• Composites Research
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• v.20 no.6
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• pp.28-33
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• 2007

The puncture properties of short-fiber reinforced rubber were investigated as functions of fiber aspect ratio(AR: length of fiber/diameter of fiber), fiber content, specimen size and testing velocity. The puncture stresses of the matrix and short-fiber reinforced rubber decreased with specimen size, and increased with testing velocity at same specimen size. As the fiber AR increased the puncture stress at given fiber content also increased. The problem of the specimen shape was investigated by the comparison of the tensile strength with puncture stress. The forces acting in the membrane wall of the matrix and the short-fiber reinforced rubber showed a similar data regardless of specimen size. And those increased with testing velocity at same specimen size. As the fiber AR increased the force acting in the wall at given fiber content also increased. Overall, it was found that the specimen size, testing velocity had an important effects on the puncture properties.

• Journal of the Society of Naval Architects of Korea
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• v.51 no.2
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• pp.114-121
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• 2014

Liquefied natural gas(LNG) cargo containment system(CCS) has the primary function of ensuring both adequate structural safety with respect to sloshing load which is defined as a violent behaviour of the liquid contents in CCS due to external forced motions and thermal insulation keeping natural gas below its boiling point. Among different LNG CCS types such as independent B-type and membrane ones, Mark III CCS is considered in this paper to perform its strength assessment. Mark III CCS plate is designed and constructed by stacking various non-metallic engineering materials such as plywood, triplex, reinforced PU foam that are supported by series of mastic upon inner steel hull structure. From the viewpoint of structural analysis, this plated structure is treated as a laminated composite structure showing complex structural behaviour under external load. Advanced finite element models of Mark III CCS plate is generated and used in conjunction with ultimate strength based failure criteria from laminated composite mechanics for the strength assessment. The strength assessment is performed within the initial failure state of Mark III CCS plate. Results provide failure details such as failure locations and loads. Finally obtained results are reviewed using the loads from acceptance criteria suggested by classification.

• Journal of Electrochemical Science and Technology
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• v.14 no.1
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• pp.85-95
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• 2023

In recent years, solid-state Li metal batteries (SSLBs) have attracted significant attention as the next-generation batteries with high energy and power densities. However, uncontrolled dendrite growth and the resulting pulverization of Li during repeated plating/stripping processes must be addressed for practical applications. Herein, we report a plastic-crystal-based polymer/ceramic composite solid electrolyte (PCCE) to resolve these issues. To fabricate the one-side ceramic-incorporated PCCE (CI-PCCE) film, a mixed precursor solution comprising plastic-crystal-based polymer (succinonitrile, SN) with garnet-structured ceramic (Li₇La₃Zr₂O₁₂, LLZO) particles was infused into a thin cellulose membrane, which was used as a mechanical framework, and subsequently solidified by using UV-irradiation. The CI-PCCE exhibited good flexibility and a high room-temperature ionic conductivity of over 10^-3 S cm^-1. The Li symmetric cell assembled with CI-PCCE provided enhanced durability against Li dendrite penetration through the solid electrolyte (SE) layer than those with LLZO-free PCCEs and exhibited long-term cycling stability (over 200 h) for Li plating/stripping. The enhanced Li⁺ transference number and lower interfacial resistance of CI-PCCE indicate that the ceramic-polymer composite layer in contact with the Li anode enabled the uniform distribution of Li⁺ flux at the interface between the Li metal and CI-PCCE, thereby promoting uniform Li plating/stripping. Consequently, the Li//LiFePO₄ (LFP) full cell constructed with CI-PCCE demonstrated superior rate capability (~120 mAh g^-1 at 2 C) and stable cycle performance (80% after 100 cycles) than those with ceramic-free PCCE.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.3A
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• pp.457-464
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• 2006

Fiber-reinforced composite materials due to their high specific strength, high stiffness and light weight are becoming increasingly used in many engineering industry, especially in the aerospace, marin and civil, etc. In this paper, the buckling load and mode shapes of composite laminates with elliptical cross-section including transverse shear deformations are analyzed. For solving this problems, a versatile flat shell element has been developed by combining a membrane element with drilling degree-of-freedom and a plate bending element. Also, an improved shell element has been established by the combined use of the addition of enhanced assumed strain and the substitute shear strain fields. The combined influence of shell geometry and elliptical cross-sectional parameter, fiber angle, and lay-up on the buckling loads of elliptical cylinder is examined. The critical buckling loads and mode shapes analyzed here may serve as a benchmark for future investigations.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.3
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• pp.551-565
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• 2017

A spray-applied waterproofing membrane which consists of polymers has a relatively higher constructability and adhesion than the conventional sheet-type waterproofing materials. Additionally, the spray-applied waterproofing membrane generally shows a waterproofing ability as a composite structure with shotcrete or concrete lining. Because its purpose is waterproofing at the structure, structural effects were not well reported than waterproofing abilities. In this study, structural effects of the membrane-attached concrete lining were evaluated using 3-point bending test by the numerical method. From the analysis, a load-displacement behavior of the concrete lining and fracturing energy after yielding were compared with various conditions. Consequently, concrete lining with spray-applied waterproofing membrane shows higher flexural strength and fracturing energy than the single-layer concrete lining.

• Membrane Journal
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• v.24 no.6
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• pp.453-462
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• 2014

Thin film composite (TFC) polyamide (PA) membranes were prepared on polyester (PET) nonwoven reinforced polysulfone supports for forward osmosis (FO) processes. PSF (polysulfone) supports were prepared via the phase inversion process from PSF casting solutions in dimethyl formamide (DMF) solvents (19 wt%) by using a PET nonwoven (thickness of $100{\mu}m$) as a mechanical reinforcing material for reverse osmosis (RO) membrane. The PSF support from 19 wt% of DMF/PSF casting solution showed sponge-like morphology and asymmetric internal structure. To reduce the internal concentration polarization in FO operation, thin ($20{\mu}m$ of thickness) nonwoven-supported PSF supports were prepared by using PSF/DMF casting solution (9~19 wt%). A desirable support structure with a highly porous sponge-like morphology were achieved from the thin nonwoven-supported PSF layer prepared with 9~12 wt% casting solution. A crosslinked aromatic polyamide layer was fabricated on top of each support to form a TFC PA membrane. The tested sample from 12 wt% of DMF/PSF casting solution presented outstanding FO performance, almost 5.5 times higher water flux (24.3 LMH) with low reverse salt flux (RDF, 1.5 GMH) compared to a thick nonwoven rainforced membrane (4.5 LMH of flux and 3.47 GMH of RSF). By reducing the thickness of the nonwoven and optimizing PSF concentration of casting solution, the morphology of the prepared membranes were changed from a dense structure to a porous sponge structure in the boundary area between nonwoven and PET support layer.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.4
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• pp.262-270
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• 2021

Consumption of Liquefied Natural Gas (LNG) has increased due to environmental pollution; therefore, the need for LNG carriers can efficiently transport large quantities of LNG, is increased. In various types of LNG Cargo Containment System (CCS), Membrane-type MARK-III composed of composite materials is generally employed in the construction of an LNG carrier. Among composite materials in a Mark-III system, glass-fiber composites act as a secondary barrier to prevent the inner hull structure from leakage of LNG when the primary barrier is damaged. Nevertheless, several cases of damage to the secondary barriers have been reported and if damage occurs, LNG can flow into the inner hull structure, causing a brittle fracture. To prevent those problems, this study conducted the applicability assessment of composite material manufactured by bonding glass-fiber and aluminum with epoxy resin and increasing layer from three-ply (triplex) to five-ply (pentaplex). Tensile tests were performed in five temperature points (25, -20, -70, -120, and -170℃) considering temperature gradient in CCS. Scanning Electron Microscopy (SEM) and Coefficient of Thermal Expansion (CTE) analyses were carried out to evaluate the microstructure and thermos-mechanical properties of the pentaplex. The results showed epoxy resin and increasing layer number contributed to improving the mechanical properties over the whole temperature range.

• Polymer(Korea)
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• v.38 no.3
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• pp.293-298
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• 2014

We prepared hydrophilic porous supporters for the reinforced composite fuel cell membrane by radiation grafting of acrylonitrile (AN) and hydrophilic sodium allylsulfonate (SAS) into a porous polytetrafluoroethylene (PTFE) supporter. The physicochemical properties of the supporters prepared under various reaction conditions such as molar ratio of SAS/AN, monomer concentration, and irradiation dose were evaluated. FTIR was utilized to confirm the successful introduction of SAS/AN copolymer chains into the porous PTFE. The pores of the porous PTFE film were found to be decreased with an increase in the degree of grafting by using FE-SEM and gurley number. Furthermore, by analyzing the degree of grafting, contact angle, and TBO (toluidine blue O) uptake, the hydrophilicity of the prepared supporters was found to increase with an increase in the degree of grafting.

• Journal of the Korean Geosynthetics Society
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• v.16 no.4
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• pp.151-161
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• 2017

A TSL (Thin Spray-on Liner) has a higher initial strength and faster construction time than conventional cementitious shotcrete. Because of its high adhesion and tensile strength, the TSL reinforced concrete show a characteristic like composite materials. In this study, to consider an application to the conventional design method, ASD (allowable stress design), numerical study was used. In the numerical analysis, material and contact properties were adopt from previous studies. Then a thickness of concrete in the tunnel was evaluated with the TSL reinforced case by the ASD concept. In other words, bending compressive stress, bending tensile stress and shearing force of the concrete were considered to determine a thickness of concrete lining by the given boundary conditions. From the numerical analysis, there was no tendency to show by the ASD because the ASD is based on the elastic theory while the TSL typically contributes to reinforcement after yielding.