• 제목/요약/키워드: Rechargeable Battery

Search Result 242, Processing Time 0.031 seconds

Preparation and Characterization of Microporous PVdF Membrane for Li-ion Rechargeable Battery (이차전지용 미세다공성 PVdF 분리막의 제조와 물성)

  • Nam, Sang-Yong;Yu, Dae-Hyun;Jeong, Mi-Ae;Rhim, Ji-Won;Byun, Hong-Sik;Jeong, Chul-Ho;Lee, Young-Moo;Seo, Myung-Su
    • Membrane Journal
    • /
    • v.17 no.3
    • /
    • pp.233-243
    • /
    • 2007
  • In this study, a separate. which is a microporous membrane based on poly(vinylidene fluoride)(PVdF) was prepared by phase inversion method. Being prepared by dissolving the PVdF in the N,N'-dimethylformamide(DMF) with mechanical stirring, the homogenous casting solution was cast onto a clean glass plate. Pore size and porosity of the membranes were controlled by changing preparation condition. The highest porosity of the membrane was 78.6%. The mechanical property of the membrane was determined by using an universal testing machine(UTM). The morphology of the membrane was investigated by scanning electron microscopy(SEM). The cross-section of the membrane shows sponge-like small micro-pores.

Electrochemical Characterization of Anodic Tin Oxides with Nano-Porous Structure (나노 구조를 가지는 다공성 주석 산화물의 전기화학적 특성)

  • Lee, Jae-Wook;Park, Su-Jin;Shin, Heon-Cheol
    • Korean Journal of Materials Research
    • /
    • v.21 no.1
    • /
    • pp.21-27
    • /
    • 2011
  • A nano-porous structure of tin oxide was prepared using an anodic oxidation process and the sample's electrochemical properties were evaluated for application as an anode in a rechargeable lithium battery. Microscopic images of the as-anodized sample indicated that it has a nano-porous structure with an average pore size of several tens of nanometers and a pore wall size of about 10 nanometers; the structural/compositional analyses proved that it is amorphous stannous oxide (SnO). The powder form of the as-anodized specimen was satisfactorily lithiated and delithiated as the anode in a lithium battery. Furthermore, it showed high initial reversible capacity and superior rate performance when compared to previous fabrication attempts. Its excellent electrode performance is probably due to the effective alleviation of strain arising from a cycling-induced large volume change and the short diffusion length of lithium through the nano-structured sample. To further enhance the rate performance, the attempt was made to create porous tin oxide film on copper substrate by anodizing the electrodeposited tin. Nevertheless, the full anodization of tin film on a copper substrate led to the mechanical disintegration of the anodic tin oxide, due most likely to the vigorous gas evolution and the surface oxidation of copper substrate. The adhesion of anodic tin oxide to the substrate, together with the initial reversibility and cycling stability, needs to be further improved for its application to high-power electrode materials in lithium batteries.

Electrochemical Properties of LiMn2O4-LiNi1/3Mn1/3Co1/3O2 Cathode Materials in Lithium Secondary Batteries (리튬이차전지 양극활물질용 LiMn2O4-LiNi1/3Mn1/3Co1/3O2의 전기화학적 특성)

  • Kong, Ming Zhe;Nguyen, Van Hiep;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.29 no.5
    • /
    • pp.298-302
    • /
    • 2016
  • In this work, $LiMn_2O_4$ and $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ cathode materials are mixed by some specific ratios to enhance the practical capacity, energy density and cycle performance of battery. At present, the most used cathode material in lithium ion batteries for EVs is spinel structure-type $LiMn_2O_4$. $LiMn_2O_4$ has advantages of high average voltage, excellent safety, environmental friendliness, and low cost. However, due to the low rechargeable capacity (120 mAh/g), it can not meet the requirement of high energy density for the EVs, resulting in limiting its development. The battery of $LiMn_2O_4-LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (50:50 wt%) mixed cathode delivers a energy density of 483.5 mWh/g at a current rate of 1.0 C. The accumulated capacity from $1^{st}$ to 150th cycles was 18.1 Ah/g when the battery is cycled at a current rate of 1.0 C in voltage range of 3.2~4.3 V.

Charge/discharge characteristics of $LiCoO_2$ thin film prepared by electron-beam evaporation with deposition rate and annealing temperatures (Electron-beam 증발법으로부터 증착속도 및 열처리 온도에 따른 $LiCoO_2$ 박막의 충방전 특성)

  • Nam S. C.;Cho W. I.;Cho B. W.;Yun K. S.;Chun H. S.
    • Journal of the Korean Electrochemical Society
    • /
    • v.2 no.1
    • /
    • pp.46-49
    • /
    • 1999
  • Lithium cobalt oxide cathode for thin-film rechargeable lithium batteries were fablicated by electron-beam evaporation. Annealed lithium cobalt oxide, which was deposited on to stainless steel substrate, showed well-developed (003) planes of the hexagonal structure and potential plateau at $\~3.9 V$. Lithium cobalt oxide thin films had the stoichiometric Li/co ratio at high deposition rates and exhibited high discharge capacity at $15{\AA}/s$. As the annealing temperature increased, discharge capacity increased with maximum value at $700^{\circ}C$, but showed low capacity as a result of reaction with substrate above $700^{\circ}C$. Unuiformity of the lithium and cobalt in the depth profile gave initial capacity loss with charge/discharge performance.

Increase in Discharge Capacity of Li Battery Assembled with Electrochemically Prepared V2O5/polypyrrole-composite-film Cathode

  • Kim, You-Na;Kim, Joo-Seong;Thieu, Minh-Triet;Dinh, Hung-Cuong;Yeo, In-Hyeong;Cho, Won-Il;Mho, Sun-Il
    • Bulletin of the Korean Chemical Society
    • /
    • v.31 no.11
    • /
    • pp.3109-3114
    • /
    • 2010
  • Flexible composite films of $V_2O_5$ and conductive polypyrrole ($V_2O_5$/PPy) were grown by facile electrochemical polymerization, wherein an anodization potential was applied to the substrate electrode in an electrolyte solution containing pyrrole monomer and dispersed $V_2O_5$ particles. The coating of polypyrrole (PPy) on the surface of $V_2O_5$ particles was induced by the oxidative catalytic action of $V_2O_5$ during the electrochemical polymerization of pyrrole. PPy in the composite film connects the isolated $V_2O_5$ particles. This results in the formation of conductive networks in the composite film cathode, thereby enhancing the Li+ ion diffusion to the surface of the isolated $V_2O_5$ particles and thus increasing the accessibility of the $Li^+$ ions. The specific capacity tests of the Li rechargeable batteries revealed that the discharge capacity of this composite film cathode was higher, i.e., $497\;mAhg^{-1}$, than that of $V_2O_5$/PPy powder or pristine $V_2O_5$.

Analysis of the Castalia Simulator to Implement User-friendly Simulator for Solar Energy Harvesting WSNs (사용자 친화형 태양 에너지 기반 센서 네트워크 시뮬레이터 구현을 위한 Castalia 시뮬레이터 분석)

  • Yi, Jun Min;Kang, Min Jae;Noh, Dong Kun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2013.10a
    • /
    • pp.743-746
    • /
    • 2013
  • Most of existing simulator for wireless sensor networks (WSNs) models the battery-based sensor and provides the MAC and routing protocols designed for the battery-based WSNs. Recently, however, as the energy harvesting sensor systems are studied widely, the require of the simulator for them is getting increased; but the related work is insignificant. Unlike the existing simulators, the simulator for the energy-harvesting WSNs requires the new energy model which is integrated with the energy-harvesting model, rechargeable battery model and energy-consuming model. Additionally, it should provide the well-known MAC and routing protocols designed for the energy-harvesting WSNs, and also provide the user-friendly interface for the convenient usage. In this work, we analysis the existing Castalia simulator and revise it for the user-friendly simulator for the solar energy harvesting WSNs.

  • PDF

Effect of Calcination Temperature of Size Controlled Microstructure of LiNi0.8Co0.15Al0.05O2 Cathode for Rechargeable Lithium Battery

  • Park, Tae-Jun;Lim, Jung-Bin;Son, Jong-Tae
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.2
    • /
    • pp.357-364
    • /
    • 2014
  • Size controlled, $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ cathode powders were prepared by co-precipitation method followed by heat treatment at temperatures between 750 and $850^{\circ}C$. The synthesized samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical performance. The synthesized $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ after calcined at $750^{\circ}C$ has a good electrochemical performance with an initial discharge capacity of $190mAhg^{-1}$ and good capacity retention of 100% after 30 cycles at 0.1C ($17mAg^{-1}$). The capacity retention of $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ after calcined at $750^{\circ}C$ is better than that at 800 and $850^{\circ}C$ without capacity loss at various high C rates. This is ascribed to the minimized cation disorder, a higher conductivity, and higher lithium ion diffusion coefficient ($D_{Li}$) observed in this material. In the differential scanning calorimetry DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by calcined at high temperature, and this decrease is especially at $850^{\circ}C$. This behavior implies that the high temperature calcinations of $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ prevent phase transitions with the release of oxygen.

Preparation and Characterization of PVdF-HFP Microporous Membranes for Li-ion Rechargeable Battery (Poly(vinylidene fluoride-hexafluoropropylene)를 이용한 이차전지용 미세다공성 분리막의 제조와 물성)

  • Nam, Sang-Yong;Yu, Dae-Hyun;Jeong, Mi-Ae;Rhim, Ji-Won;Byun, Hong-Sik;Yoo, Hyun-Oh;Kim, Jong-Man;Seo, Myung-Su
    • Membrane Journal
    • /
    • v.17 no.4
    • /
    • pp.359-368
    • /
    • 2007
  • The copolymer membranes, poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) were prepared by phase inversion method using as an additive with N,N-dimethylformamid as a solvent. The pores are generated during the solvent and non-solvent exchange process in the coagulation bath filled with non-solvent (distilled water). The highest porosity of the membrane was 60%. The surface and cross-section of the membranes was observed with a scanning electron microscopy (SEM). The mechanical property of the membrane was determined by using an universal testing machine (UTM). Tensile strength of measured membranes is presented the maximum 6.57 MPa at 30 wt% of PVdF-HFP.

An empirical study Influencing the Wireless Battery Charger on Choice to Repurchase Intention (무선 충전기가 스마트폰 재구매 선택을 결정하는 영향에 관한 실증적 연구)

  • Kim, Do-Goan
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2015.10a
    • /
    • pp.123-124
    • /
    • 2015
  • Recently, with the economy and the information communication technology developed, the smartphone market grows continuously. The market outlook on the wireless rechargeable technology grows rapidly so that the market size is increased about six times bigger than that of the last year, and it will grow about 18 billion dollars in 2014. Because of that, as the interest on this area out focused, many kinds of technology and new product are being exploited in this field. In this research, we aim to analyze factors influencing of the wireless battery charger on continue using intention of Smartphone. Predictor factors were selected perceived usefulness, perceived ease of use and perceived design suggested based extended the technology acceptance model. IBM SPSS Statistics 19 were employed for descriptive statistics, Smart PLS(partial least squares) was employed for confirmatory factor analysis and path analysis of casual relationship among variables and effect. This study suggests practical and theoretical implications based on the results.

  • PDF

A Study on the Power Feeding for ISDN Subscriber Loop (ISDN 가입자 선로에 대한 망급전 연구)

  • 한운영;남윤석;이홍우;차균현
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.19 no.12
    • /
    • pp.2508-2519
    • /
    • 1994
  • In this thesis, two possible schemes for power feeding are considered. The first one is the network power feeding, and the other is the power feeding from the rechargeable battery. Though each scheme has its merits and demerits, the domestic network operator has proposed the latter due to the large deviation of line resistance, high power loss, and safety. This scheme, however, has several problems. The usage is limited by the life of battery leading to the failure of minimal voice service for many hours. The space occupation of that battery is another serious problem. Moreover, the network opeator should have overhead of maintenance and repair. In order to alleviate such the difficulties, the sealing current is introduced through the subscriber loop. Flowing the current into the loop prevents from rusting. This thesis designs a power controller using PEB2025 to control various amount, duration, and period of this sealing current, to achieve the optimum current supply for sealing.

  • PDF