• Proceedings of the SCSK Conference
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• 1999.10a
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• pp.65-74
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• 1999

We have studied the stability of W/O high internal phase emulsions(HIPE) containing water, cetyl dimethicone copolyol and oils varying magnesium sulfate in the range 0 to 0.5wt% and oil polarities, respectively. The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The greater the increase of concentrated modulus was, the less coalescence occurred and the more consistent the concentrated emulsions were. The increasing pattern of complex modulus versus volume fraction has been explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsion. The stability is dependent on: (i) the choice of the oil is important, the requirements coincide with the requirements for the formation of the rigid liquid crystalline phases :5; and (ii) addition of salts the aqueous phase opposes the instability due to coalescence:. Increasing the salt concentration increases the refractive index of the aqueous phase. It lowers the difference in the refractive index between the oil and aqueous phases. This decreases the attraction between the water domains, thus increasing the stability.

• Korean Journal of Optics and Photonics
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• v.2 no.1
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• pp.7-12
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• 1991

A nondestructive technique for measuring the refractive index of a simple lens is described. The shearing interferornetric technique is used for determining the focal length of a lens by immersing it in various liquids. The lens itself acts as autocollimator and decollimator. An equation for the defocusing error has been theoretically deduced and experimentally verified. The wave aberration has also been investigated for the different values of the focal length.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.350.2-350.2
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• 2014

We investigated the structural and optical evolution of Ga2O3 thin films on glass substrates deposited using radio frequency magnetron sputtering. Initially, amorphous Ga2O3 thin film is grown, and then, surface humps and nanowire (NW) bundles are gradually formed as the film thickness increases. The surface humps are Ga-rich and provide nucleation sites for NWs through a self-catalytic vapor-liquid-solid mechanism with self-assembled Ga droplets. Both the surface humps and the NWs induce variation of the optical properties such as the optical bandgap and refractive index by absorbing light in the ultraviolet region.

• Bulletin of the Korean Chemical Society
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• v.26 no.6
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• pp.947-951
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• 2005

Rotating compensator multichannel spectroscopic ellipsometry has been employed to determine the optical functions of various liquids used in chemistry. We attempted three different measurement configurations: (1) air-liquid interface, (2) prism-liquid interface, and (3) liquid-sample interface. In prism-liquid interface, we found that the prism surface had roughness and it should be considered in analysis for accurate results. In liquidsample interface, we had much higher reflection, better sensitivity, and less limitation compared to the other two configurations when crystalline silicon was used as reference sample. We discuss the merit of each configuration and present the optical functions of various liquids. Also we demonstrate Bruggeman effective medium theory to determine the optical properties of mixed liquid.

• Journal of Korean Ophthalmic Optics Society
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• v.13 no.3
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• pp.1-6
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• 2008

Purpose: Plastic optical monomer materials having ultra high refractive index have an income of the whole quantity from advanced nations to domestic companies which are related to plastic optical lens. It is necessary to develop novel plastic optical lens materials in order to overcome a FTA provision and revitalize a stagnating optical lens industry in the interior optical lens industries. The new plastic optical lens materials against the substitution effect of income should be gradually demanded. This work will be synthesized novel super high refractive monomer resin materials of urethane lens series and studied the properties of optical lens using it. Methods: ETS-4 (2-(2-mercaptoethylthio)-3-{2-[3-mercapto-2-(2-mercaptoethylthio)propyl thio]ethylthio}propane -1-thiol), which is optical lens monomer resin having super high refractive index, was synthesized and identified its structure and property by elemental analysis, EI-MS, TGA, FT-IR spectroscopy, $^1H$ and $^{13}C$ NMR spectroscopies. After mixing evenly from mixed monomer resin and diisocyanate series, it was casting in glass mold. After thermal curing, the obtained optical lenses were measured and compared with the refractive index and Abbe number for studies of their optical properties. Results: We have synthesized the novel ultra high refractive index monomer resin, ETS-4, and have identified its structure and property by elemental analysis, EI-MS, TGA, FT-IR spectroscopy, $^1H$ and $^{13}C$ NMR spectroscopies. The existence of three isomers for EST-4 was identified by $^{13}C$ NMR spectroscopy. The refractive index ($N_d$ at $25^{\circ}C$) of monomer resin in liquid state obtained from the Abbe refractometer was 1.647. The refractive indexes of raw plastic optical lenses prepared from the mixed ETS-4 monomer and diisocyanate series were in the range of 1.656~1.680. Conclusions: Novel super high refractive index plastic optical lens monomer was synthesized and analysed, the optical lenses prepared using it were colorless transparency and excellent properties. It is of utility for the industrialization.

• Proceedings of the Optical Society of Korea Conference
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• 2009.02a
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• pp.507-508
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• 2009

We have proposed and demonstrated noncontact refractometer incorporating a fiber bundle. The fiber bundle is composed of a TEC(thermally expended core) fiber and hundreds multimode fibers. The fiber is designed in such a way that the detected reflected optical power from a liquid is constant against the distance between fiber bundle and liquid surface. Low differactive characteristic of TEC fiber make it possible to increase the available distance between the fiber bundle and liquid surface, The obtained sensitivity, optical intensity variation by change of refractive index of liquid is 0.4.

• Korean Journal of Optics and Photonics
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• v.19 no.3
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• pp.182-186
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• 2008

The prism spectrometer is a standard device for the measurement of refractive index; it is used in undergraduate laboratories. Typically, however, lots of attention is required in the alignment, and the accuracy of the obtained refractive index is not so high in spite of the durability of the device. The maximum and minimum deviation method, which compensates the disadvantages of the prism spectrometer, can be composed cost effectively using a length marking tape and a rotating platform. It can measure the refractive indices accurately by utilizing a wide screen. In this study, the equal sided hollow prism whose length is 26 mm was fabricated and measured the refractive indices of seven kind of liquids (pure water, $C_3H_5(OH)_2$, $CCl_4$, $C_6H_4NH_2$, $CS_2$, $C_6H_4(CH_3)_2)$ by using the prism spectrometer and maximum and minimum deviated laser beam method at the wavelengths of He-Ne laser (${\lambda}$= 632.8 nm) and YVO4 laser (${\lambda}$= 532 nm). The result shows that the data obtained by the latter method are more accurate and precise than those obtained by the former device.

• Analytical Science and Technology
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• v.8 no.4
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• pp.457-460
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• 1995

A new hollow fiber filled with the lower refractive index liquid as core constructs a liquid core optical fiber(LCOF). The LCOF have been used as colorimetric cell to determine elements Cr and Cu in the presence of 70%- 50% ethanol or 50% dioxane aqueous solution, based on colored complex of Chromium(VI) with Diphenycarbazid(DPC) and copper with Chromaurd S(CAS) respectively. The sensitivity (1/ng/ml) of calibration curve of Cr and Cu are 0.052, 0.017 over the range 0 - 25, 0 - 24(ng/ml) respectively. The Cr in the animal gum and Nation Standard of China are determined with recoveries of 94 - 102%.

• Korean Journal of Optics and Photonics
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• v.24 no.6
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• pp.318-323
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• 2013

Digital holographic microscopy allows optical path difference measurement. Optical path difference depends on both the refractive index and the morphology of the sample. When interference fringes are very closely spaced, the phase data contain high frequencies where $2{\pi}$ ambiguities cannot be resolved. The immersion testing method, which is a transmission test while the sample is immersed in liquid, is very effective in reducing high frequency fringes in transmission measurements so that large dynamic range testing is possible for a non-null configuration. We developed a digital holographic microscope using liquid that can measure the high numerical aperture aspheric morphology of a sample. This system provides highly precise three-dimensional information on the sample. By improving the experimental method, choosing liquids which have similar refractive index to the sample, we can measure more accurate three-dimensional information on the samples.

• Journal of the Optical Society of Korea
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• v.17 no.5
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• pp.423-427
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• 2013

We present the preparation and characteristics of liquid-phase sensors based on nano-porous silicon multilayer structures for determination of organic content in gasoline. The principle of the sensor is a determination of the cavity-resonant wavelength shift caused by refractive index change of the nano-porous silicon multilayer cavity due to the interaction with liquids. We use the transfer matrix method (TMM) for the design and prediction of characteristics of microcavity sensors based on nano-porous silicon multilayer structures. The preparation process of the nano-porous silicon microcavity is based on electrochemical etching of single-crystal silicon substrates, which can exactly control the porosity and thickness of the porous silicon layers. The basic characteristics of sensors obtained by experimental measurements of the different liquids with known refractive indices are in good agreement with simulation calculations. The reversibility of liquid-phase sensors is confirmed by fast complete evaporation of organic solvents using a low vacuum pump. The nano-porous silicon microcavity sensors can be used to determine different kinds of organic fuel mixtures such as bio-fuel (E5), A92 added ethanol and methanol of different concentrations up to 15%.