• Journal of the Korean Institute of Gas
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• v.21 no.6
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• pp.1-7
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• 2017

This study is aimed to investigate the US code and European code on the evaluation of fuel economy of natural gas vehicles and deduce the formula suitable for domestic natural gas fuel. The fuel consumption formula have been derived by carbon balance relation between fuel composition and exhaust emission. The US code does not limit the composition of the test gas, but European code should be used the reference gases such as G20 and G23. In the case of NGV using domestic city gas, it is confirmed that the fuel economy determined by European code is 12% worse than that of US code because of difference of test gas. Also, a method of determining the fuel properties from the calorific value is proposed to evaluate the fuel economy of natural gas vehicles.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.28-36
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• 2013

The underground coal which is buried in the ground will have a lot of attention to overcome energy crisis as an energy resources standpoint. Many studies of underground coal gasification have been also conducted because of its advantage which does not require mining. In this study, the simulation of underground coal gasification process was carried out with Aspen Plus. This study was executed by Rock Mountain 1 Underground Coal Gasification project in the United States in the late 1980s as a reference. Sensitivity analysis proceeded to investigate synthesis gas characteristics following different injection condition of oxidizing agent. The underground coal gasification model has been implemented. That is divided into drying, pyrolysis, char gasification and the simulation results was confirmed by the production gas flow, yield of synthesis gas and amount of gasified carbon from results of the actual experimental data.

• Analytical Science and Technology
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• v.18 no.1
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• pp.74-84
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• 2005

Understandings of adsorption characteristic of interface are very important in several advanced materials processes, related to NT and BT technology. Volumetric gas adsorption method, suitable for absolute measurements, is regarded as the standardized measurement technique for specific surface area. In order to verify the reliability of commercial equipments, certified reference materials (called CRM) of specific surface area are developed and evaluated its uncertainty factors by standard equipment which has traceability to SI units. Specific surface areas of developed materials are $10.72{\pm}0.46m^2g^{-1}$ for silicon nitride powders and $149.50{\pm}3.44m^2g^{-1}$ for alumina. These disseminations of CRMs would result in improved reliability chains in industrial processes, and lead eventually to contribution to productivity improvement, quality management, safety evaluation, and possibly to new material development.

• Bulletin of the Korean Chemical Society
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• v.35 no.11
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• pp.3275-3279
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• 2014

A mass balance method for purity assessment of thermolabile organic reference materials was established by combining several techniques, including liquid chromatography with UV/VIS detector (LC-UV), Karl-Fischer (K-F) Coulometry, and thermal gravimetric analysis (TGA). This method was applied to three fluoroquinolones like enrofloxacin, norfloxacin and ciprofloxacin. LC-UV was used to analyze structurally related organic impurities based on UV/VIS absorbance spectra obtained in combination with LC separation. For all three organic reference materials, the UV/VIS spectra of the separated impurities were similar to that of the major component of the corresponding materials. This indicates that the impurities are structurally related to the respective reference material sharing common chromophores. Impurities could be quantified by comparing their absorbances at the wavelength of maximum absorbance (${\lambda}_{max}$). The water contents of the reference materials were measured by K-F Coulometry by an oven-drying method. The total inorganic impurities contents were assayed from ash residues in TGA analysis with using air as a reagent gas. The final purities estimated from results of those analytical techniques were assigned as ($99.91{\pm}0.06$), ($97.09{\pm}0.17$) and ($91.85{\pm}0.17$)% (kg/kg) for enrofloxacin, norfloxacin and ciprofloxacin, respectively. The assigned final purities would be applied to the reference materials which will be used as calibrators for the certification of those compounds in matrix CRMs as starting points for the traceability of their certified values to SI units.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.45 no.6
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• pp.82-94
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• 2008

The purpose of web-sensor is to transmit the measured sensor data and the related information to remote user. Since the user exists at remote place, the sensor information must be trustworthy, and the diagnosis for sensors should be easy to handle. To make sure of these issues, IEEE 1451 for smart sensor had been presented in the past. This research proposes the smart web sensor. The proposed smart web sensor is based on IEEE 1451.0, therefore most of the sensor interfaces are able to be used, and could realize the smart sensor by using TEDS information. Also it has the user-friendly web-service by using XML so that the remote user can handle easily the every possible information related to sensor. This research presents reference model for smart web sensor, and to prove how valuable it is, web-service using gas sensor is implemented.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.11
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• pp.1548-1562
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• 2003

This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

• Journal of Power System Engineering
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• v.18 no.1
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• pp.69-75
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• 2014

The pressure and temperature characteristics of mixed refrigerant gases in bulb for thermostatic expansion valve were studied using R22 refrigerant and $N_2$ gases. The characteristics of mixed refrigerant gases were investigated according to pressure variation and the variation of composition ratio of R22 refrigerant and $N_2$ gases in the temperature range of -$15^{\circ}C$~$15^{\circ}C$. The Maximum operating pressure(MOP) of mixed refrigerant gases were showed a tendency to decrease with decreasing the mixing ratio of $N_2$ gas. The characteristics in the case of the mixing ratio of 90:1 for R22 refrigerant and $N_2$ gases were the same result as Reference refrigerant. In addition, the characteristics of the mixed refrigerant gases in the mixing ratio of 90:1 for R22 refrigerant and $N_2$ gases were showed almost linear in the measurement range of pressure-temperature, and the physical properties also were showed similar results with Reference refrigerant. It was able to confirm that a MOP on the thermostatic expansion valve for sensing bulb can be maintained by adjusting the mixing ratio of R22 refrigerant and $N_2$ gases.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.615-622
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• 2023

In this study, the theoretical analysis focused on the quantity of liquid hydrogen required for cooling down to 20 K, as well as the generation of boil-off gas (BOG) from the cooling process of the cryogenic components. The study involved calculating the amount of liquid hydrogen needed to achieve the desired temperature for the cryogenic components and subsequently determining the resulting BOG production at various reference temperatures. It was shown that it was important to efficiently lower the temperature of cryogenic parts through preliminary cooling. As a result, the reference temperature and pressure had an influence on the BOG generation on the cooling of cryogenic components using liquid hydrogen.

• Applied Biological Chemistry
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• v.34 no.2
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• pp.154-161
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• 1991

An objective method for measuring rancidity in soybean oil was developed based on the volatile contents obtained by headspace gas chromatographic analysis. Apparatus for headspace volatile cold trapping-thermal desorption was described, designed to collect and analyze volatiles of soybean oil. Samples of commercially processed soybean oil were stored under controlled condition and then evaluated for flavor by a eight member trained panel and for volatile contents by headspace gas chromatographic analysis. Twenty-three GC peaks were identified on the basis of relative retention time of reference compounds and gas chromatography-mass spectrometry. The volatile compounds identified were autoxidation products of principal unsaturated fatty acids of soybean oil. The simple linear regressions of flavor score with the pentanal or hexanal contents in aged soybean oil gave correlation coefficient of 0.990 and 0.994. respectively. Pentanal and hexanal contents could be used as a potentially useful index for predicting flavor scores of soybean oil.

• Applied Biological Chemistry
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• v.35 no.1
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• pp.36-41
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• 1992

Several commercial cottonseed, corn and rapeseed oils were stored at $60^{\circ}C\;and\;70^{\circ}C$ with daily exposure of fluorescent light for 12 hours and evaluated their rancidity by headspace gas chromatographic analysis of pentanal and hexanal. The data of gas chromatographic analysis was compared with organoleptic flavor evaluation. For headspace gas chromatographic analysis, the volatile compounds were recovered by porous polymer trap and flushed into a fused silica capillary column at $250^{\circ}C$. Twenty-three GC peaks were identified on the basis of relative retention time of reference compounds and gas chromatography-mass spectrometry. The results showed that the contents of pentanal and hexanal were linearly increased during storage. A very simple linear relationship was found between organoleptic flavor scores and amounts of two volatile compounds with very high correlation coefficient. This results suggested the possible implication of pentanal and hexanal as an quality index for rancidity evaluation of cottonseed, corn and rapeseed oils.