• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.1
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• pp.57-68
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• 2023

In this study, coffee waste was recycled into nitrogen-doped porous carbon fibers as an active material for high-energy EDLC (Electric Double Layer Capacitors). The coffee waste was mixed with polyvinylpyrrolidone and dissolved into dimethylformamide. The mixture was then electrospun to fabricate coffee waste-derived nanofibers (Bare-CWNF), and carbonization process was followed under a nitrogen atmosphere at 900℃. Similar to Bare-CWNF, the as-synthesized carbonized coffee waste-derived nanofibers (Carbonized-CWNF) maintained its fibrous form while preserving the composition of nitrogen. The electrochemical performance was analyzed for carbonized coffee waste (Carbonized-CW)-, carbonized PAN-derived nanofibers (Carbonized-PNF)-, and Carbonized-CWNF-based electrodes in the operating voltage window of -1.0-0.0V, Among the electrodes, Carbonized-CWNF-based electrodes exhibited the highest specific capacitance of 123.8F g^-1 at 1A g^-1 owing to presence of nitrogen and porous structure. As a result, nitrogen-contained porous carbon fibers synthesized from coffee waste showed excellent electrochemical performance as electrodes for high-energy EDLC. The experimental designed in this study successfully demonstrated the recycling of the coffee waste, one of the plant-based biomass that causes the environmental pollution into high-energy materials, also, attaining the ecofriendliness.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.3
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• pp.196-201
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• 2014

As political circumstances in oversea countries and Korea varies, the risk of vulnerability from unexpected extreme loading conditions, such as explosions or extreme impacts, also increased. In addition, construction companies in Korea recently have taken chances of overseas expansion to countries where their domestic situations are not in rest. Therefore, the resistance of construction materials for blast or impact loading become taking more consideration from engineering field. This study is a part of the research to develop a high performance fiber reinforced cementitious composite materials with high volume steel fibers and primary purpose of this study is to find an optimum mix proportions of in-fill slurry. In order to accomplish the tasks this study performed experimental investigations on the slurry for consistency, compressive strength, flowability, J-penetration, bleeding and rheology properties as well as mechanical properties, compressive and flexural strength, with respect to different mix proportions.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.3
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• pp.282-289
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• 2017

The flexural behavior tests of UHPC segmental Box girder which has 160MPa compressive strength and 15.4m length were carried out. The test variables are area of prestressing wires, volume fraction of steel fibers and longitudinal reinforcing bars in upper flange and web. PS tendons which has 32 strands of 15.2mm diameter in lower flange, 24 strands and 14 strands in lower flange were arranged and volume fraction of 2%, 1.5% and 1.0% is used in box girder concrete. UHPFRC box girder which has 32 strands in lower flange showed the over reinforcement and brittle behavior. UHPFRC box girder which has 24 strands showed the similar peak load as 32 strands girder and ductile behavior as large deflection. UHPFRC box girder which has 14 strands showed half of the peak load of 24 strands box girder and ductile behavior. After the application of the formular for the reinforcement index to the behavior of the UHPFRC box girders, reinforcement index does not determine the characteristic of behavior of UHPFRC box girder exactly. So the index should consider the dimension precisely and modify the reference value corresponding to the 0.005 strain of the prestressing strands.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.3
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• pp.290-297
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• 2017

The flexural behavior tests of UHPC segmental U-girder and composite U-girder which has 160MPa compressive strength and 15.4m length were carried out. The test variables are volume fraction of steel fibers and slab over the U-girder. Each U-girder has longitudinal re-bars in web and lower flange. PS tendons which has 2 of 15.2mm diameter in upper flange and PS tendons which has 7 of 15.2mm diameter in lower flange were arranged and prestressed at onetime in U-girder connection stage. Enough strong prestressing force which applied to U-girder due to ultra high performance concrete strength can withstand the self weight and dead load in U-girder stage. By comparison with the brittle behavior of U-girder, composite U-girder showed the stable and ductile behavior. After the construction of slab over U-girder, flexural load capacity of composite U-girder can bear the design load in final construction stage with only one time prestressing operation which already carried out in U-girder stage. This simple prestressing method due to the ultra high strength concrete have the advantage in construction step and cost. The shear key which has narrow space has the strong composite connection between ultra high strength concrete U-girder and high strength concrete slab didn't show any slip and opening right before failure load.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.3
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• pp.252-260
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• 2015

The aim of this research is providing the fundamental data for treating and recycling the byproducts by using the wet processed bottom ash as a fine aggregate replacement for cement-based extruded panel. Although the cement-based extruded panel was used mainly as a cladding component with its high strength and outstanding durability, it was hardly spread because of low economic feasibility due to the high cost of additives or fibers which were used to achieve 14 MPa of flexural strength as a cladding material. As a solution of this drawback, by the previous research, it was possible to replace cement by fly ash up to 80 % by decreasing quality criteria with restricting the application to indoor purpose. In this research, based on the previous research, by using the bottom ash as a replacement of fly ash, improvement of shape retention performance is tried. As a result of the experiment on evaluating the optimum content and PSD of bottom ash, as the fineness modulus and content of bottom ash was increased, the extruding performance was decreased and penetration resistance was increased. Additionally, the optimum content and the maximum particle size was found as 20 %, and 0.3 mm, respectively.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.363-370
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• 2016

Lightweight geopolymers are more readily produced and give higher fire resistant performance than foam cement concrete. Lowering the density of solid geopolymers can be achieved by inducing chemical reactions that entrain gases to foam the geopolymer structure. This paper reports on the effects of adding different concentrations of aluminum powder on the properties of cellular structured geopolymers. The apparent density of lightweight geopolymers has a range from 0.7 to $1.2g/m^3$ with 0.025, 0.05 and 0.10 wt% of a foaming agent concentration, which corresponds to about 37~60 % of the apparent density, $1.96g/cm^3$, of solid geopolymers. The compressive strength of cellular structured geopolymers decreased to 6~18 % of the compressive strength, 45 MPa of solid geopolymers. The microstructure of geopolymers gel was equivalent for both solid and cellular structured geopolymers. The workability of geopolymers with polyprophylene fibers needs to be improved as in fiber-reinforced cement concrete. The lightweight geopolymers could be used as indoor wall tile or board due to fire resistance and incombustibility of geopolymers.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.279-286
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• 2019

In this study, an experimental study on the tensile properties of steel fiber-reinforced ultra high strength concrete(UHSC) with a standard compressive strength of 180MPa was performed. Steel fibers with a volume ratio of 1% were mixed to prepare direct tensile strength specimens and prism specimens for the three-point bending test. The fabricated specimens were set up in the middle section of the specimen to induce cracks, and the test was carried out according to each evaluation method. First, the stress-strain curves were analyzed by performing direct tensile strength tests to investigate the behavior characteristics of concrete after cracking. In addition, the load-CMOD curve was obtained through the three-point bending test, and the inverse analysis was performed to evaluate the stress-strain curve. Tensile behavior characteristics of the direct tensile test and the three-point bending test of the indirect test were similar. In addition, the tensile stress-strain curve modeling presented in the SC structural design guidelines was performed, and the comparative analysis of the measured and predicted values was performed. When the material reduction factor of 1.0 was applied, the predicted value was similar to the measured value up to the strain of 0.02, but when the material reduction factor of 0.8 was applied, the predicted value was close to the lower limit of the measured value. In addition, when the strain was greater than 0.02, the predicted value by SC structural design guideline to underestimated the measured value.

• Resources Recycling
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• v.24 no.1
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• pp.58-65
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• 2015

Although Korea is a top market sharing and world leading producer and developer of flat panel display devices, relevant recycling technology is not up to her prestigious status. Besides, most of the waste glass arising from flat panel displays is currently land-filled. The present paper mainly reviews on development of recycling systems for waste TFT-LCD glass from end-of-life LCD TVs and monitors and TFT-LCD process waste of crushed glass particles with target end uses of raw material for high strength concrete pile and glass fibers, respectively. Waste LCD glass was recycled to fabricate ingredients for high strength concrete piles with enhanced physical properties and spherical foam products. The waste LCD glass recycling technology is already developed to fabricate long and short fibers at commercial level. In view of these, future R & D on waste LCD glass materials is to be directed toward implementation of commercial materials recycling system therefrom.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.1
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• pp.36-42
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• 1997

The fiber wall filling(FWF) technology, which is based on Precipitatin of fillers in the micropores of the cell wall structure of never-dried chemical pulp fiber, has been developed to improve filling and loading process in papermaking. In presenting FWF technique here, micropores of pulp fiber are first impregnated with an ionic solution of water soluble salt and consecutively impregnated with the second salt solution. This procedure generates an insoluble precipitate within the micropores of cell wall by chemical interaction of these two ionic salt solutions This is the first attempts to use FWF technology for the quality of waste paper grade which is recycled in papermaking, even though this FWF technology has been impressively improved for never-dried chemical pulp in filling and loading process of papermaking. The precipitated amount of CaCO$_3$ and SrCO$_3$ reached 5-6% and 4-5% of the waste paper weight respectively, which was measured by ash content of the burned waste paper fiber. On the other way the precipitated amounts of those materials impregnated into never-dried chemical pulp fiber have reached 17-18% and 16-18% respectively. The micropore loading technique gives optical and physical properties to the handsheets formed with celt-wall-filled fibers which are better than those handsheet properties resulting from conventional loading. The papers made from the cell-wall-filled pulps are stronger than those with the customary location of filler between the fibers.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.515-521
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• 2023

In this study, waste carbon fiber obtained by pyrolysis of carbon fiber reinforced plastic (CFRP) was used to produce carbon fluoride through vapor phase fluorination and recycled as a reducing electrode material for lithium primary batteries. First, the physicochemical properties of the waste carbon fiber obtained by pyrolysis were determined, and the structural and chemical properties of carbon fluoride were analyzed to evaluate the effect of vapor phase fluorination on the waste carbon fiber. XRD analysis confirmed that the hexagonal network carbon laminated structure (002 peak) of the waste carbon fiber was gradually converted into a carbon fluoride structure (CF_X, 001 peak) as the temperature of gas phase fluorination increased. The discharge capacity of the lithium primary battery produced using this carbon fluoride was up to 862 mAh/g. This was compared to the discharge capacity of carbon fluoride-based Li-ion batteries made of other carbon materials. These results suggest that carbon fluoride made from waste CFRP-based carbon fibers can be used as a reducing electrode material for Li-ion batteries.