• 제목/요약/키워드: Reducibility

검색결과 78건 처리시간 0.028초

On Semi C-Reducibility of General (α, β) Finsler Metrics

  • Tiwari, Bankteshwar;Gangopadhyay, Ranadip;Prajapati, Ghanashyam Kr.
    • Kyungpook Mathematical Journal
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    • 제59권2호
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    • pp.353-362
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    • 2019
  • In this paper, we study general (${\alpha}$, ${\beta}$) Finsler metrics and prove that every general (${\alpha}$, ${\beta}$)-metric is semi C-reducible but not C2-like. As a consequence of this result we prove that every general (${\alpha}$, ${\beta}$)-metric satisfying the Ricci flow equation is Einstein.

폐기물 가스화 합성가스로부터 수소 생산을 위한 수성가스전이 반응용 Cu 기반 촉매 연구 (A Study on Cu Based Catalysts for Water Gas Shift Reaction to Produce Hydrogen from Waste-Derived Synthesis Gas)

  • 나현석;정대운;장원준;이열림;노현석
    • 한국수소및신에너지학회논문집
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    • 제25권3호
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    • pp.227-233
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    • 2014
  • Simulated waste-derived synthesis gas has been tested for hydrogen production through water-gas shift (WGS) reaction over supported Cu catalysts prepared by co-precipitation method. $CeO_2$, $ZrO_2$, MgO, and $Al_2O_3$ were employed as supports for WGS reaction in this study. $Cu-CeO_2$ catalyst exhibited excellent catalytic activity as well as 100% $CO_2$ selectivity for WGS in severe conditions ($GHSV=40,206h^{-1}$ and CO concentration = 38.0%). In addition, $Cu-CeO_2$ catalyst showed stable CO conversion for 20h without detectable catalyst deactivation. The high activity and stability of $Cu-CeO_2$ catalyst are correlated to its easier reducibility, high oxygen mobility/storage capacity of $CeO_2$.

미량 귀금속 첨가에 의한 Ni-계열 메탄 수증기 개질 촉매의 반응 활성 향상에 관한 연구 (A Study of Reactivity Improvement of Ni-based Methane Steam Reforming Catalysts by Small Addition of Noble Metals)

  • 정진혁;구기영;서유택;서동주;노현석;서용석;이득기;김동현;윤왕래
    • 한국수소및신에너지학회논문집
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    • 제17권3호
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    • pp.248-254
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    • 2006
  • The promotion effects of noble metals upon the activity and reducibility in steam methane reforming over $Ni/MgAl_2O_4$ catalysts were investigated. While $Ni/MgAl_2O_4$ catalysts require the pre-reduction by $H_2$, the noble metal-added catalysts show high catalytic activities without pre-treatment. According to $CH_4$-TPR, the addition of noble metal makes the $Ni/MgAl_2O_4$ catalyst easily reducible. The reduction degree of NiO in the noble metal-added catalysts after using at $650^{\circ}C$ without pre-reduction was $15{\sim}20%$, and was lower than that in the $H_2$-reduced $Ni/MgAl_2O_4$ catalyst(reduction degree=27%). The enhancement of the catalytic activity over noble metal-added catalysts results from easier reducibility by addition of noble metal and the synergy effect between noble metal and Ni.

Oxychlorination of methane over FeOx/CeO2 catalysts

  • Kim, Jeongeun;Ryou, Youngseok;Hwang, Gyohyun;Bang, Jungup;Jung, Jongwook;Bang, Yongju;Kim, Do Heui
    • Korean Journal of Chemical Engineering
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    • 제35권11호
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    • pp.2185-2190
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    • 2018
  • Methane activation through oxychlorination is in the spotlight due to the relatively mild reaction conditions at atmospheric pressure and in the temperature range of $450-550^{\circ}C$. Although $CeO_2$ is known to exhibit good activity for methane oxychlorination, significant amounts of by-products such as $CO_2$, CO and carbon deposits are produced during the reaction over $CeO_2$. We investigated the effect of iron in $FeO_x/CeO_2$ catalysts on methane oxychlorination. $FeO_x/CeO_2$ with 3 wt% iron shows the maximum yield at $510^{\circ}C$ with 23% conversion of methane and 65% selectivity of chloromethane. XRD and $H_2$ TPR results indicate that iron-cerium solid solution was formed, resulting in the production of more easily reduced cerium oxide and the suppression of catalysts sintering during the reaction. Furthermore, the selectivity of by-products decreased more significantly over $FeO_x/CeO_2$ than cerium oxide, which can be attributed to the facilitation of HCl oxidation arising from the enhanced reducibility of the former sample.

A REDUCIBILITY OF SRIVASTAVA'S TRIPLE HYPERGEOMETRIC SERIES F(3)[x, y, z]

  • Choi, Junesang;Wang, Xiaoxia;Rathie, Arjun K.
    • 대한수학회논문집
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    • 제28권2호
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    • pp.297-301
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    • 2013
  • When certain general single or multiple hypergeometric functions were introduced, their reduction formulas have naturally been investigated. Here, in this paper, we aim at presenting a very interesting reduction formula for the Srivastava's triple hypergeometric function $F^{(3)}[x,y,z]$ by applying the so-called Beta integral method to the Henrici's triple product formula for hypergeometric series.

스테인리스 냉연공정에서 강판의 형상판정 (Shape Decision of the Stainless Steel at the Skin Pass Mill)

  • 허윤기;최영규
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2008년도 하계종합학술대회
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    • pp.1047-1048
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    • 2008
  • The objective of this paper is to build a decision method of the shape quality for the stainless steel and ensure reducibility of working-load for next rolling process. The criterion of the shape quality is derived from the customer needs, and Automatic Shape Decision System is implemented in SPM (Skin Pass Mill). The methods of shape decision are based on curve fitting and frequency analysis and so on. The Field Test with concerned customers is successful. The performance of right decision is 99% and the claims from the customer have been largely reduced.

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구조해석을 통한 척추측만증 교정 분석에 필요한 모델 개발 (Development of a Mathematical Model for Effect of Scoliosis Surgical Correction)

  • 김영은;최형연;손창규;이광희;이춘기
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 추계학술대회 논문집
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    • pp.1059-1061
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    • 2002
  • A FE model is to develop a personalized biomechanical model of the scoliotic spine that will allow the design of clinical test providing optimal estimation of the post-operation results. A flexible multi-body model of the spine including rib cage, clavicle, and scapular was developed to simulate several mobility simulations. Vertebrae, clavicle and scapular were represented using rigid bodies and ribs and sternum were modeled as flexible bodies. Kinematical Joints and spring elements were used to represent the intervertebral disc and ligaments respectively. Postero-anterior and lateral radiographics of a scoliotic spine were used to represent a 3D reconstruction. CT data for same patient were also used to verify vertebrae rotation driven from postero-anterior and lateral radiographic images. Simulated results showed good reducibility almost uniformly distributed along the spinal segments. It was also found that boundary and loading conditions, required to mimic the operation procedures, were proven to be very sensitive parameters to its results rather than its mechanical properties

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재발성 장중첩증에 대한 임상적 분석 (Clinical Evaluation of Recurrent Intussusception)

  • 박민재;이두선
    • Advances in pediatric surgery
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    • 제9권1호
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    • pp.24-29
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    • 2003
  • To evaluate the clinical findings of the recurrent intussusception, 351 patients with 445 intussusceptions were reviewed. Recurrence rate, pattern of recurrence, reducibility, pathologic lead points (PLP), and operative findings and long term follow up of the multiple recurrences were analyzed. Of 351 patients, 303 had no recurrence, 26 had one recurrence, and 22 had multiple recurrences. Over all recurrence rate was 16.4% ; 18.5% were managed by air reduction, 16.2% by barium reduction and 5.9% by operation. Eleven PLPs were proved operatively and an additional 6 suspected PLPs were depicted radiologically. The most frequent PLP was ileal lymphoid hyperplasia. Intervals between reduction and recurrence were less than 2 weeks in 31 cases, between 2 weeks and 1 year in 55, and more than 1 year in 8. The longest interval was 2 years and 4 months.

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A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals

  • 박진남;김재현;이호인
    • Bulletin of the Korean Chemical Society
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    • 제21권12호
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    • pp.1233-1238
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    • 2000
  • $Mo/{\gamma}-Al_2O_3catalysts$ modified with Fe, Co, and Ni were prepared by impregnation method and catalytic activity for water gas shift reaction was examined. The optimum amount of Mo loaded for the reaction was 10 wt% $MoO_3$ to ${\gamma}-Al_2O_3.$ The catalytic activity of $MoO_3/{\gamma}-Al_2O_3was$ increased by modifying with Fe, Co, and Ni in the order of Co${\thickapprox}$ Ni > Fe. The optimum amounts of Co and Ni added were 3 wt% based on CoO and NiO to 10 wt% $MoO_3/{\gamma}-Al_2O_3$, restectively. The TPR (temperature-programmed reduction) analysis revealed that the addition of Co and Ni enganced the reducibility of the catalysts. The results of both catalytic activity and TPR experiments strongly suggest that the redox property of the catalyst is an important factor in water gas shift reaction on the sulfided Mo catalysts, which could be an evidence of oxy-sulfide redox mechanism.

A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction I. TPR Studies of $Mo/\gamma -Al_2O_3$ Catalysts

  • 박진남;김준희;이호인
    • Bulletin of the Korean Chemical Society
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    • 제19권12호
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    • pp.1363-1368
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    • 1998
  • Mo/γ-Al2O3 catalysts were prepared by impregnation method in various conditions to identify the states of surface Mo species. TPR (Temperature-Programmed Reduction) and Raman spectroscopy were applied to analyze the surface Mo species. TPR analysis revealed that MoO3 was reduced to Mo through MoO2, the intermediate state and the increase of Mo loading enhanced the reducibility of Mo oxide till the formation of monolayer coverage. High temperature calcination induced oxygen defects in MoO3 giving their unstable states for easier reduction. Raman spectroscopy analysis showed that the increase of Mo loading induced the polymeric Mo oxide.