• Title/Summary/Keyword: Reference gas

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Trends and Prospects for information standards of chemical process plants (화학 공정 플랜트 정보 표준의 동향 및 전망)

  • Suh, Min-ho;Yoo, Jaeyoung
    • Proceedings of the Korea Contents Association Conference
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    • 2007.11a
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    • pp.487-489
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    • 2007
  • In this paper chemical process plant information is addressed to be standardized. The chemical process plant information has complexities in the context of its various types such as functions, shapes, connectivity etc. as well as its usages such as design, construction, operation, maintenance and so on. It was well known that the standard should be made by its users themselves to be used widely. The chemical process industry oriented ISO 15926 RDL (Systems and integration of life-cycle data for oil and gas production facilities : Reference Data Library) can provide the methodology for exchanging and sharing of plant equipment information, which will be developed through integrating existing standards such as ISO 10303 AP221, AP231, AP227. The PCA (Posc Caesar Association) which is located in Oslo, Norway, has the initiative in developing ISO 15926. Korea is a member of PCA and takes part in proposing and reviewing the new standard. The trends and prospects for the standard of chemical process plant information are addressed.

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Analysis of Automotive Paints using Pyrolysis-Gas Chromatography (열분해-가스크로마토그라피에 의한 자동차 페인트 분석)

  • Shon, Sung-Kun;Park, Ha-Sun;Lee, Jin-Sook;Hong, Sung-Wook;Park, Sung-Woo;Cho, Sung-Hye
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.101-107
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    • 2000
  • The automotive paints could be generally differentiated by color, layer sequence and chemistry of the paint layers comprising each of the topcoat and the primer system. The successful identification of hit-andrun a and traffic accidental vehicles from evidential paint fiagments is greatly facilitated with a comprehensive laboratory collection of reference paint samples and the technique for direct analysis without sample preparation. The Pyrolysis-Gas Chromatography(PGC) is a precise and reliable method for performing both quantitative and qualitative analysis of polymeric materials and forensic samples. Our Forensic Laboratory is conducting the examination and identification of 73 reference paint samples; 4 colors of each domestic automotive make that is popular in Korea, by Curie Point Pyrolyzer(JHP-3) and GC with capillary column(ultra alloy-5). This method can be used not only to compare paint traces with their suspected sources, but also to identify the type, make and model of the automotive car.

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An Analytical Study of Geologic Characteristics and Production- Related Problems of Beep Natural Gas Resources (심부 천연가스의 지질학절 부존 환경 특성과 생산관련 현안 문제점 분석 연구)

  • Chang Seungyong
    • 한국석유지질학회:학술대회논문집
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    • autumn
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    • pp.28-46
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    • 2001
  • Natural gas is a mixture of hydrocarbon gases and impurities such as nitrogen, hydrogen sulfide, and carbon dioxide and a clean energy producing no pollution materials for combustion. Currently, the demand of the natural gas is rapidly increasing due to worldwide environmental problems. According to Hubbert's study in the past, the natural gas was predicted as rapidly depleted resources, and then the results led to high gas price and limitation of usage during 1980s. Afterward, the study of natural gas resources based on geology identified the additional natural gas resources that were not considered in Hubbert's study. They are unconventional gas, additional resources in the existed reservoirs, and natural gas in deep subsurface areas. Such additional resouces made the future of natural gas bright and pormised low and stable gas price in the future. Deep natural gas is defined as the gas existing at or below 15,000ft$(4,752{\cal}m)$ in depth from the surface. According to the study from the U.S. Geological Survey(USGS) in 1995, 1,412 TCF of technically recoverable natural gas was remained to be discovered or developed in the onshore of United States. A significant part of that resource base, 114 TCF, exists at deep sedimentary basins, and it shows wide distribution with various geological environments. In 1995, the deep gas contributed to $6.7\% of total supply amount of natural gas in the United States and is expected to be $18.7\% by 201.5. However, the development of the deep gas is a high risky business due to expensive investment and high portion of dry holes, although it is developed. Thus, for developing the deep gas economically, it is necessary to overcome many technical challenges. In this paper, for increasing success rate of the deep gas, 1) geologic and compositional characteristics, and production cost have been analyzed according to depth, 2) technical problems related to deep gas production have been summarized, and 3) finally future study areas for increasing application of the deep gas have been suggested. For reference, this paper was written based on the study results from USGS and Gas Research Institute(GRI), for the United States is doing the most active R&D in the deep gas area, and thus, has many reliable data.

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A Study of Hydrogen Embrittlement on a Material of CNG Storage Tank (CNG 저장용기 재료의 수소취성에 관한 연구)

  • Han, J.O.;Lee, Y.C.;Lee, J.S.;Chae, J.M.;Hong, S.H.
    • Journal of the Korean Institute of Gas
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    • v.15 no.2
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    • pp.9-14
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    • 2011
  • A set of test was conducted on a SA-372 steel for CNG storage tank to study the effect of hydrogen embrittlement. Tensile tests were carried out several conditions such as CNG, HCNG and H2 gas environment including air and Ar under the 35 MPa. Also, the test speed was set at 4*10^-4/s and 4*10^-5/s respectively. To maintain the high pressure for environmental gas during test process, we chose MTS which was installed autoclave. Test results showed that tensile stress, elongation rate and cross sectional contraction under Ar and CNG charging condition were similar to that of reference of air. And there was little bit change with test speed variations. However, hydrogen added conditions such as HCNG and H2 were revealed noticeable change in elongation rate and cross sectional contraction. Tensile stress was still uniform for all conditions. From the results, the effect of hydrogen embrittlement was confirmed on the hydrogen enriched conditions. Also its effect was showed more strong with much hydrogen concentration and slower test speed.

A Study on the Emission and Particulate Matter of a Heavy Duty Natural Gas Engine According to Gas Composition under certification tests (인증시험 조건에서 가스조성 변화에 따른 대형 천연가스 엔진 배기가스 및 입자상 물질 배출 특성에 관한 연구)

  • Choi, Ji-Seon;Park, Cheol-Woong;Jang, Hyoung-Jun;Kim, Chang-Gi
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.66-73
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    • 2021
  • In this study, The full load test and WHTC mode test were performed to examine the effect on a heavy duty natural gas engine according to the type of standard gas for certification to check engine performance and exhaust characteristics. Two types of standard gas (Gr, G23) and commercially available natural gas were applied as the fuel used. As a result of the test results of three natural gases with different fuel compositions, G23 with a high nitrogen content was inferior in torque, fuel consumption, and thermal efficiency conditions. In addition, when evaluated in the WHTC mode it was possible to obtain a result that satisfies the EURO VI regulation. However, compared to the other two fuels, the emission characteristics of G23 decreased CO2 and CO, but increased CH4, NOx and PN emissions.

Catalytic combustion type hydrogen gas sensor using TiO2 and UV LED (TiO2 광촉매와 UV LED를 이용한 접촉연소식 수소센서)

  • Hong, Dae-Ung;Han, Chi-Hwan;Han, Sang-Do;Gwak, Ji-Hye;Lee, Sang-Yeol
    • Journal of Sensor Science and Technology
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    • v.16 no.1
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    • pp.7-10
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    • 2007
  • A thick film catalytic gas sensors which can be operated at $142^{\circ}C$ in presence of ultra violet-light emitting diode has been developed to measure hydrogen concentration in 0-5 % range. The sensing material as a combustion catalyst consists of $TiO_{2}$ (5 wt%) and Pd/Pt (20 wt%) supported on $Al_{2}O_{3}$ powder and the reference material to compensate the heat capacity of it in a bridge circuit was an catalyst free $Al_{2}O_{3}$ powder. Platinum heater and sensor materials were formed on the alumina plate by screen printing method and heat treatment. The effect of UV radiation in the presence of photo catalyst $TiO_{2}$ on the sensor sensitivity, response and recovery time has been investigated. The reduction of operating temperature from $192^{\circ}C$ to $142^{\circ}C$ for hydrogen gas sensing property in presence of UV radiation is attributed to the hydroxy radical and superoxide which was formed at the surface of $TiO_{2}$ under UV radiation.

NMHCs measurement using a cryogenic concentration system and application on gas samples (저온농축장치를 이용한 NMHCs의 측정법과 가스 시료에 적용)

  • Kim, Su Ha;Moon, Dong Min;Kim, Jin Seog
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.375-381
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    • 2012
  • In this study, we have developed a cryogenic concentration system for the analysis of non-methane hydrocarbons (NMHCs) in air sample. NMHCs with nmol/mol level of concentrations in the atmosphere were quantified by a comparative method with certified reference gas mixture. GC/FID with cryogenic concentration system operated in the range from $-67^{\circ}C$ to $180^{\circ}C$ was adopted. After cryogenic concentration, a fast desorption by heating could achieve a large amount of sample injection into the GC/FID. The linearity of the system was verified with the peak areas of NMHCs of the concentration amount of sample. The reproducibility is less than 10% and the limit of detection (LOD) is 0.1 nmol/mol. For the application of this system, we analyzed NMHCs in gas samples taken from air and soil in Daejeon, Seosan and Goheung.

Ejector Optimization for SOFC Anode Off-Gas Recirculation System (SOFC 산화전극 배기가스 순환 시스템을 위한 이젝터 최적 설계)

  • Jo, Sung Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.2
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    • pp.139-148
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    • 2013
  • In this study, an ejector was designed to recirculate the anodic off-gas of SOFC, and a parametric study of the system performance was conducted at various ejector entrainment ratios. Aspen Plus, a chemical engineering program, was used to calculate the operational conditions of the ejector. To minimize the calculation load of the CFD and to ensure the global optimum, a genetic algorithm and Kriging model were used for the optimization. The optimization results showed that the dominant design variables of the sonic ejector are the throat diameter and the first flow nozzle position. The designed ejector has enough flexibility for different operating conditions of a 1-kW SOFC system. When the ejector was applied to the SOFC, it reduced 56% of the steam and 8.4% of the fuel compared to the reference case.

Evaluation of the Shock Resistance of a Gas Turbine Package (가스터빈 패키지 내충격 성능평가에 관한 연구)

  • Kim, Jae Boo;Park, Yun Ki;Park, Min Seok;Lee, Jong Hwan;An, Sung Chan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.10
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    • pp.1005-1009
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    • 2017
  • In this study, the shock resistance of a gas turbine package subjected to a shock load caused by non-contact underwater explosion was investigated using numerical analysis. To perform shock analysis, the time-history shock load was calculated according to BV-043 (German Navy Regulation). The direct transient response analysis in the time domain for the simplified Whole Engine Model (WEM) was performed using the calculated shock load. In addition, the structural integrity of a detailed model was evaluated by considering the shock load transferred to each component. As a result, it was confirmed that the safety factor was at least 1.0 as compared with the reference stress. Finally, the structural and functional integrity of the Engine Management System (EMS) of the gas turbine package was verified through an actual shock test.

Study on Calibration Methods of Discharge Coefficient of Sonic Nozzles using Constant Volume Flow Meter

  • Jeong, Wan-Seop;Sin, Jin-Hyeon;Gang, Sang-Baek;Park, Gyeong-Am;Im, Jong-Yeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.17-17
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    • 2010
  • This paper address technical issues in calibrating discharge coefficients of sonic nozzles used to measure the volume flow rate of low vacuum dry pumps. The first challenging issue comes from the technical limit that their calibration results available from the flow measurement standard laboratories do not fully cover the low vacuum measurement range although the use of sonic nozzles for precision measurement of gas flow has been well established in NMIs. The second is to make an ultra low flow sonic nozzlesufficient to measure the throughput range of 0.01 mbar-l/s. Those small-sized sonic nozzles do not only achieve the noble stability and repeatability of gas flow but also minimize effects of the fluctuation of down stream pressures for the measurement of the volume flow rate of vacuum pumps. These distinctive properties of sonic nozzles are exploited to measure the pumping speed of low vacuum dry pumps widely used in the vacuum-related academic and industrial sectors. Sonic nozzles have been standard devices for measurement of steady state gas flow, as recommended in ISO 9300. This paper introduces two small-sized sonic nozzles of diameter 0.03 mm and 0.2 mm precisely machined according to ISO 9300. The constant volume flow meter (CVFM) readily set up in the Vacuum center of KRISS was used to calibrate the discharge coefficients of the machined nozzles. The calibration results were shown to determine them within the 3% measurement uncertainty. Calibrated sonic nozzles were found to be applicable for precision measurement of steady state gas flow in the vacuum process. Both calibrated sonic nozzles are demonstrated to provide the precision measurement of the volume flow rate of the dry vacuum pump within one percent difference in reference to CVFM. Calibrated sonic nozzles are applied to a new 'in-situ and in-field' equipment designed to measure the volume flow rate of low vacuum dry pumps in the semiconductor and flat display processes.

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