• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2494-2498
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• 2012

Preparation of several new spirocyclic mercapto derivatives is described. Thiol protection on multi-carbonyl compounds allows of high sulfur content necessary to induce high refractive index. Condensation of 1,3-dimercapto-2-propanol and cyclohexanone followed by successive oxidation and thioacetalization affords a dispirocycle with four sulfurs. Selective S,S-protection of cyclohexane-1,4-dione is achieved with 1,3-dimercapto-2-propanol and 2,3-dimercapto-1-propanol to provide dispirocycles with four sulfurs. Olefine-oxidation of norbornene gives a useful dialdehyde intermediate which is transformed to 1,3-dithiolane for a linearly-bound-cyclic molecule. Refractive index of linearly-bound-cycles was below 1.60 and dispirocycles exhibited high refractive index of 1.57-1.69.

• 한국세라믹학회지
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• 제46권1호
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• pp.10-15
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• 2009

We have fabricated silicon-rich silica thin films via RF magnetron sputtering using a SiO target. Thickness evolution and microstructure change of such $SiO_x$ (1$SiO_x$ thin films turned out to be mainly responsible for the increase of refractive index.

• Korean Chemical Engineering Research
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• 제59권4호
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• pp.644-651
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• 2021

Alkyl amines are widely used in various industries. Nowadays these are also used in CO₂ capture technology because amines react with CO₂ and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The 𝚫n values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (𝚫n) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.120-123
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• 2002

In this study it had an excellent optical characteristic, it followed in the creation rate and the refractive index regulation to the ease. Chalcogenide produced the $As_{45}Se_{45}Te_{10}$ thin film and the $MgF_{2}$ thin film. It measured thin film plan simulation, and the thin film has a 1 -dimensional photonic band gap. The chalcogenide $As_{45}Se_{45}Te_{10}$ thin film was measured with the fact that it has a high refractive index (2.6~2.9). The $As_{45}Se_{45}Te_{10}$ and $MgF_{2}$ thin film, have a high refractive index and a low refractive index, it used a simulation and planed period 5-pairs structure, the result was from 500nm to 800nm. It will be able to confirm the characteristic which most of the incidence light reflects, the He-Ne (632.8nm) laser was irradiated in the thin film which stabilized the thin film. $As_{45}Se_{45}Te_{10}$ (high refractive index layer: H) and $MgF_{2}$ (low refractive index layer: L) results which plans the thin film with glass/LHLHLLHLHL/air structure, 632.8nm against transmitance, increased a lot. An application possibility with the filter against a specific wave length was confirmed.

• 한국안광학회지
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• 제5권2호
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• pp.151-155
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• 2000

칼라 렌즈 제작시 착색 시간에 따른 분광반사율을 측정하여 렌즈표면의 굴절률을 계산하였다. 착색 시간이 길수록 반사율과 굴절률은 커진다. 렌즈 표면에 착색물질이 포화상태가 될 때까지 굴절률은 시간에 따라 증가하였다. 시간에 따른 blue color 렌즈의 굴절률 변화 곡선은 Boltzmann 성장곡선을 따르며, 이때 $n_{min}$은 1.482. $n_{max}$는 1.497. $t_c=11.53$ 그리고 $d_0$ 등의 2.287 등의 parameter 값을 얻었다.

• 조명전기설비학회논문지
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• 제29권3호
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• pp.39-44
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• 2015

Optical characteristics including the radiant flux and viewing angle of UV LEDs were investigated according to both silicone encapsulants with different refractive indexes and lens shapes. Lead frame was fabricated using the enhanced heat dissipation characteristics with a heat slug structure and the reflector based on EMC(Epoxy Mold Compound) material. Four types of lens shapes were designed and their optical characteristics depending on the refractive index of silicone encapsulants were evaluated. The maximum radiant flux can be achieved when the height of lens are 1.32mm and 1.08mm for silicone encapsulants with low and high refractive indexes, respectively. Depending on the encapsulating method, the viewing angle changes from $148.9^{\circ}$ to $130.2^{\circ}$ for low refractive index and from $145.3^{\circ}$ to $136.8^{\circ}$ for high refractive index. As a result, it is found that the optical characteristics of UV LEDs can be controled through both encapsulating method and the refractive index of encapsulants.

• 폴리머
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• 제34권6호
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• pp.588-593
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• 2010

실리콘, 게르마늄, 주석이 결합된 7개의 아크릴 단량체가 개발되었고 이를 광경화시킨 필름의 굴절률을 측정하였다. 공단량체로 가교도가 높은 triacrylate(Trimer)를 사용하여 형성된 공중합체의 굴절률로부터 단일중합체의 굴절률을 계산하였다. 공유 결합된 $Ph_3Si$, $Ph_3Ge$, $Ph_3Sn$은 각각 아크릴 고분자 필름의 굴절률을 향상시키는데 기여하였고 주석이 게르마늄에 비해 약간 높은 기여도로 나타났다. 주석에 의한 굴절률 향상 효과는 $Bu_3Sn$을 도입한 결과와 aliphatic acrylate의 비교로 보다 명확하게 입증되었다. 주석과 황의 안정된 결합을 이용하여 $Ph_3SnS$가 도입된 아크릴 고분자의 굴절률은 589 nm에서 1.671로 높게 측정되었다. 측정 파장으로 656, 830, 1310, 1550 nm에서도 비슷한 굴절률이 관찰되었다.

• 설비공학논문집
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• 제19권8호
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• pp.599-606
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• 2007

An experimental study was performed to measure a ice concentration of ice slurry flowing in a pipe in a real time. In the present paper, we suggested a measuring method by a refractive index and compared it to other methods by a freezing point and a density. To measure the refractive index of the solution, ice particles in the ice slurry should be completely removed and a hydro-cyclone was introduced instead of a mesh. The measuring method through the refractive index coincided with the density method using the real-time solution density within ${\pm}5%$ error range, having the error range less than the other two methods. In the other hand, the measuring method through the density has a good resolution, but the result using the initial density of the solution was different more than 10% error from that using the real-time density. And it has an error range 1.5 times greater than the method through the refractive index.

• 폴리머
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• 제33권5호
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• pp.413-419
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• 2009

프리즘 시트의 프리즘 층 물질의 굴절률을 증가시킬수록 휘도가 향상되어 LCD 백라이트 유닛의 효율이 향상되었다. 프리즘 층의 굴절률을 증가시키기 위해서 방향족을 포함하고 있는 고굴절 물질과 다관능성 반응물을 혼합하여 자외선 경화형 수지를 제조하였다. 9,9-Bis [4-(2-acryloyloxyethoxy)phenyl] fluorene을 반응시켜 프리즘층의 도막 굴절률을 1.58까지 증가시켰고 백라이트의 휘도를 향상시킬 수 있었다. 백라이트 유닛에 사용되는 광원에 장기간 노출될 경우 프리즘 시트에 황변현상이 발생하게 되어 휘도가 감소되므로 자외선 안정제로 hindered amine light stabilizer를 사용하여 프리즘 시트의 내황변성을 크게 향상시켰다.

• 한국광학회지
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• 제7권4호
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• pp.357-362
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• 1996

스핀 코팅으로 제작한 MNA/PMMA 고분자박막의 두께 및 굴절율과 소광계수를 결정하였다. 타원해석 스펙트럼을 분석하여 박막의 두께 및 투과영역에서의 굴절율을 결정하고 광흡수 스펙트럼으로부터 흡수영역에서의 소광계수 스펙트럼을 역방계산하였다. 이 소광계수 스펙트럼을 가장 잘 나타내는 고전적 Lorentz 진동자 상수들과 양자역학적 진동자 상수들을 각각 구하고 이들 진동자에 의한 복소굴절율 스펙트럼들을 비교하였다. 이 방법은 대부분의 고분자박막의 두께 및 굴절율과 소광계수 스펙트럼을 구하는데 적용될 수 있으며 고분자박막의 광학적 특성을 규정짓는데 매우 유용하게 사용될 수 있겠다.