• Journal of Electrochemical Science and Technology
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• 제9권1호
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• pp.37-43
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• 2018

In order to improve current efficiency and decrease energy consumption in the electrosynthesis of ammonium persulfate, electrolytic properties of four cation exchange membranes, namely, the $JCM-II^{(R)}$ membrane, $Nafion^{(R)}$ 324 membrane CMI-$7000^{(R)}$ membrane and a self-made perfluorosulfonic ion exchange membrane (PGN membrane) were investigated using a sintered platinized titanium anode and a Pb-Sb-Sn alloy cathode in a self-made electrolytic cell. The effect of cell voltage and electrolyte flow rate on the current efficiency and the energy consumption were investigated. The results indicated that the PGN membrane could improve current efficiency to 94.85% and decrease energy consumption to $1119kWh\;t^{-1}$ (energy consumption per ton of the ammonium persulfate generated) under the optimal operating conditions and the highest current efficiency of the $JCM-II^{(R)}$ membrane, $Nafion^{(R)}$ 324 membrane and CMI-$7000^{(R)}$ membrane were 80.73%, 77.76% and 73.22% with their lowest energy consumption of $1323kWh\;t^{-1}$, $1539kWh\;t^{-1}$ and $2256kWh\;t^{-1}$, respectively. The PGN membrane has the advantages of high current efficiency and energy power consumption and has sufficient mechanical strength with the reinforced mesh. Therefore the PGN membrane will has good value in popularization in the industrial electrosynthesis of ammonium persulfate in the future.

• 멤브레인
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• 제33권5호
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• pp.257-268
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• 2023

막 축전식 탈염 공정(membrane capacitive deionization, MCDI)은 이온교환막을 다공성 전극과 함께 사용하여 탈염 효율을 향상시킬 수 있는 CDI 공정의 변형이다. 이온교환막은 MCDI의 성능에 큰 영향을 미치는 핵심 구성요소이다. 본 연구에서는 MCDI의 탈염 효율을 크게 향상시킬 수 있는 이온교환막의 최적 제조 인자를 도출하고자 하였다. 이를 위해 PE 다공성 필름의 세공에 단량체를 충진하고 in-situ 광중합을 진행하여 세공충진 이온교환막(pore-filled ion-exchange membranes, PFIEMs)을 제조하였다. 실험 결과, 제조된 PFIEMs은 다양한 탈염 및 에너지 변환 공정에 적용할 수 있는 수준의 우수한 전기화학적 특성을 나타내었다. 또한, MCDI 성능과 막 특성 인자와의 상관성 분석을 통해 막의 가교도를 제어하여 막의 전기적 저항이 충분히 낮은 범위에서 이온 선택 투과성을 최대화하는 것이 MCDI의 성능 향상을 위해 가장 바람직한 막제조 조건이라는 결론을 얻었다.

• 대한기계학회논문집A
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• 제24권8호
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• pp.1968-1799
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• 2000

A warpage analysis program has been developed for fiber-reinforced injection molded parts. The warpage is predicted from the residual stress and anisotropic thermo-mechanical properties coupled with fiber orientation in the integrated injection molding simulation. A simple elastic model is used for the calculation of thermally and pressure-induced residual stresses which are employed as the initial conditions in the structural analysis. To improve the reliability of warpage analysis, a new triangular flat shell element superimposing well-known efficient plate bending and membrane element is presented. The numerical examples address the necessity to use anisotropic models for fiber-reinforced materials and show that predicted warpage is in good agreement with experimentally measured one.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2003년도 봄 학술발표회 논문집
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• pp.153-160
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• 2003

Nonlinear finite element analysis of reinforced concrete panels subjected to biaxial tensile loads are carried out by using a 9-node assumed strain shell element. The present study mainly focuses on the performance evaluation of material models such as cracking criteria, tension stiffening model and steel model in the membrane energy dominant situation. From numerical results, the exponential form of tension stiffening model together with the use of average yield stress model for the steel embedded in the concrete performs well in the panel analysis under biaxial tensile loading condition and it produces a good agreement with experiment results. Finally, the present results are provided as a benchmark test for reinforced concrete panel structures.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.745-750
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• 2000

A warpage analysis program has been developed for fiber-reinforced injection molded parts. The warpage is Predicted from the residual stress and anisotropic thermo-mechanical properties coupled with fiber orientation in the integrated injection molding simulation. A simple elastic model is used for the calculation of thermally and pressure-induced residual stresses which are employed as the initial conditions in the structural analysis. To improve the reliability of warpage analysis, a new triangular flat shell element superimposing well-known efficient plate bending and membrane element is presented. The numerical examples address the neccesity to use anisotropic models for fiber-reinforced materials and show that predicted warpage is in good agreement with experimentally measured one.

• 한국공간구조학회논문집
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• 제3권1호
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• pp.77-85
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• 2003

This paper presents a truss model that can predict the shear behavior of reinforced concrete (RC) beams subjected to the combined actions of shear and flexure. Unlike other truss models, the proposed truss model, TATM, takes into account the effect of the flexural moment on the shear strength of RC beams with different shear span-to-depth ratios. To check the successfulness of the proposed model experimentally obtained stress shear strain curves were compared to the predicted ones using the proposed truss model. Furthermore, the shear strengths of 170 RC test beams with variable shear span-to-depth ratios were compared to the shear strengths as given by the truss model reported in this paper.

• Carbon letters
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• 제13권3호
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• pp.139-150
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• 2012

Poly-L-lactic acid (PLLA), PLLA/hydroxyapatite (HA), PLLA/multiwalled carbon nanotubes (MWNTs)/HA, PLLA/trifluoroethanol (TFE), PLLA/gelatin, and carbon nanofibers (CNFs)/${\beta}$-tricalcium phosphate (${\beta}$-TCP) composite membranes (scaffolds) were fabricated by electrospinning and their morphologies, and mechanical properties were characterized for use in bone tissue regeneration/guided tissue regeneration. MWNTs and HA nanoparticles were well distributed in the membranes and the degradation characteristics were improved. PLLA/MWNTs/HA membranes enhanced the adhesion and proliferation of periodontal ligament cells (PDLCs) by 30% and inhibited the adhesion of gingival epithelial cells by 30%. Osteoblast-like MG-63 cells on the randomly fiber oriented PLLA/TEF membrane showed irregular forms, while the cells exhibited shuttle-like shapes on the parallel fiber oriented membrane. Classical supersaturated simulated body fluids were modified by $CO_2$ bubbling and applied to promote the biomineralization of the PLLA/gelatin membrane; this resulted in predictions of bone bonding bioactivity of the substrates. The ${\beta}$-TCP membranes exhibit good biocompatibility, have an effect on PDLC growth comparable to that of pure CNF membrane, and can be applied as scaffolds for bone tissue regeneration.

• 멤브레인
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• 제33권6호
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• pp.325-343
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• 2023

직접 메탄올 연료전지(direct methanol fuel cell, DMFC)는 연료의 개질 없이 메탄올 연료를 공급하여 수소이온과 전자 생성을 통해 전류를 생산하는 에너지 변환 장치이다. 현재 DMFC에 적용되고 있는 고분자 전해질 막(polymer electrolyte membrane, PEM)은 높은 수소이온 전도도와 물리화학적 안정성을 갖는 과불소화계 이오노머를 활용한 PEM이지만, 높은 메탄올 투과율과 분해 시 발생되는 환경 오염 물질 등의 문제로 인해 신규 소재 개발이 요구되고 있다. 최근 들어, 과불소화계 이오노머에 비해 낮은 연료 투과율 및 우수한 물리화학적 안정성을 갖는 탄화수소계 고분자 기반 PEM을 DMFC에 적용하는 연구들이 보고되고 있다. 본 총설에서는 탄화수소계 고분자 기반 PEM 중 1) 친수성/소수성 영역의 뚜렷한 나노 상분리 구조를 나타내는 가지형 공중합체를 합성하여 수소이온 전도성과 메탄올의 선택도를 향상시킨 연구, 2) 제막 단계에서 가교 구조를 도입하여 메탄올 투과율을 감소시키고 치수 안정성을 향상시킨 연구, 3) 유/무기계 첨가제 및 다공성 지지체를 도입하여 성능을 개선한 복합 막 개발 연구에 대해 소개하고자 한다.

• Journal of Welding and Joining
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• 제13권3호
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• pp.1-7
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• 1995

1992년 9월 현재 전 세계적으로 운전 중(건설포함)인 액화 및 인수기지의 LNG 저장탱크는 지상식-이중벽 금속 탱크, 지상식-맴브레인 PC 탱크, 지상식-자립식 내부탱크/PC 외부탱크, 피드식-RC(Reinforced Concrete) 보강둑 탱크, 피트식-이중벽 금속탱크, 피트식-자립식 내부탱크/PC 외부탱크 및 지하식 탱크의 7가지 유형으로 나 타낼 수 있다. 또한 액화천연가스를 저장하는 내부탱크 소재에 따라 9%Ni강 및 MEMBRANE(SUS304) 형식으로 대별할 수 있다. MEMBRANE 저장탱크 형식의 핵심기술인 MEMBRANE은 -162.deg.C의 LNG에 의한 열수축팽창에 견딜 수 있도록 스테인레스강판 (SUS304)을 사용하여 기하학적으로 특이한 주름진 형상을 갖도록 설계되었으며 주름 형상에 따라 프랑스의 테크니가즈(Technigaz), 일본의 가와사끼(Kawasaki). 미쓰비시 (Mitsubishi), 이시가와지마하리마(Ishikawajima-Harima)사의 멤브레인과 세계에서 3번째로 한국가스공사 연구개발원이 개발한 링디식 멤브레인으로 구별할 수 있다. 본 해설에서는 국내의 전국 천연가스 공급사업계획 및 건설현황을 검토하고 최근 전 세계적으로 널리 사용되고 있는 액화천연가스 저장탱크의 종류를 용량별, 년도별로 분석하여 전세계의 액화천연가스 저장탱크에 관해 소개 하겠다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술대회지
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• pp.39-44
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• 2004

A heat and room temperature construction method of asphalt have been mainly applying to rooftop waterproofing in concrete structure, and the rest construction method are sheet, membrane and mortar waterproofing construction method. In particular, joint method in sheet waterproof method is as overlap joint which on being reinforced with fiber and tape, have been applying for job site to mechanical fix using protection disk and anchorage and metal ironwork on the end of sheet. These construction method cause cutting off joint of sheet as behavior of structure according to repairs of sheet itself and thermal conduct, outdoor air environment. In conclusion, we analyzed and examined the application of various sheets and piece ashes about superior 'I' joint which divide from one and the other sheet and progressed about joint construction method of fixing method for overlap.