• Journal of the Korean Institute of Gas
• /
• v.26 no.2
• /
• pp.14-20
• /
• 2022

In this study, the catalytic reaction characteristics for producing hydrogen using methanol steam reforming were investigated. Nickel and copper are frequently used in steam reforming reaction and methanol synthesis, were used as main active metals. As a support, hydrotalcite has a high specific surface area, excellent porosity and thermal stability, and has weak Lewis acid sites and basic properties. Hydrotalcite was used to identify catalysts of methanol steam reforming with catalytic activity and their properties. In this research, high reactivity was shown in the catalyst of copper metal with high reducibility. And increasing of active metal loading showed the higher the methanol conversion and hydrogen selectivity.

• Communications of the Korean Mathematical Society
• /
• v.39 no.1
• /
• pp.187-199
• /
• 2024

In the present paper, following the pullback approach to Finsler geometry, we study intrinsically the C^v-reducible and generalized C^v-reducible Finsler spaces. Precisely, we introduce a coordinate-free formulation of these manifolds. Then, we prove that a Finsler manifold is C^v-reducible if and only if it is C-reducible and satisfies the 𝕋-condition. We study the generalized C^v-reducible Finsler manifold with a scalar π-form 𝔸. We show that a Finsler manifold (M, L) is generalized C^v-reducible with 𝔸 if and only if it is C-reducible and 𝕋 = 𝔸. Moreover, we prove that a Landsberg generalized C^v-reducible Finsler manifold with a scalar π-form 𝔸 is Berwaldian. Finally, we consider a special C^v-reducible Finsler manifold and conclude that a Finsler manifold is a special C^v-reducible if and only if it is special semi-C-reducible with vanishing 𝕋-tensor.

• Korean Chemical Engineering Research
• /
• v.52 no.5
• /
• pp.678-687
• /
• 2014

The catalytic performance of silicon carbide supported nickel catalysts modified with or without second metal (Co, Cu and Zn) for the methanation of CO has been investigated in a fixed-bed reactor using a feed consisting of 25% CO and 75% $H_2$ without any diluent gas. It has been found that the introduction of Co species can clearly improve the catalytic activity of Ni/SiC catalyst, whereas the addition of Cu or Zn can result in a significant decrease in the catalytic activity. The characterizations by means of XRD, TEM, XPS, CO-TPD and $H_2$-TPR indicate that the addition of Co could decrease the particle size of active metal, increase active sites on the surface of methanation catalyst, improve the chemisorption of CO and enhance the reducibility of methanation catalysts. Additionally, the special interaction between Co species and Ni species is likely favorable for the dissociation of adsorbed CO on the surface of catalyst, and this may also contribute to the high activity of 5Co-Ni/SiC catalyst for CO methanation reaction. For 5Cu-Ni/SiC catalyst and 5Zn-Ni/SiC catalyst, Cu and Zn species could cover partial nickel particles and decrease the chemisorption amount of CO. These could be responsible for the low methanation activity. In addition, a 150h stability test under 2 MPa and $300^{\circ}C$ showed that 5Co-Ni/SiC catalyst was very stable for CO methanation reaction.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.10
• /
• pp.3213-3217
• /
• 2012

Reactive adsorption desulfurization (RADS) experiments were conducted over a series of commercial metal oxide supports ($Al_2O_{3-}$, $SiO_{2-}$, $TiO_{2-}$ and $ZrO_{2-}$) supported Ni/ZnO adsorbents. The adsorbents were characterized by X-ray diffraction (XRD), temperature programmed reduction (TPR), and Fourier transform infrared spectroscopy (FTIR) in order to find out the influence of specific types of surface chemistry and structural characteristics on the sulfur adsorptive capacity. The desulfurization performance of all the studied adsorbents decreased in the following order: Ni/ZnO-$TiO_2$ > Ni/ZnO-$ZrO_2$ > Ni/ZnO-$SiO_2$ > Ni/ZnO-$Al_2O_3$. Ni/ZnO-$TiO_2$ shows the best performance and the three hour sulfur capacity can achieve 12.34 mg S/g adsorbent with a WHSV of $4h^{-1}$. Various characterization techniques suggest that weak interaction between active component and support component, high dispersion of NiO and ZnO, high reducibility and large total Lewis acidity of the adsorbents are important factors in achieving better RADS performance.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.9
• /
• pp.2726-2732
• /
• 2014

The promoting effect of rhodium on the structure and activity of the supported Cu-Co based catalysts for CO hydrogenation was investigated in detail. The samples were characterized by DRIFTS, $N_2$-adsorption, XRD, $H_2$-TPR, $H_2$-TPD and XPS. The results indicated that the introduction of rhodium to Cu-Co catalysts resulted in modification of metal dispersion, reducibility and crystal structure. DRIFTS results of CO hydrogenation at reaction condition (P=2 MPa, $T=260^{\circ}C$) indicated the addition of 1 wt % rhodium improved hydrogenation ability of Cu-Co catalysts. The ethanol selectivity and CO conversion were both improved by 1 wt % Rh promoted Cu-Co based catalysts. The alcohol distribution over un-promoted and rhodium promoted Cu-Co based catalysts obeys A-S-F rule and higher chain growth probability was got on rhodium promoted catalyst.

• Korean Chemical Engineering Research
• /
• v.54 no.5
• /
• pp.712-718
• /
• 2016

Platinum catalysts supported on the mesoporous material synthesized from Y zeolite were applied to synthesis of jet-fuel through n-octadecane hydroupgrading. The mesoporous aluminosolicate, $MMZ_{HY}$ was synthesized using Y zeolite as its framework source. The effect of the addition of Mg to $Pt/MMZ_{HY}$ catalyst for n-octadecane hydroupgrading was investigated. Catalyst characterization was performed with X-ray diffraction, $N_2$ adsorption, temperature-programmed reduction in hydrogen flow, temperature-programmed desorption of ammonia, and infrared spectroscopy of adsorbed pyridine. The high yield of jet-fuel over the $PtMg(2.0)/MMZ_{HY}$ can be attributed not only to the higher dispersion of Pt metal and higher reducibility, but also the higher amount of acid sites and higher strength of acid sites. The selectivity to iso-paraffin in the jet-fuel fraction could be reached above 80% over the optimized $PtMg/MMZ_{HY}$ catalyst.

• Transactions of the Korean hydrogen and new energy society
• /
• v.26 no.6
• /
• pp.516-523
• /
• 2015

Nickel based oxygen transfer materials supported on two different YSZs were tested to evaluate their performance in methane chemical-looping reforming. The oxygen transfer materials of YSZs were selected with different amount of the doped yittrium in the $ZrO_2$ structure. The yittrium of 8 mol% stabilized the zirconia oxide to a cubic structure compare to the 3 mol% doping, which is known to be a good for oxygen transfer. Various nickel amounts (16wt.%, 32wt.%, 48wt.%) were loaded on the selected supports. The nickel amount of 32% shows the optimized catalyst structure with good physical properties and reducibility from the XRD, BET and H2-TPR analysis, especially when the support of 8YSZ was used. From the methane chemical-looping reforming, hydrogen was produced by methane decomposition catalyzed by Ni on both YSZs. Comparing two YSZ supports of 3YSZ and 8YSZ during the cycling tests, the catalyst with 8YSZ (Ni 32%) exhibits not only the higher methane conversion and hydrogen production but also a faster reaction rate reaching to the stable point.

• Clean Technology
• /
• v.21 no.2
• /
• pp.96-101
• /
• 2015

Hematite reduction using hydrogen was conducted and the various process parameters were closely observed. A lab scale fluidized bed unit was designed especially for this study. The optimal values of the gas velocity, reduction time and temperature were evaluated. The values which indicated the highest reduction rate were set as fixed parameters for the following tests starting with the reduction time of 30 minutes and 750 ℃ of temperature. Among these variables the one with the highest interest was the gas specific consumption. It will tell the amount of the gas which is required to achieve a reduction rate of over 90% at the optimal conditions. This parameter is important for the scale up of the lab scale unit. 1,500 Nm³/ton-ore was found to be the optimal specific gas consumption rate at which the reduction rates exhibit the highest values for hematite.

• Journal of the Korean Society of Costume
• /
• v.64 no.7
• /
• pp.97-113
• /
• 2014

The study aims to determine the significance and characteristics of self-similarity inherent in natural objects or phenomena, the existence of self-similarity in design created by fashion designers, and the traits and internal significance implied in self-similarity and their effects on fashion. The subject of the study is Viktor & Rolf, and the scope of the study is the collections created from 2001 to 2014, which include designs implemented in their early years and those unveiled in the media. Self-similarity means attributes of a fractal structure appearing without change in the original form, even after modification of scale or direction in terms of shape or phenomena. As self-similarity is applied to the arts and design sectors, it leads people to pay attention to fundamental characteristics and intrinsic forms as a factor of expressing a unique creative world. Analysis of Viktor & Rolf collections generated ribbons, overlapping/juxtaposition, side decorations and exaggerated design elements as basic units of self-similarity. These factors had self-similarity rates as high as 84%. Self-similarity was established as design elements formed in the incipient stage were repeated in a certain form, and continued for a long period of time. It served as an element that recognizes design and a fashion designer at the same time. Characteristics of self-similarity appearing in Viktor & Rolf collections can be summarized as homeostasis based on an equivalent relationship, balance based on self-organization, reducibility into essential elements, and uniqueness based on odd shapes. These characteristics influenced the pursuit of consistent brand image, the maintenance of a fashion designer's creative world, the formation of styles and the expression of a fashion designer's identity.

• International Journal of Internet, Broadcasting and Communication
• /
• v.7 no.2
• /
• pp.96-104
• /
• 2015

Fischer Tropsch reaction is one of the interesting topic for renewable and clean energy. Polymerization of carbon monoxide or carbon dioxide with hydrogen over metal supported catalyst can produce long chain hydrocarbons. Synthetic liquid hydrocarbons are promising alternative to fossil fuels. This research work has been focused on the synthesis of Fe based catalyst for Fischer Tropsch reaction. Mesoporous silica (MS) support prepared by a precipitation method using two different washing solution, distilled water (DW) and acid in ethanol solution (ET), and different calcination temperature. Then, Fe/MS was prepared by an incipient wetness impregnation method. All of samples were systematically characterized using various physical and chemical techniques. TEM and XRD analysis were used to ensure that the cubic Ia3d mesostructure is stable after calcination. FTIR spectra are useful to ascertain the existence of template in the support. TPR studies were also used to understand the nature of Fe species and their reducibility. The results reveal that washing the support with distilled water and calcination at $550^{\circ}C$ can efficiently remove the triblock copolymer templates. The existence of template in the support affects the textural properties of all catalyst investigated.