• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.994-1001
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• 2012

The Effects of operating variables on reactivity of two $CO_2$ absorbents (PKM1-SU and P4-600) for SEWGS process were investigated in a pressurized fluidized bed reactor. For both $CO_2$ absorbents, $CO_2$ sorption capacity decreased as the number of absorption-regeneration cycles increased. PKM1-SU absorbent represented higher $CO_2$ sorption capacity than that of P4-600 absorbent. However, P4-600 absorbent represented better performance than PKM1-SU absorbent from the view points of regeneration temperature and regeneration rate. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the steam concentration increased. However, $CO_2$ sorption capacity increased initially as the steam concentration increased from 5% to 10%, but maintained thereafter for P4-600 absorbent. For both $CO_2$ absorbents, $CO_2$ sorption capacity increased as the final regeneration temperature increased. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the pressure increased and the increment tendency was drastic at higher pressure than 15 bar.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.2
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• pp.191-200
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• 2011

A way to adsorptively remove indoor carbon dioxide at relatively lower concentration under ambient temperature was studied. A small lab-scale carbon dioxide adsorption and desorption reactors were prepared, and 5A and 13X zeolites were packed in this reactors to investigate their adsorption and desorption characteristics. The inflow carbon dioxide concentration was controlled to 5,000 ppm, relatively higher concentration found in indoor spaces with air quality problems, by diluting carbon dioxide with nitrogen gas. The flow rate was varied as 1~5 L/min, and the carbon dioxide concentration after this reactor was constantly monitored to examine the adsorption characteristics. It was found that 5A adsorbed more carbon dioxide than 13X. A lab-scale carbon dioxide desorption reactor was also prepared to investigate the desorption characteristics of zeolites, which is essential for the regeneration of used zeolites. The desorption temperature was varied as $25{\sim}200^{\circ}C$, and the desorption pressure was varied as 0.1~1.0 bar. Carbon dioxide desorbed better at higher temperature, and lower pressure. 5A could be regenerated more than three times by thermal desorption at $180^{\circ}C$. It is required to modify zeolites for higher adsorption and better regeneration performances.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.2
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• pp.644-650
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• 2021

This study characterized the reforming of methane with carbon dioxide, which is a major cause of global warming. The methane decomposition reaction with carbon dioxide was carried out using transition metal catalysts. The reactivity of tin was lower than that of a transition metal, such as nickel and iron. Most of the decomposition reaction occurred in the solid state. The melting point of tin is 505.03 K. Tin reacts in a liquid phase at the reaction temperature and has the advantage of separating carbon produced by the decomposition of methane from the liquid tin catalyst. Therefore, deactivation due to the deposition of carbon in the liquid tin can be prevented. Methane decomposition with carbon dioxide produced carbon monoxide and hydrogen. Ni was used to promote the catalyst performance and enhance the activity of the catalyst and lifetime. In this study, catalysts were synthesized using the excess wet impregnation method. The effect of the reaction temperature, space velocity was measured to calculate the activity of catalysts, such as the activation energy and regeneration of catalysts. The carbon-deposited tin catalyst regeneration temperature was 1023 K. The reactivity was improved using a nickel co-catalyst and a water supply.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.7
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• pp.329-334
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• 2014

This study indicated the possibility of energy regeneration from waste coolant heat, by using thermoelectric generation integrated with heat pipe. The internal combustion engine rejects more than 60% wasteful energy to the atmosphere by heat. The thermoelectric generator has recently been studied, to convert the energy from engine waste heat into electricity. For coolant waste heat recovery, a thermoelectric generator was investigated, to find out the possibility of vehicular application. Performance characteristics were conducted with various test conditions of coolant temperature, coolant mass flow rate, air temperature, and air velocity, with the thermoelectric generator installed either horizontally or vertically. Experimental results show that the electric power and conversion efficiency increases according to the temperature difference between the hot and cold side of the thermoelectric generator, and the coolant flow rate of the hot side heat exchanger. Performance improvement can be expected by optimizing the heat pipe design.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.25-30
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• 2003

Several desiccant cooling systems have been developed in terms of cost and performance. In this study a fin-tube exchanger has been used for liquid desiccant dehumidification system. This dehumidifier has been designed to study the absorption characteristic of the aqueous triethylene glycol(TEG) solution which has the flow range from 20 to 50 LPM. The dehumidifier performance characteristic of working factor variables such as inlet solution flow rate, air flow rate, solution concentration, solution temperature, brine temperature, air temperature and inlet air relative humidity has been analyzed. The result of this experiment can provide useful data for hybrid air conditioning system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.5
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• pp.413-421
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• 2014

Desiccant cooling system is an air conditioning system that uses evaporative cooler to cool air and it can perform cooling by using heat energy only without electrically charged cooler. Thus, it can solve many problems of present cooling system including the destruction of ozone layer due to the use of CFC[chloro fluoro carbon] affiliated refrigerants and increase of peak power during summer season. In this study, cooling performance and exergy analysis was conducted in order to increase efficiency of desiccant cooling system. Especially, using exergy analysis based on the second law of thermodynamics can resolve the issue related to system efficiency in a more fundamental way by analyzing the cause of exergy destruction both in whole system and each component. The purpose of this study is to evaluate COP[coefficient of performance], cooling capacity and exergy performance of desiccant cooling system incorporating a regenerative evaporative cooler in various regeneration temperature and outdoor air conditions.

• Journal of Environmental Science International
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• v.15 no.6
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• pp.579-586
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• 2006

The purposes of this paper were to monitor the temperature rising courses and spark discharge of the modified granular activated carbon (GAC) by microwave (MW) irradiation and to evaluate absorption of benzene. The GAC coated on $SiO_2$, boron, talc, ferrite was named as the modified GAC. Thermal and spark discharge measurement of virgin GAC and modifed GAC has been carried out using a MW device operating at 2450 MHz under various energy conditions. The results of this paper as follows. First, the modified GAC is more efficient than the virgin GAC in temperature control. Temperature gradient of the modified GAC is more lower than that of virgin GAC. The temperature gradient of GAC was observed in the following order : virgin GAC, Mn-Zn ferrite/GAC, Ni-Zn ferrite,/GAC, $SiO_2/GAC$, Boron/GAC, Talc/GAC. Second, the spark discharge of the modified GAC was diminished, compared with that of virgin GAC. Because of its excellent electrical insulating properties, the coating material prevents the spark discharge. Finally, the benzene adsorption capacity of the modified GAC decreased due to diminishing of adsorption site by the coating material. Considering the temperature gradient and spark discharge of GAC, the GAC coated $SiO_2$ would be appropriate absorbent under irradiation of MW.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.11
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• pp.965-974
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• 2009

This study evaluated the degradation efficiency of malodorous sulfurized-organic compounds by utilizing N- and Sdoped titanium dioxide under visible-light irradiation, and examined the catalyst deactivation and regeneration. Catalyst surface was characterized by employing Fourier-Transform-Infrared-Red (FTIR) spectra. The visible-light-driven photocatalysis techniques were able to efficiently degrade low-level dimethyl sulfide (DMS) and dimethyl disulfide (DMDS) with degradation efficiencies exceeding 97%, whereas they were not effective regarding the removal of high-level DMS and DMDS, with degradation efficiencies of 84 and 23% within 5 hrs of photocatalytic processes. As compared with DMS, DMDS which containes one more sulfur element revealed quick catalyst deactivation. Catalyst deactivation was confirmed by the equality between input and output concentrations of DMD or DMDS, the obsevation of no $CO_2$ generation during a photocatalytic process, and the FTIR spectrum peaks related with sulfur ion compounds, which are major byproducts formed on catalyst surfaces. The mineralization efficiency of DMS at 8 ppm, which was a peak value during a photocatalytic process, was calculated as 144%, exceeding 100%. The catalyst regenerated by high-temperature calcination exhibited higher catalyst recovery efficiency (53 and 58% for DMDS and DMS, respectively) as compared with dry-air and humid-air regeneration processes. However, even the calcined method was unable to totally regenerate deactivated catalysts.

• Journal of the Korean Chemical Society
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• v.54 no.2
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• pp.192-197
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• 2010

The spinel compound was obtained by the thermal decomposition of Zn-Co and Zn-Ni gel prepared by sol-gel method using oxalic acid as a chelating agent. The formation of spinel compound has been comfirmed by thermogravimetric analysis (TGA), x-ray powder diffraction (XRD) and infrared spectroscopy (IR). The particle size of 13 nm~16 nm was calculated by Scherrer's equation. The sol-gel method provides a practicable and effective route for the synthesis of the spinel compound at low temperature ($350^{\circ}C$). The kinetic parameters such as activation energy (Ea) and pre-exponential factor (A) for each compound were found by means of the Kissinger method and Arrhenius equation. The decomposition of spinel compound has an activation energy about 155 kJ/mol. Finally, the thermodynamic parameters (${\Delta}G^{\varphi}$, ${\Delta}H^{\varphi}$, ${\Delta}S^{\varphi}$) for decomposition of spinel compound was determined.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.154-156
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• 2008

A prototype of the desiccant cooling system with a regenerative evaporative cooler was built and tested for the performance evaluation. The regenerative evaporative cooler is to cool a stream of air using evaporative cooling effect without an inc6rease in the humidity ratio. It is comprised of multiple pairs of dry and wet channels and the evaporation water is supplied only to the wet channels. By redirecting a portion of the air flown out of the dry channel into the wet channel, the air can be cooled down to a temperature lower than its inlet wet-bulb temperature at the outlet end of the dry channels. Incorporating a regenerative evaporative cooler eliminates the need for deep dehumidification in the desiccant rotor that is necessary to achieve low air temperature in the system with a direct evaporative cooler. Subsequently, the regenerative evaporative cooler enables the use of low temperature heat source to regenerate the dehumidifier permitting the desiccant cooling system more beneficial compared with other thermal driven air conditioners. At the ARI condition with the regeneration temperature of $60^{\circ}C$, the prototype showed the cooling capacity of 4.4 kW and COP of 0.75.