• Title/Summary/Keyword: Reducing $CO_2$

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Electrochemical and Spectroelectrochemical Studies of Cobalt Salen and Salophen as Oxygen Reduction Catalysts

  • Bertha Ortiz;Park, Su Mun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.4
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    • pp.405-411
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    • 2000
  • Electrochemical and spectroelectrochemical studies of cobalt-Schiff (Co-SB) base complexes, Co(salen) [N-N'-bis(salicylaldehyde)-ethylenediimino cobalt(II)] and Co(salophen) [N-N'-bis(salicylaldehyde)-1,2-pheny-lenediimino cobalt(II)], have been c arried out to test them as oxygen reduction catalysts. Both compounds were found to form an adduct with oxygen and exhibit catalytic activities for oxygen reduction. Comparison of spec-tra obtained from electrooxidized complexes with those from Co-SB complexes equilibrated with oxygen in-dicates that the latter are consistent with the postulated complex formed with oxygen occupying the coaxial ligand position, namely, Co(III)-SB·O2 - .The catalysis of oxygen reduction is thus achieved by reducing Co(III) in the oxygen-Co-SB adduct, releasing the oxygen reduction product, e.g., O2 - ., from the Co(II)-SB complex.

Effect of Alginate on the Growth of Nannochloropsis oculata NIES-2145 (알긴산이 Nannochloropsis oculata NIES-2145의 생장에 미치는 영향)

  • Park, Hyun-Jin;Kim, Young-Hwa;Lee, Jae-Hwa
    • KSBB Journal
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    • v.26 no.3
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    • pp.206-210
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    • 2011
  • The growth effect of Nannochloropsis oculata (N.oculata), unicellular microalgae, by alginate was investigated. Alginate was depolymerized with sulfuric acid ($H_2SO_4$) and heat ($121^{\circ}C$), simultaneously. Addition of 0.75% alginate oligomer depolymerized with 0.2 N $H_2SO_4$ showed the maximum yield and the growth rate of N. oculata. Chlorophyll content and reducing sugar was increased by alginate oligomer in a dose-dependent manner. Alginate oligomer promoted the growth of N. oculata, whereas the original alginate polysaccharides had no significant effect. Laminaria japonica (L. japonica) extract containing high level of alginate was also increased growth rate and chlorophyll content. $CO_2$ supply addition to L. japonica extract showed no change the growth rate, although addition to alginate oligomer showed prominently increased. N. oculata could use more saccharides in presence of $CO_2$ according to reducing sugar determination. From these results, it is useful to establish optimal condition for high cell density cultivation of N. oculata.

Study on the Strategy of CO2 Reduction Technology in Vehicle according to CO2 Emissions Regulation in EU - Focusing on Auxiliary Energy Improvement - (유럽 CO2 감축법에 따른 차량 CO2 감축 기술 전략에 관한 연구 - 보기류 개선을 중심으로 -)

  • Seok, Kyu-Up;Yoon, Hyoung Jin
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.230-238
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    • 2015
  • The main purpose of this paper is to suggest opportunities for reducing $CO_2$ emission in energy conversion of a vehicle, focused on auxiliary energy improvement in the automotive field. As part of worldwide efforts to curb global warming and to protect the domestic industry as trade barriers, many countries have set goals to regulate greenhouse gas emissions. As an example, new $CO_2$ emission regulation in EU was expected to go into effect strictly in 2020. Therefore, global car-makers need to establish strategic responsiveness of the regulations. This paper shows $CO_2$ economic value by using the correct interpretation of the relevant laws and regulations. The $CO_2$ value analyzed using quantitative figures leads to the possibility of auxiliary(accessories, HVAC, electric apparatus etc.) technology for improving fuel economy. As a result, this study generalizes the meaning of electric power saving for each driving mode by auxiliary energy improvement.

Performance Analysis of an Oxy-fuel Combustion Power Generation System Based on Waste Heat Recovery: Influence of CO2 Capture (배열회수형 순산소연소 발전시스템의 성능해석: CO2 포집의 영향)

  • Tak, Sang-Hyun;Park, Sung-Ku;Kim, Tong-Seop;Sohn, Jeong-Lak;Lee, Young-Duk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.12
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    • pp.968-976
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    • 2009
  • As the global warming becomes a serious environmental problem, studies of reducing $CO_2$ emission in power generation area are in progress all over the world. One of the carbon capture and storage(CCS) technologies is known as oxy-fuel combustion power generation system. In the oxy-fuel combustion system, the exhaust gas is mainly composed of $CO_2$ and $H_2O$. Thus, high-purity $CO_2$ can be obtained after a proper $H_2O$ removal process. In this paper, an oxy-fuel combustion cycle that recovers the waste heat of a high-temperature fuel cell is analyzed thermodynamically. Variations of characteristics of $CO_2$ and $H_2O$ mixture which is extracted from the condenser and power consumption required to obtain highly-pure $CO_2$ gas were examined according to the variation of the condensing pressure. The influence of the number of compression stages on the power consumption of the $CO_2$ capture process was analyzed, and the overall system performance was also investigated.

A study on $CO_2$ absorption of concrete during life cycle of building (건물 생애주기 동안 콘크리트의 이산화탄소 흡수에 관한 연구)

  • Lee, Sang-Hyun;Lee, Han-Seoung;Song, Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.577-580
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    • 2008
  • Concrete absorbs $CO_2$ in the air because of carbonation. according to rising concern for lasting earth environment efforts of reducing greenhouse gas, especially co2, are occurred whole industry throughout the world. In this paper selected one building and computed amount of production and absorbtion of co2 during its lifecycle at concrete. In computing amount of absorbtion of co2 considered amount of absorbtion according to the area of concrete changing senarioes of servicelife(40,60,80 years) and deconstruct preiod(60,40,20 years). As a result, size of concrete and maintenance period of disused concrete work increasement of $CO_2$ as main factors. We came to the conclusion that maintenance period is more important than recycle of unused concrete as a method for reducing environmental load in architectural industry.

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Synthesis of Ultrafine TiC-5%Co Powder by Using Co Nitrate and TiO(OH)2 Slurry and Evaluation of Sintered Materials Prepared by Mixing WC-Co (Co 질산염과 TiO(OH)2 슬러리를 이용한 초미립 TiC-5%Co 제조 및 WC-Co 분말과의 혼합에 따른 소결체 특성)

  • Hong, Seong-Hyeon;Kim, Byoung-Kee
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.107-113
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    • 2008
  • Ultrafine TiC-5%Co powders were synthesized by spray drying of aqueous solution of TiO$(OH)_2$ slurry and cobalt nitrate, followed by calcination and carbothermal reaction. The oxide powders with carbon powder was reduced and carburized at $900^{\circ}C{\sim}1250^{\circ}C$ under hydrogen atmosphere. During reduction, CO gas was mainly evolved by reducing reaction of oxides. Ultrafine TiC-5%Co powders were easily formed by carbothermal reaction at $1250^{\circ}C$ due to using ultrafine powders as raw materials. The ultrafine WC-TiC-Co alloy prepared by sintering of mixed powder of ultrafine WC-13%Co powder and ultrafine TiC-5%Co powder has higher sintered density and mechanical properties than WC-TiC-Co alloy prepared by commercial WC, TiC and Co powders.

Gas Sensing Characteristics and Doping Effect of $MoO_3$ Thin Films prepared by RF magnetron sputtering (RF magnetron sputtering법으로 제조한 $MoO_3$ 박막의 가스 감지 특성 및 첨가물의 영향)

  • Hwang, Jong-Taek;Jang, Gun-Eik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.460-463
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    • 2002
  • $MoO_3$ thin films were deposited on electrode and heater screen-printed alumina substrates in $O_2$ atmosphere by RF reactive sputtering using Molybdenum metal target. The deposition was performed at $300^{\circ}C$ with 350W of a forward power in an $Ar-O_2$ atmosphere. The working pressure was maintained at $3{\times}10^{-2}mtorr$ and all deposited films were annealed at $500^{\circ}C$ for 5hours. To investigate gas sensing characteristics of the addition doped $MoO_3$ thin film, Co, Ni and Pt were used as adding dopants. The sensing properties were investigated in tenn of gas concentration under exposure of reducing gases such as $H_2$, $NH_3$ and CO at optimum working temperature. Co-doped $MoO_3$ thin film shows the maximum 46.8% of sensitivity in $NH_3$ and Ni-doped $MoO_3$ thin film exhibits 49.7% of sensitivity in $H_2$.

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Gas Sensing Characteristics and Doping Effect of MoO3Thin Films Sensor (박막형 MoO3가스센서의 가스 감지 특성 및 첨가물의 영향)

  • 황종택;장건익;윤대호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.8
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    • pp.705-710
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    • 2003
  • MoO$_3$thin films were deposited on electrode of alumina substrates in $O_2$atmosphere by RF reactive sputtering using molybdenum metal target. The deposition was performed at 30$0^{\circ}C$ with 350 W of a forward power in an Ar-O$_2$atmosphere. The working pressure was maintained at 3$\times$10$^{-2}$ torr and all deposited films were annealed at 50$0^{\circ}C$ for 5 hours. The surface morphology of films was observed by using a SEM and crystalline phases were analyzed by using a XRD. To investigate gas sensing characteristics of the doped MoO$_3$thin film, Co, Ni and Pt were used as dopants. The sensing properties were investigated in term of gas concentration under exposure of reducing gases such as H$_2$, NH$_3$and CO at optimum working temperature. Co-doped MoO3 thin film shows the maximum 46.8 % of sensitivity in NH$_3$ and Ni-doped MoO$_3$thin film exhibits 49.7 % of sensitivity in H$_2$.

Studies on Combined Usage of Velvet Antler Water Extract and Anti-neoplastic Drugs (I) -Reducing Effect of Velvet Antler Water Extract to the Adverse Actions of cis-Platin and Mitomycin C- (녹용 물추출물과 항암제의 병용투여에 관한 연구(제 1보) -녹용 물추출물과 cis-Platin 및 Mitomycin C 병용투여에 의한 항암제 부작용 경감효과-)

  • Sim, Sang-Bum;Kim, Jae-Kun;Won, Do-Hee;Hong, Nam-Doo;Kim, Nam-Jae
    • Korean Journal of Pharmacognosy
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    • v.29 no.2
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    • pp.93-103
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    • 1998
  • In order to investigate the reducing effect of velvet antler water extract (VAWE) on the toxicity of anti-cancer drug, cis-platin (CDDP) and mitomycin C (MMC), we examined effects of co-administration with VAWE and anti-cancer drugs on their toxicities. We recognized that $LD_{50}$ of CDDP/MMC were increased by co-administration with VAWE and them in mice. It was found that co-administration of VAWE and MMC increased the survival rate in mice treated by lethal dose of MMC. Also, co-administration of VAWE and CDDP/MMC inhibited decrease of the body weight and organ weight in mice intoxificated by CDDP/MMC. The increase of serum blood urea and serum creatinine levels in rats intoxicated by CDDP were significantly inhibited by the co-administrationin with VAWE and CDDP. The decrease of RBC and WBC in rats intoxificated by MMC were significantly inhibited by the co-administration with VAWE and MMC. These results suggest that the combined usage of VAWE and CDDP/MMC drugs may be a new method for prevented or minimized the toxicity of them.

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Improved Surface Characteristics of Automotive Interior Parts Fabricated by Injection Molding Method (사출법으로 제조된 자동차 내장부품의 표면특성 개선 연구)

  • Choi, Dong-Hyuk;Hwang, Hyun-Tae;Son, Dong-Il;Kim, Daeil
    • Journal of the Korean institute of surface engineering
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    • v.52 no.1
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    • pp.43-51
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    • 2019
  • The environmental pollution which is global warming and abnormal climate is caused by increasing population and activated economics. To reduce environmental pollution, we have being efforts into reducing $CO_2$ emission and use of energy, resources. Especially, for the sake of light weight and fuel efficiency of automotive industry, many countries have defined the restrict environmental regulation which stipulate high magnitude of reducing $CO_2$ emission. In this study, we have predicted the problem of Mu-cell injection molding through the finite element analysis as a function of temperature controlled by Joule heating or in terms of mold temperature. From the result of finite element analysis, we have determined the optimized process and made the injection mold included electric current heating system with Mu-cell manufacturing. Lastly, we analyzed the surface characteristics of the injection products with mold temperature.