• Title/Summary/Keyword: Reduction technology

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Synthesis of Nitrogen Doped Protein Based Carbon as Pt Catalysts Supports for Oxygen Reduction Reaction (산화환원반응용 백금 촉매 지지체를 위한 질소 도핑된 단백질계 탄소의 제조)

  • Lee, Young-geun;An, Geon-hyeong;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.28 no.3
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    • pp.182-188
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    • 2018
  • Nitrogen (N)-doped protein-based carbon as platinum (Pt) catalyst supports from tofu for oxygen reduction reactions are synthesized using a carbonization and reduction method. We successfully prepare 5 wt% Pt@N-doped protein-based carbon, 10 wt% Pt@N-doped protein-based carbon, and 20 wt% Pt@N-doped protein-based carbon. The morphology and structure of the samples are characterized by field emission scanning electron microscopy and transmission electron micro scopy, and crystllinities and chemical bonding are identified using X-ray diffraction and X-ray photoelectron spectroscopy. The oxygen reduction reaction are measured using a linear sweep voltammogram and cyclic voltammetry. Among the samples, 10 wt% Pt@N-doped protein-based carbon exhibits exellent electrochemical performance with a high onset potential of 0.62 V, a high $E_{1/2}$ of 0.55 V, and a low ${\Delta}E_{1/2}=0.32mV$. Specifically, as compared to the commercial Pt/C, the 10 wt% Pt@N-doped protein-based carbon had a similar oxygen reduction reaction perfomance and improved electrochemical stability.

Estimation of GHG Emissions Reduction and Fuel Economy Improvement of Heavy-Duty Trucks by Using Side Skirt and Boat Tail (사이드스커트와 보트테일을 이용한 대형화물차량의 연비개선 효과 및 온실가스 감축량 추정)

  • Her, Chul haeng;Yun, Byoeng gyu;Kim, Dae wook
    • Journal of Climate Change Research
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    • v.7 no.2
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    • pp.177-184
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    • 2016
  • Recently, the need for technology development of commercial vehicle fuel consumption has emerged. Fuel economy improvement of transport equipment and transportation efficiency, and increasing attention to the logistics cost reduction measures. Increasing attention to the logistics cost reduction measures by fuel economy improvement of transport equipment and transportation efficiency. In this study, we have installed aerodynamic reduction device (side skirt, boat tail) to 14.5 ton cargo trucks and 45 ft tractor-trailers. And the fuel consumption was compared installed before and after. Fuel economy assessment for the aerodynamic reduction value device was tested by modifying the SAE J1321 Joint TMC/SAE Fuel Consumption Test Procedure - Type II test in according domestic situation. Greenhouse gas reductions were calculated in accordance with the scenario, including fuel consumption test results. When the 14.5 ton cargo trucks has been equipped with side skirts and boat tail, it confirmed the improvement in fuel efficiency of 4.72%. One Heavy-duty truck's the annual greenhouse gas reductions value are $6.86ton\;CO_2\;eq$. And if applying the technology to more than 50% of registered 15 ton trucks, greenhouse gas reductions are calculated as $686,826ton\;CO_2\;eq./yr$.

Analysis on an Oxidation-Reduction Reaction of Photocatalytic Plasma Complex Module

  • KIM, Young-Do;KWON, Woo-Taeg
    • Journal of Wellbeing Management and Applied Psychology
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    • v.5 no.2
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    • pp.21-27
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    • 2022
  • Purpose: This study is about photocatalytic technology and plasma oxidation-reduction technology. To the main cause of exposure to odor pollution, two deodorization techniques were applied to develop a module with higher removal efficiency and ozone reduction effect. Research design, data and methodology: A composite module was constructed by arranging two types of dry deodorization equipment (catalyst, adsorbent) in one module. This method was designed to increase the responsiveness to the components of complex odors and the environment. standard, unity, two types of oxidizing photo-catalyst technology and plasma dry deodorization device installed in one module to increase the potential by reduction to 76% of ozone, 100%, and 82%. Results: The complex odor disposal efficiency was 92%. Ammonia was processed with 50% hydrogen sulfide and 100% hydrogen sulfide, and ozone was 0.01ppm, achieving a target value of 0.07ppm or less. The combined odor showed a disposal efficiency of 93%, ammonia was 82% and hydrogen sulfide was 100% processed, and ozone achieved a target value of 0.07 ppm or less. Conclusions: Ozone removal efficiency was 76% by increasing Oxidation-Reduction Reaction(ORR). The H2S removal efficiency of the deodorizer was higher than that of the biofilter system currently used in sewage disposal plants.

Reduction of Trimethylamine Off-Odor by Lactic Acid Bacteria Isolated from Korean Traditional Fermented Food and Their In Situ Application

  • Park, Seul-Ki;Jo, Du-Min;Yu, Daeung;Khan, Fazlurrahman;Lee, Yang Bong;Kim, Young-Mog
    • Journal of Microbiology and Biotechnology
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    • v.30 no.10
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    • pp.1510-1515
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    • 2020
  • Trimethylamine (TMA) is a well-known off-odor compound in fish and fishery products and is a metabolic product of trimethylamine N-oxide (TMAO) generated by the enzymatic action of microorganisms. The off-odor is a factor that can debase the value of fish and fishery products. The present study aimed to remove TMA using lactic acid bacteria (LAB). A total of fifteen isolates exhibiting the TMA reduction efficacy were isolated from Korean traditional fermented foods. Among these isolates, five LAB isolates (Lactobacillus plantarum SKD 1 and 4; Lactobacillus paraplantarum SKD 15; Pediococcus stilesii SKD 11; P. pentosaceus SKD 14) were selected based on their high TMA reduction efficacy. In situ reduction of TMA efficacy by the LAB cell-free supernatant was evaluated using a spoiled fish sample. The results showed effective TMA reduction by our selected strains: SKD1 (45%), SKD4 (62%), SKD11 (60%), SKD14 (59%), and SKD15 (52%), respectively. This is the first study on TMA reduction by the metabolic activity of LAB and in situ reduction of TMA using cell-free supernatant of LAB. The present finding suggests an economically useful and ecofriendly approach to the reduction of TMA.

Green Synthesis of Platinum Nanoparticles by Electroreduction of a K2PtCl6 Solid-State Precursor and Its Electrocatalytic Effects on H2O2 Reduction

  • Kim, Kyung Tae;Jin, Sung-Ho;Chang, Seung-Cheol;Park, Deog-Su
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3835-3839
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    • 2013
  • A new synthesis route for Pt nanoparticles by direct electrochemical reduction of a solid-state Pt ion precursor ($K_2PtCl_6$) is demonstrated. Solid $K_2PtCl_6$-supported polyethyleneimine (PEI) coatings on the surface of glassy carbon electrode were prepared by simple mixing of solid $K_2PtCl_6$ into a 1.0% PEI solution. The potential cycling or a constant potential in a PBS (pH 7.4) medium were applied to reduce the solid $K_2PtCl_6$ precursor. The reduction of Pt(IV) began at around -0.2 V and the reduction potential was ca. -0.4 V. A steady state current was achieved after 10 potential cycling scans, indicating that continuous formation of Pt nanoparticles by electrochemical reduction occurred for up to 10 cycles. After applying the reduction potential of -0.6 V for 300 s, Pt nanoparticles with diameters ranging from $0.02-0.5{\mu}m$ were observed, with an even distribution over the entire glassy carbon electrode surface. Characteristics of the Pt nanoparticles, including their performance in electrochemical reduction of $H_2O_2$ are examined. A distinct reduction peak observed at about -0.20 V was due to the electrocatalytic reduction of $H_2O_2$ by Pt nanoparticles. From the calibration plot, the linear range for $H_2O_2$ detection was 0.1-2.0 mM and the detection limit for $H_2O_2$ was found to be 0.05 mM.

Detection of tension force reduction in a post-tensioning tendon using pulsed-eddy-current measurement

  • Kim, Ji-Min;Lee, Jun;Sohn, Hoon
    • Structural Engineering and Mechanics
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    • v.65 no.2
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    • pp.129-139
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    • 2018
  • Post-tensioning (PT) tendons are commonly used for the assembly of modularized concrete members, and tension is applied to the tendons during construction to facilitate the integrated behavior of the members. However, the tension in a PT tendon decreases over time due to steel corrosion and concrete creep, and consequently, the stress on the anchor head that secures the PT tendon also diminishes. This study proposes an automatic detection system to identify tension reduction in a PT tendon using pulsed-eddy-current (PEC) measurement. An eddy-current sensor is installed on the surface of the steel anchor head. The sensor creates a pulsed excitation to the driving coil and measures the resulting PEC response using the pick-up coil. The basic premise is that the tension reduction of a PT tendon results in stress reduction on the anchor head surface and a change in the PEC intensity measured by the pick-up coil. Thus, PEC measurement is used to detect the reduction of the anchor head stress and consequently the reduction of the PT tendon force below a certain threshold value. The advantages of the proposed PEC-based tension-reduction-detection (PTRD) system are (1) a low-cost (< $ 30), low-power (< 2 Watts) sensor, (2) a short inspection time (< 10 seconds), (3) high reliability and (4) the potential for embedded sensing. A 3.3 m long full-scale monostrand PT tendon was used to evaluate the performance of the proposed PTRD system. The PT tendon was tensioned to 180 kN using a custom universal tensile machine, and the tension was decreased to 0 kN at 20 kN intervals. At each tension, the PEC responses were measured, and tension reduction was successfully detected.

Preparation of sulfonated reduced graphene oxide by radiation-induced chemical reduction of sulfonated graphene oxide

  • Jung, Chang-Hee;Hong, Ji-Hyun;Jung, Jin-Mook;Hwang, In-Tae;Jung, Chan-Hee;Choi, Jae-Hak
    • Carbon letters
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    • v.16 no.1
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    • pp.41-44
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    • 2015
  • We report the preparation of sulfonated reduced graphene oxide (SRGO) by the sulfonation of graphene oxide followed by radiation-induced chemical reduction. Graphene oxide prepared by the well-known modified Hummer's method was sulfonated with the aryl diazonium salt of sulfanilic acid. Sulfonated graphene oxide (SGO) dispersed in ethanol was subsequently reduced by ${\gamma}$-ray irradiation at various absorbed doses to produce SRGO. The results of optical, chemical, and thermal analyses revealed that SRGO was successfully prepared by ${\gamma}$-ray irradiation-induced chemical reduction of the SGO suspension. Moreover, the electrical conductivity of SRGO was increased up to 2.94 S/cm with an increase of the absorbed dose.

A cable tension identification technology using percussion sound

  • Wang, Guowei;Lu, Wensheng;Yuan, Cheng;Kong, Qingzhao
    • Smart Structures and Systems
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    • v.29 no.3
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    • pp.475-484
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    • 2022
  • The loss of cable tension for civil infrastructure reduces structural bearing capacity and causes harmful deformation of structures. Currently, most of the structural health monitoring (SHM) approaches for cables rely on contact transducers. This paper proposes a cable tension identification technology using percussion sound, which provides a fast determination of steel cable tension without physical contact between cables and sensors. Notably, inspired by the concept of tensioning strings for piano tuning, this proposed technology predicts cable tension value by deep learning assisted classification of "percussion" sound from tapping a steel cable. To simulate the non-linear mapping of human ears to sound and to better quantify the minor changes in the high-frequency bands of the sound spectrum generated by percussions, Mel-frequency cepstral coefficients (MFCCs) were extracted as acoustic features to train the deep learning network. A convolutional neural network (CNN) with four convolutional layers and two global pooling layers was employed to identify the cable tension in a certain designed range. Moreover, theoretical and finite element methods (FEM) were conducted to prove the feasibility of the proposed technology. Finally, the identification performance of the proposed technology was experimentally investigated. Overall, results show that the proposed percussion-based technology has great potentials for estimating cable tension for in-situ structural safety assessment.

Denoising Autoencoder based Noise Reduction Technique for Raman Spectrometers for Standoff Detection of Chemical Warfare Agents (비접촉식 화학작용제 탐지용 라만 분광계를 위한 Denoising Autoencoder 기반 잡음제거 기술)

  • Lee, Chang Sik;Yu, Hyeong-Geun;Park, Jae-Hyeon;Kim, Whimin;Park, Dong-Jo;Chang, Dong Eui;Nam, Hyunwoo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.24 no.4
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    • pp.374-381
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    • 2021
  • Raman spectrometers are studied and developed for the military purposes because of their nondestructive inspection capability to capture unique spectral features induced by molecular structures of colorless and odorless chemical warfare agents(CWAs) in any phase. Raman spectrometers often suffer from random noise caused by their detector inherent noise, background signal, etc. Thus, reducing the random noise in a measured Raman spectrum can help detection algorithms to find spectral features of CWAs and effectively detect them. In this paper, we propose a denoising autoencoder for Raman spectra with a loss function for sample efficient learning using noisy dataset. We conduct experiments to compare its effect on the measured spectra and detection performance with several existing noise reduction algorithms. The experimental results show that the denoising autoencoder is the most effective noise reduction algorithm among existing noise reduction algorithms for Raman spectrum based standoff detection of CWAs.

A Study on the Methodology of Calculating Greenhouse Gas Emission Reduction by HFCs Reduction - Focusing on the Foam Industry - (HFCs 감축에 따른 온실가스 감축량 산정방법론 연구 - 발포산업을 중심으로 -)

  • Choi, Ji Won;Kim, Jung Man;Ahn, Jun Kwan
    • Journal of Climate Change Research
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    • v.9 no.4
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    • pp.399-406
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    • 2018
  • The purpose of this study is to propose a methodology for estimating greenhouse gas emission reduction through HFCs used in the foam industry. This study investigated characteristics of HFCs and greenhouse gas emissions from production processes in the foam industry, which uses HFCs as a blowing agent. Also, we investigated fluorinated gas removal technology to determine a proper technology for the foam industry. And we confirmed the criteria and characteristics of External Project for methodology development. According to criteria of External Project and foam industrial process emission, a methodology for calculating the amount of greenhouse gas emission reduction in foam industry was developed. Lastly, we analyzed the amount of greenhouse gas emission reduction and KOC (Korea Of Offset) in the foam industry based on the domestic government's plan to reduce HCFCs and imported amount of HFCs used as a blowing agent. The results of this study demonstrate that linking greenhouse gas reduction in the foam industry and the domestic greenhouse gas reduction system can contribute to achieve the domestic greenhouse gas reduction goal.