• Title/Summary/Keyword: Reaction stability

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ORTHODONTIC TREATMENT RELATED TO FACIAL PATTERNS (안모유형에 따른 교정치료)

  • Hwang, Chung-Ju
    • The korean journal of orthodontics
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    • v.18 no.2
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    • pp.475-488
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    • 1988
  • Certain malocclusion are associated with specific "facial type," and it is important for the clinician to classify the common facial characteristic of each patient. Because the reaction to treatment mechanics and the stability of the denture is depended upon the analysis of the facial pattern. Basically, there are 3 district facial types or patterns under which almost all malocclusion can be classified. 1. mesofacial is the most average growth. 2. brachyfacial which is a horizontal growth pattern has a week muscle, with dental arch, deep bite. 3. dolichofacial which is a vertical growth pattern has a strong muscle, narrow dental arch, open bite. Brachyfacial pattern show a resistant to mandibular rotation during treatment can accept a more protrusive denture and are prominantly nonextraction, whereas dolichofacial patterns tend to open during treatment require a more retracted denture in order to assure post-treatment stability. Brachyfacial pattern would better treat to use extrusive force system, whereas dolichofacial pattern treat to use intrusive force system with head gear and intermaxillary elastics.

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Charge Transport Properties of Polyaniline-gold/graphite Oxide Composite Films

  • Basavaraja, C.;Kim, Won-Jung;Thinh, P.X.;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.449-452
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    • 2012
  • A polyaniline-gold composite was prepared via the polymerization of aniline hydrochloride with or without water-soluble graphite oxide using auric acid as an oxidant. The reaction products were characterized using Xray photoelectron spectroscopy. The thermal stability and embedded crystallinity of the composites were also investigated using thermogravimetric and X-ray diffraction analyses. The electrical properties of the composites were examined using cyclic voltammetric measurements at room temperature and temperature-dependent DC conductivity within 300-500 K. Compared to pure graphene oxide and polyaniline-gold composite, the polyaniline-gold-graphene composite exhibited higher crystallinity and thermal stability, and higher current density response under equivalent conditions.

Stability of Photochromism in New Bifunctional Copolymers Containing Spiropyran and Chalcone Moiety in the Side Chain

  • Choi, Dong-Hoon;Ban, Si-Young;Kim, Jae-Hong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.441-445
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    • 2003
  • We synthesized three copolymers bearing photochromic spiropyran dye and chalcone moiety in the side chain for studying the dynamic properties of their photochromism. They contain methacrylate-spiropyran (MAspiropyran) and methacrylate-chalcone (MA-chalcone) with the different concentration. The photosensitivity of the newly synthesized copolymers was investigated by using UV-Vis absorption spectroscopy. We observed photodimerization and photochromic behavior under UV irradiation at the same time. The effect of photocrosslink on the rate and stability of photochromism in three copolymers was considered in this study. This study might be helpful to design photochromic materials for irreversible optical memory by virtue of photocrosslinking reaction.

Efficient Transdermal Penetration and Improved Stability of L-Ascorbic Acid Encapsulated in an Inorganic Nanocapsule

  • Yang, Jae-Hun;Lee, Sun-Young;Han, Yang-Su;Park, Kyoung-Chan;Choy, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.499-503
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    • 2003
  • Encapsulation of L-ascorbic acid (vitamin C) within a bio-compatible layered inorganic material was achieved by coprecipitation reaction, in which the layered inorganic lattice and its intercalate of vitamin C are simultaneously formed. The nano-meter sized powders of vitamin C intercalate thus prepared was again encapsulated with silica nano-sol to form a nanoporous shell structure. This ternary nanohybrid of vitamin Clayered inorganic core-$SiO_2$ shell exhibited an enhanced storage stability and a sustained releasing of vitamin C. Furthermore, the nano-encapsulation of vitamin C with inorganic mineral was very helpful in delivering vitamin C molecules into skin through stratum corneum, facilitating transdermal penetration of vitamin C in topical application.

A Numerical Study of the Flame Cell Dynamics in Opposed Nonpremixed Tubular Configuration (비예혼합 튜브형상내 화염셀의 거동에 대한 수치 해석적 연구)

  • Park, Hyunsu;Yoo, Chun Sang
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.175-178
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    • 2014
  • The flame cell dynamics in 2-D opposed nonpremixed tubular configuration was investigated using high-fidelity numerical simulations. The diffusive-thermal instability occurs as the $Damk{\ddot{o}}hler$ number, Da, approaches the 1-D extinction limit of the tubular flames and several flame cells are generated depending on Da, and flame radius. In general, the number of flame cells are found close to the largest wave number from the linear stability analysis. It was also found from the displacement speed analysis that during the local flame extinction and cell formation, negative edge flame speed is observed due to small gain from reaction compared to large loss from diffusion.

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Fabrication of Multi-Layered Graphenes/P(S-co-BA) Nanocomposite via Sudden Heating Heterocoagulation Process

  • Choi, JinKyu;Lee, Eun-Kyoung;Shim, Sang Eun
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.272-279
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    • 2017
  • The heterocoagulation of latex is a simple and useful method to fabricate various polymer nanocomposites in which a precise control of the colloid stability is essential. In this work, a multi-layered graphenes (MLGs)/poly(styrene-co-butyl acrylate) (P(S-co-BA)) nanocomposite having an excellent dispersion of MLGs was prepared via the sudden heating heterocoagulation process. The P(S-co-BA) component was obtained by emulsion polymerization. This process can effectively shorten the process and particles growth steps. The colloid stability of these dispersions was controlled by factors such as ionic charge, temperature, and reaction times. The influence of these factors on heterocoagulation was evaluated and the properties of the nanocomposites were investigated. The conductivity of the MLGs/P(S-co-BA) nanocomposites increased from -11.53 to -5.70 S/cm for an increase in MLG content from 0.01 to 5 wt%. Moreover, percolation threshold was observed in the case of 0.01 wt% MLGs.

A Study on Stability of the Container Crain with respect to the Direction of wind Load (풍향에 따른 고효율 갠트리 크레인의 안정성에 관한 연구)

  • Kwon S.K.;Han G.J.;Shim J.J.;Han D.S.;Lee S.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1984-1987
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    • 2005
  • This study evaluate the statical stability of the container crane with respect to the direction of wind load which is varied between $0^{\circ}$ and $180^{\circ}$ and its average velocity is 40m/s. Using wind experimental data and a formula of wind pressure, we figured out the wind load needed to perform a finite element analysis. And we can obtain the variation of reaction forces at each supporting point according to the direction of wind load.

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Stability of Red Ginseng Saponin in Aqueous Solution (홍삼사포닌의 수용액에서의 안정성)

  • Lee, Seung-Jin;Kim, Shin-Il;Kim, Kil-Soo
    • Journal of Pharmaceutical Investigation
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    • v.24 no.4
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    • pp.227-231
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    • 1994
  • The stability of red ginseng saponin in aqueous solution was studied with the acceleration test method. The degradation rate constant of ginsenoside Rb1, an index component of red ginseng saponin, was $2.371{\times}10^{-4}\;day^{-1}$ at $20^{\circ}C$, and the shelf-life was about 570 days. The pH-rate profile demonstrated that the most stable range was pH 6-8. Mannitol and benzyl alcohol, common excipients for injection, exerted no influence on the degradation reaction of ginsenoside Rb1.

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Effects of Light on Disassembly of Chloroplast during Senescence of Detached Leaves in Phaseolus vulgaris

  • Dong-Hee Lee;Jun
    • Journal of Environmental Science International
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    • v.1 no.2
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    • pp.69-80
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    • 1992
  • Effects of light on leaf senescence of Phseolus vulgaris were investigated by measuring the disassembly of chlorophyll-protein complexes in detached leaves which had been kept in the dark or under light. The loss of chlorophyll accompanied by degradation of chlorophyll- protein complexes. PSI (photosystem I) complex containing LHCI (light harvesting complex of PSI) apoproteins was rapidly decreased after the early stage of dark-induced senescence. RC(reaction center)-Cores was slightly increased until 4 d and slowly decreased thereafter. As disassembly of LHCII trimer progressed after the late stage of senescence, there was a steady increase in the relative amount of SC(small complex)-2 containing LHCII monomer. On the other hand, white and red light adaptation caused the structural stability of chlorophyll-protein complexes during dark-induced senescence. Particularly, red light was more effective in the retardation of LHCII breakdown than white light, whereas white light was slightly effect in protecting the disassembly of PSI complex compared to red light. These results suggest, therefore, that light may be a regulatory factor for stability of chlorophyll-protein complexes in the senescent leaves.

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정적 보행모델에 기반을 둔 4족 보행로봇의 온라인 틸팅 제어알고리즘

  • 이순걸;조창현;홍예선
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.3
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    • pp.83-91
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    • 2000
  • During static walking of a quadruped walking robot, stability of the robot depends on whether the projection of the mass center is located within the supporting area that is varying with leg motion and formed by standing legs. In this paper, force margin instead of the mass center was used to determine stability and body-tilting method was used to enhance it. On-line control of body tilting was realized with simple reaction feedback based on force margin of the static walking model of the robot instead of complicated calculation. Model reference on-line control where the model searches stable pose for predefined force margin also gave good walking performance.

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