 강도, 유동성, 내구성능 및 건조수축 특성을 검토하였다. 실험결과 쇄석분은 치환율 10% 증가시마다 무치환시의 압축강도를 약 10~15%씩 감소시키며, 변형계수와 물구속비를 감소시켜 초유동콘크리트의 유동성 향상에 효과적이다. 또한 초유동콘크리트에서 쇄석분 10%치환시 마다 단위시멘트량 감소에 따른 최고 단열온도상승량을 약 4$^{\circ}C$씩 감소시켰다. 반면 건조수축량은 10%치환시 마다 약 5%증가시켰다. 한편 초유동콘크리트의 내구성능은 단위분체량과 유동성향상에 따른 조직의 치밀화로 쇄석분 치환에 관계없이 상대동탄성계수 90%이상으로 우수하게 나타났다. 이와 같이 분체로서 쇄석분 사용은 치환량에 따른 초유동콘크리트의 강도조절이 가능하며 수화발열량을 저감시킬 수 있다. ^ x Super flowing concrete causes high strength and the increase of heat of hydration because of the big unit powder content of concrete to increase flowability and to improve compact of concrete. Therefore, this study investigates the characteristic properties of strength, flowability, durability and drying shrinkage to control strength and to reduce heat of hydration of super flowing concrete using crushed stone fines. According to the experimental results, when crushed stone fines are increased every 10%, 10~15% of compressive strength is decreased and flowability of super flowing concrete is effectively improved due to the decrease of modulus of deformation and confined water ratio. When crushed stone fines are replaced every 10%, 4$^{\circ}C$ of the highest adiabatic temperature rise is decreased by reducing the unit cement. However, 5% of drying shrinkage is increased in the same condition. In the meantime, durability of super flowing concrete is excellent, having over 90 % of good relative dynamic modulus of elasticity due to fineness of formation caused by the increase of the unit powder content and the improvement of flowability, without regard to the replacement of crushed stone fines. Therefore, it can be said that the usage of crushed stone fines can control the strength of super flowing concrete by replacement and reduce heat of hydration.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.31 no.5
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• pp.375-384
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• 2013

Most of regions within the city of Mokpo, located on the southwest coast of the Korean Peninsula, are subjected to significant subsidence because about 70% of the city is land reclaimed from the sea (Kim et al., 2005). In this study, we aimed to estimate the rate of subsidence over Mokpo by using PALSAR L-band dataset from 2006 to 2010. Time series analysis was performed as well using GPS surveying data from 2010 to 2012. Results from these two independent datasets are then compared and analyzed over the common period of time. GPS data processing provides the results of seasonal variation on the surface, that is, via repeatedly rising and falling in association with the periodic cycle. Therefore, a time series analysis was performed to calculate the rate of ground subsidence. The deformation rates calculated for the same point are 3.89cm/yr and 2.65cm/yr from the GPS data and SAR data, respectively. SAR and GPS data processing results show a very similar pattern in terms of magnitude of annual subsidence. Thus, if the two datasets are integrated together, new modeling on ground subsidence is feasible. Lastly, subsidence was detected in a landfill area in the city of Mokpo, which has been continuously occurring through 2012.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.3
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• pp.355-373
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• 2017

Tunnelling in urban areas, it is essential to understand existing structure-tunnel interactive behavior. Serviced structures in the city are supported by pile foundation, since they are certainly effected due to tunnelling. In this research, thus, pile load distribution and ground behavior due to tunnelling below grouped pile were investigated using laboratory model test. Grouped pile foundations were considered as 2, 3 row pile and offsets (between pile tip and tunnel crown: 0.5D, 1.0D and 1.5D for generalization to tunnel diameter, D means tunnel diameter). Soil in the tank for laboratory model test was formed by loose sand (relative density: Dr = 30%) and strain gauges were attached to the pile inner shaft to estimate distribution of axial force. Also, settlements of grouped pile and adjacent ground surface depending on the offsets were measured by LVDT and dial gauge, respectively. Tunnelling-induced deformation of underground was measured by close range photogrammetric technique. Numerical analysis was conducted to analyze and compare with results from laboratory model test and close range photogrammetry. For expression of tunnel excavation, the concept of volume loss was applied in this study, it was 1.5%. As a result from this study, far offset, the smaller reduction of pile axial load and was appeared trend of settlement was similar among them. Particulary, ratio of pile load and settlement reduction were larger when the offset is from 0.5D to 1.0D than from 1.0D to 1.5D.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.1
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• pp.107-114
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• 2017

A turbocharger is an engine supercharger that is driven by exhaust gas. It improves the output and fuel efficiency by increasing the charging efficiency of the mixture gas, which is achieved by changing the rotatory power of the turbine connected to the exhaust passage. It is important to control the supercharging for this purpose. A nozzle slide joint is one of the core parts. Austenitic stainless steel is currently used as the material for this part, and its excellent mechanical properties include high heat resistance and corrosion resistance. However, because of its poor machinability, there are many difficulties in producing products with complicated shapes. Machining is used in the production of nozzle slide joints for high dimensional accuracy after metal powder injection molding. As design variables in this study, we investigated the sintering temperature, product stress, deformation rate, radius of curvature of the punch, and angle of the chamfer punch, which are related to the strain and shapes. The goal is to suggest a forming process using Nitronic 60 that does not require machining to manufacture a nozzle slide joint for a turbocharger. Accordingly, we determined the best process environment using finite-element analysis, the signal-noise ratio, and the Taguchi method for experiment design. The relative density and hydrostatic pressure of the final product were in accordance with the results of the finite element analysis. Therefore, we conclude that the Taguchi method can be applied to the design process of metal powder injection molding.

• Journal of Korean Society of Steel Construction
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• v.23 no.3
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• pp.261-273
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• 2011

Recently, the demands for steel frame are increasing because of the trend and due to the demand for bigger and higher buildings. In the analysis of typical steel frame, connections are based on the idealized fixed or pinned connection. A fixed connection assumes that the relative angle of each member before deformation is the same after the transformation. Therefore, the stiffener reinforces the connection to sufficient rigidity and stability of the panel zone. In the economical aspect, however, the necessity of connection that the stiffener reinforcement has omitted is increasing due to the excessive production as well as labor costs of connection. In contrast, pinned connection is assumed that bending moments between the beams and columns do not transfer to each member. This is easy to make in the plant and the construction is simple. However, the structural efficiency is reduced in pinned connection because connection cannot transfer moments. The introduction of this semirigid process can decide efficient cross-sectional dimensions that promote ease in the course of structural erection, as performed by members in the field-a call for safety in the entire frame. Therefore, foreign countries exert efforts to study the practical behavior and the results are applied to criterion. This paper analyzes the semirigid connection of domestic steel by design specifications of AISC/LRFD and make data bank that pertain to each steel. After wards, the results are compared to those of idealized connection; at the same time, this paper presents a design method that matches economic efficiency, end-fixity, and rotational stiffness.

• Journal of the Korean Geotechnical Society
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• v.20 no.7
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• pp.69-78
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• 2004

In this study, the back analysis program was developed by applying the genetic algorithm, one of artificial intelligence fields, to the direct method. The optimization process which has influence on the efficiency of the direct method was modulated with genetic algorithm. On conditions that the displacement computed by forward analysis for a certain rock mass model was the same as the displacement measured at the tunnel section, back analysis was executed to verify the validity of the program. Usefulness of the program was confirmed by comparing relative errors calculated by back analysis, which is carried out under the same rock mass conditions as analysis model of Gens et at (1987), one of back analysis case in the past. We estimated the total displacement occurring by tunnelling with the crown settlement and convergence measured at the working faces in three tunnel sites of Kyungbu Express railway. Those data measured at the working face are used for back analysis as the input data after confidence test. As the results of the back analysis, we comprehended the tendency of tunnel behaviors with comparing the respective deformation characteristics obtained by the measurement at the working face and by back analysis. Also the usefulness and applicability of the back analysis program developed in this study were verified.

• Journal of the Korean GEO-environmental Society
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• v.10 no.5
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• pp.19-26
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• 2009

Rammed Aggregate Pier (RAP) method is intermediate foundation between deep and shallow foundation, and it has been built in world wide. RAP represents a relatively new method that has grown steadily over 19 years since Geopier of USA developed this revolutionary method in 1989. The investigation and research in domestic is not accomplished. In this paper, the examined details of different spacing of piles, bearing capacities, respectively, conclude with recommendations on how RAP can be used in future needs. This documentation further provides comparisons of the laboratory test results which were obtained from changing the spacing of piles, namely installed rammed aggregate pier. Laboratory model test was administered in a sand box. Strain control test was conducted to determine the bearing capacities of the piers; 20 mm, 30 mm and 40 mm RAP in diameter using drilling equipment to make holes were installed in sand at initial relative densities of 40%. By comparing different spacing of piles, in this experiment, piles are spaced structually span, form a ring shape, narrowing the distance of each other, to the center. the result shows that as diameter of pier is bigger in diameter, bearing capacity also dramatically increased due to raised stiffness. Also, as the space between each piers was closed, the settlement rate of soil was decreased significantly. From the test results, as the space between each piles were getting closer, it allows greater chances to have more resistance to deformation, and shows more improved stability of structures. After from the verification work which is continuous leads the accumulation of the site measuring data which is various, and bearing capacity and the settlement is a plan where the research will be advanced for optimum installed RAP.

• Tribology and Lubricants
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• v.11 no.5
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• pp.128-135
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• 1995

Atomic force microscopy/friction force microscopy (AFM/FFM) techniques are increasingly used for tribological studies of engineering surfaces at scales, ranging from atomic and molecular to microscales. These techniques have been used to study surface roughness, adhesion, friction, scratching/wear, indentation, detection of material transfer, and boundary lubrication and for nanofabrication/nanomachining purposes. Micro/nanotribological studies of single-crystal silicon, natural diamond, magnetic media (magnetic tapes and disks) and magnetic heads have been conducted. Commonly measured roughness parameters are found to be scale dependent, requiring the need of scale-independent fractal parameters to characterize surface roughness. Measurements of atomic-scale friction of a freshly-cleaved highly-oriented pyrolytic graphite exhibited the same periodicity as that of corresponding topography. However, the peaks in friction and those in corresponding topography were displaced relative to each other. Variations in atomic-scale friction and the observed displacement has been explained by the variations in interatomic forces in the normal and lateral directions. Local variation in microscale friction is found to correspond to the local slope suggesting that a ratchet mechanism is responsible for this variation. Directionality in the friction is observed on both micro- and macro scales which results from the surface preparation and anisotropy in surface roughness. Microscale friction is generally found to be smaller than the macrofriction as there is less ploughing contribution in microscale measurements. Microscale friction is load dependent and friction values increase with an increase in the normal load approaching to the macrofriction at contact stresses higher than the hardness of the softer material. Wear rate for single-crystal silicon is approximately constant for various loads and test durations. However, for magnetic disks with a multilayered thin-film structure, the wear of the diamond like carbon overcoat is catastrophic. Breakdown of thin films can be detected with AFM. Evolution of the wear has also been studied using AFM. Wear is found to be initiated at nono scratches. AFM has been modified to obtain load-displacement curves and for nanoindentation hardness measurements with depth of indentation as low as 1 mm. Scratching and indentation on nanoscales are the powerful ways to screen for adhesion and resistance to deformation of ultrathin fdms. Detection of material transfer on a nanoscale is possible with AFM. Boundary lubrication studies and measurement of lubricant-film thichness with a lateral resolution on a nanoscale have been conducted using AFM. Self-assembled monolyers and chemically-bonded lubricant films with a mobile fraction are superior in wear resistance. Finally, AFM has also shown to be useful for nanofabrication/nanomachining. Friction and wear on micro-and nanoscales have been found to be generally smaller compared to that at macroscales. Therefore, micro/nanotribological studies may help def'me the regimes for ultra-low friction and near zero wear.

• Korean Journal of Materials Research
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• v.16 no.4
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• pp.225-230
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• 2006

Nanoimprint lithography (NIL) is a novel method of fabricating nanometer scale patterns. It is a simple process with low cost, high throughput and resolution. NIL creates patterns by mechanical deformation of an imprint resist and physical contact process. The imprint resist is typically a monomer or polymer formulation that is cured by heat or UV light during the imprinting process. Stiction between the resist and the stamp is resulted from this physical contact process. Stiction issue is more important in the stamps including narrow pattern size and wide area. Therefore, the antistiction layer coating is very effective to prevent this problem and ensure successful NIL. In this paper, an antistiction layer was deposited and characterized by PECVD (plasma enhanced chemical vapor deposition) method for metal stamps. Deposition rates of an antistiction layer on Si and Ni substrates were in proportion to deposited time and 3.4 nm/min and 2.5 nm/min, respectively. A 50 nm thick antistiction layer showed 90% relative transmittance at 365 nm wavelength. Contact angle result showed good hydrophobicity over 105 degree. $CF_2$ and $CF_3$ peaks were founded in ATR-FTIR analysis. The thicknesses and the contact angle of a 50 nm thick antistiction film were slightly changed during chemical resistance test using acetone and sulfuric acid. To evaluate the deposited antistiction layer, a 50 nm thick film was coated on a stainless steel stamp made by wet etching process. A PMMA substrate was successfully imprinting without pattern degradations by the stainless steel stamp with an antistiction layer. The test result shows that antistiction layer coating is very effective for NIL.