Browse > Article

Synthesis of Polyacrylates Containing Si, Ge and Sn for High Refractive Index  

Maheswara, Muchchintala (Department of Chemistry Education, Pusan National University)
Do, Jung-Yun (Department of Chemistry Education, Pusan National University)
Publication Information
Polymer(Korea) / v.34, no.6, 2010 , pp. 588-593 More about this Journal
Abstract
New seven acrylic monomers with covalently bonded silicon, germanium, and tin were prepared for high refractive index materials. The monomers were copolymerized with a cross-linkable comonomer (Trimer) to prepare UV-films for optical characterization. The refractive index of the copolymers increased in proportion to the monomer content and extrapolated to determine that of homopolymer. $Ph_3Si$, $Ph_3Ge$, and $Ph_3Sn$ groups contributed to increase the refractive index of acrylic polymer, in which $Ph_3Sn$ was more effective than $Ph_3Ge$. The index increment confidently occurred with $Bu_3Sn$ attachment in comparison with aliphatic acrylic polymers. $Ph_3SnS$-attached acrylate polymer showed a refractive index of 1.671 at 589 nm. The index change was similarly observed at various different wavelengths (656, 830, 1310, and 1550 nm).
Keywords
high refractive index; germanium and tin attached acrylate; $Ph_3SnS$-acrylate; acrylic polymer film; UV-polymerization;
Citations & Related Records

Times Cited By Web Of Science : 0  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
  • Reference
1 R. H. Allcock, J. D. Bender, and Y. Chang, Chem. Mater., 15, 473 (2003).   DOI   ScienceOn
2 A. Nebioglu, J. A. Leon, and I. V. Khudyakov, Ind. Eng. Chem. Res., 47, 2155 (2008).   DOI   ScienceOn
3 M. Maheswara, M. Kim, S. J. Yun, J. J. Ju, and J. Y. Do, Tetrahedron Lett., 50, 480 (2009).   DOI   ScienceOn
4 S. D. Mandolesi, L. C. Koll, A. B. Chopa, and J. C. Podesta, J. Organomet. Chem., 555, 151 (1998).   DOI   ScienceOn
5 J. Y. Kwon, B G. Kim, J. Y. Do, J. J. Ju, and S. K. Park, Macromol. Res., 15, 533 (2007).   DOI   ScienceOn
6 J. H. Moon, Y. G. Shul, H. S. Han, S. Y. Hong, Y. S. Choi, and H. T. Kim, Int. J. Adhes. Adhes., 25, 301 (2005).   DOI   ScienceOn
7 T. Ishigure, S. Tanaka, E. Kobayashi, and Y. Koik, Journal of Lightwave Technology, 20, 1449 (2002).   DOI   ScienceOn
8 C. C. Teng, Appl. Opt., 32, 1051 (1993).   DOI   ScienceOn
9 M. Zhou, Optical Engineering, 41, 1631 (2002).   DOI   ScienceOn
10 J. J. Ju, J. Kim, J. Y. Do, M. Kim, S. K. Park, S. Park, and M. H. Lee, Optics Letters, 29, 89 (2004).   DOI   ScienceOn
11 Polymer Blends Handbook, L. A. Utracki, Editor, Springer-Verlag, Vol. 1-2 (2002).
12 Q. Dai, D. Berman, K. Virwani, J. Frommer, P. O. Jubert, M. Lam, T. Topuria, W. Imaino, and A. Nelson, Nano Lett., 10, 3216 (2010).   DOI   ScienceOn
13 H. K. Shobha, H. Johnson, M. Sankarapandian, Y. S. Kim, P. Rangarajan, D. G. Baird, and J. E. Mcgrath, J. Polym. Sci. Part A: Polym. Chem., 39, 2904 (2001)   DOI   ScienceOn
14 T. Flaim, Y. Wang, and R. Mercado, Proceedings of SPIE: Optical Systems Design, 5250, 423 (2003).
15 J. Gonzalo, O. Sanz, A. Perea, J. M. Fernandez-navarro, C. N. Afonso, and J. Garcialopez, Appl. Phys. A, 76, 943 (2003)   DOI   ScienceOn
16 T. Otsuka and Y. Chujo, Polym. J., 42, 58 (2010).   DOI
17 W. Groh and A. Zimmermann, Macromolecules, 24, 6660 (1991).   DOI
18 J. Liang, E. Toussaere, R. Hierle, R. Levenson, J. Zyss, A. V. Ochs, A. Rousseau, and B. Boutevin, Opt. Mater., 9, 230 (1998).   DOI   ScienceOn
19 P. Chhabra, R. Gupta, G. Suri, M. Tyagi, G. Seshadri, S. Sabharwal, U. K. Niyogi, and R. K. Khandal, International Journal of Polymer Science 2009 (2009), 906904, doi:10.1155/2009/906904.