• Title/Summary/Keyword: Reaction scheme

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Numerical Simulation of Unsteady CH$_4$/Air Jet Diffusion Flame (비정상 CH$_4$/공기 제트 확산화염에 관한 수치모사)

  • Lee, Chang-Eon;O, Chang-Bo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.8
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    • pp.1087-1096
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    • 2001
  • The dynamic structures of unsteady CH$_4$/Air jet diffusion flame with a flame-vortex interaction were numerically investigated. A timed-dependent, axisymmetric computational model and a low mach number approximation were employed in the present calculation. A two-step global reaction mechanism which considers 6 species, was used to calculate the reaction rates. The predicted results including the gravitational effect show that the large outer vortices and the small inner vortices can be well simulated without any additional disturbances near nozzle tip. It was found that the temperature and species concentrations have deviated values even for the same mixture fraction in the flame-vortex interaction region. It was also shown that the flame surface is not deformed by the inner vortex in upstream region, while in downstream region, the flame surface is compressed or stretched by the outer vortex roll-up. The present unsteady jet flame configuration accompanying a flame-vortex interaction is expected to give good implications for the unsteady structures of turbulent flames.

Synthesis of 2-n-Butyl-3-fluoropyrrole Derivatives

  • Kim, Bo-Mi;San, Quan-Ze;Bhatt, Lok Ranjan;Jung, Dong-Woon;Lee, Young-Hang;Chai, Kyu-Yun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1293-1296
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    • 2009
  • A new series of N-substituted 2-n-butyl-3-fluoropyrroles were prepared by a simple one-pot reaction designed of retrosynthesis. $\alpha,\alpha-Difluoro-\gamma-iodo-\gamma$-(trimethylsilyl)propyl n-butyl ketone, a component precursor molecule to 2-n-butyl-3-fluoropyrroles, was prepared with Cu(0) catalyst. It reacted with various primary amines to yield N-substituted 2-n-butyl-3-fluoropyrroles. The products were synthesized via a one-pot reaction scheme between $\alpha,\alpha-Difluoro-\gamma-iodo-\gamma$-(trimethylsilyl) propyl n-butyl ketone and primary amines in excess ( $\geq$ 5 molar equivalence), which eliminate the need of KF required in obtaining n-butyl-1H-3-fluoropyrrole. The yield of products depended reversely on spatial bulkness around N-binding carbon.

Low Temperature Methane Steam Reforming for Hydrogen Production for Fuel Cells

  • Roh, Hyun-Seog;Jun, Ki-Won
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.153-156
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    • 2009
  • Low temperature methane steam reforming to produce $H_2$ for fuel cells has been calculated thermodynamically considering both heat loss of the reformer and unreacted $H_2$ in fuel cell stack. According to the thermodynamic equilibrium analysis, it is possible to operate methane steam reforming at low temperatures. A scheme for the low temperature methane steam reforming to produce $H_2$ for fuel cells by burning both unconverted $CH_4$ and $H_2$ to supply the heat for steam methane reforming has been proposed. The calculated value of the heat balance temperature is strongly dependent upon the amount of unreacted $H_2$ and heat loss of the reformer. If unreacted $H_2$ increases, less methane is required because unreacted $H_2$ can be burned to supply the heat. As a consequence, it is suitable to increase the reaction temperature for getting higher $CH_4$ conversion and more $H_2$ for fuel cell stack. If heat loss increases from the reformer, it is necessary to supply more heat for the endothermic methane steam reforming reaction from burning unconverted $CH_4$, resulting in decreasing the reforming temperature. Experimentally, it has been confirmed that low temperature methane steam reforming is possible with stable activity.

Demand Response Based Optimal Microgrid Scheduling Problem Using A Multi-swarm Sine Cosine Algorithm

  • Chenye Qiu;Huixing Fang
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.18 no.8
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    • pp.2157-2177
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    • 2024
  • Demand response (DR) refers to the customers' active reaction with respect to the changes of market pricing or incentive policies. DR plays an important role in improving network reliability, minimizing operational cost and increasing end users' benefits. Hence, the integration of DR in the microgrid (MG) management is gaining increasing popularity nowadays. This paper proposes a day-ahead MG scheduling framework in conjunction with DR and investigates the impact of DR in optimizing load profile and reducing overall power generation costs. A linear responsive model considering time of use (TOU) price and incentive is developed to model the active reaction of customers' consumption behaviors. Thereafter, a novel multi-swarm sine cosine algorithm (MSCA) is proposed to optimize the total power generation costs in the framework. In the proposed MSCA, several sub-swarms search for better solutions simultaneously which is beneficial for improving the population diversity. A cooperative learning scheme is developed to realize knowledge dissemination in the population and a competitive substitution strategy is proposed to prevent local optima stagnation. The simulation results obtained by the proposed MSCA are compared with other meta-heuristic algorithms to show its effectiveness in reducing overall generation costs. The outcomes with and without DR suggest that the DR program can effectively reduce the total generation costs and improve the stability of the MG network.

Simulation of Vehicle-Structure Dynamic Interaction by Displacement Constraint Equations and Stabilized Penalty Method (변위제한조건식과 안정화된 Penalty방법에 의한 차량 주행에 따른 구조물의 동적상호작용 해석기법)

  • Chung, Keun Young;Lee, Sung Uk;Min, Kyung Ju
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4D
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    • pp.671-678
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    • 2006
  • In this study, to describe vehicle-structure dynamic interaction phenomena with 1/4 vehicle model, nonlinear Hertzian contact spring and nonlinear contact damper are adopted. The external loads acting on 1/4 vehicle model are selfweight of vehicle and geometry information of running surface. The constraint equation on contact surface is implemented by the Penalty method with stabilization and the reaction from constraint violation. To describe pitching motion of various vehicles two types of the displacement constraint equations are exerted to connect between car bodies and between bogie frames, i.e., the rigid body connection and the rigid body connection with pin, respectively. For the time integration of dynamic equations of vehicles and structure Newmark time integration scheme is adopted. To reduce the error caused by inadequate time step size, adaptive time-stepping technique is also adopted. Thus, it is expected that more versatile dynamic interaction phenomena can be described by this approach and it can be applied to various railway dynamic problems with low computational cost.

Kinetic Analysis of Energetic Materials Using Differential Scanning Calorimetry (DSC를 이용한 고에너지 물질의 반응속도식 추출과 활용)

  • Kim, Yoocheon;Park, Jungsoo;Yang, Seungho;Park, Honglae;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.33-41
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

Robust Position Control of a Reaction Wheel Inverted Pendulum (원판의 반작용을 이용한 역진자의 강인 자세 제어)

  • Park, Sang-Hyung;Lee, Hae-Chang;Lim, Seong-Muk;Kim, Jung-Su
    • Journal of the Korean Institute of Intelligent Systems
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    • v.26 no.2
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    • pp.127-134
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    • 2016
  • This paper presents a robust control of a reaction wheel inverted pendulum. To this end, a mathematical model is derived using physical laws, and then parameters in the model are identified as well. Based on the model, a robust position control is designed, which consists of two parts: swing-up control using passivity and robust stabilization control using LMI (Linear Matrix Inequality). When the pendulum starts to move, the swing-up control is applied. If the position of the pendulum is near the desired upright position, the control is switched to the robust stabilization control. This robust control is employed in order to deal with the uncertainties in the inertia of the pendulum dynamics. The performance of the proposed control scheme is validated not only simulation but also real experiment.

Geometric and mechanical properties evaluation of scaffolds for bone tissue applications designing by a reaction-diffusion models and manufactured with a material jetting system

  • Velasco, Marco A.;Lancheros, Yadira;Garzon-Alvarado, Diego A.
    • Journal of Computational Design and Engineering
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    • v.3 no.4
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    • pp.385-397
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    • 2016
  • Scaffolds are essential in bone tissue engineering, as they provide support to cells and growth factors necessary to regenerate tissue. In addition, they meet the mechanical function of the bone while it regenerates. Currently, the multiple methods for designing and manufacturing scaffolds are based on regular structures from a unit cell that repeats in a given domain. However, these methods do not resemble the actual structure of the trabecular bone which may work against osseous tissue regeneration. To explore the design of porous structures with similar mechanical properties to native bone, a geometric generation scheme from a reaction-diffusion model and its manufacturing via a material jetting system is proposed. This article presents the methodology used, the geometric characteristics and the modulus of elasticity of the scaffolds designed and manufactured. The method proposed shows its potential to generate structures that allow to control the basic scaffold properties for bone tissue engineering such as the width of the channels and porosity. The mechanical properties of our scaffolds are similar to trabecular tissue present in vertebrae and tibia bones. Tests on the manufactured scaffolds show that it is necessary to consider the orientation of the object relative to the printing system because the channel geometry, mechanical properties and roughness are heavily influenced by the position of the surface analyzed with respect to the printing axis. A possible line for future work may be the establishment of a set of guidelines to consider the effects of manufacturing processes in designing stages.

Numerical Study of Rocket Exhaust Plume with Equilibrium Chemical Reaction and Thermal Radiation (평형화학반응과 복사열전달을 고려한 로켓 플룸 유동 해석)

  • Shin J.-R.;Choi J.-Y.;Choi H.-S.
    • 한국전산유체공학회:학술대회논문집
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    • 2004.03a
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    • pp.146-153
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    • 2004
  • The Numerical study has been carried out to investigate the effects of chemical reaction and thermal radiation on the rocket plume flow-field at various altitudes. The theoretical formulation is based on the Navier-Stokes equations for compressible flows along with the infinitely fast chemistry and thermal radiation. The governing equations were solved by a finite volume fully-implicit TVD(Total Variation Diminishing) code which uses Roe's approximate Riemann solver and MUSCL(Monotone Upstream-centered Schemes for Conservation Laws) scheme. LU-SGS (Lower Upper Symmetric Gauss Seidel) method is used for the implicit solution strategy. An equilibrium chemistry module for hydrocarbon mixture with detailed thermo-chemical properties and a thermal radiation module for optically thin media were incorporated with the fluid dynamics code. In this study, kerosene-fueled rocket was assumed operating at O/F ratio of 2.34 with a nozzle expansion ratio of 6.14. Flight conditions considered were Mach number zero at ground level, Mach number 1.16 at altitude 5.06km and Mach number 2.9 at altitude 17.34km. Numerical results gave the understandings on the detailed plume structures at different altitude conditions. The diffusive effect of the thermal radiation on temperature field and the effect of chemical recombination during the expansion process could be also understood. By comparing the results from frozen flow and infinitely fast chemistry assumptions, the excess temperature of the exhaust gas resulting from the chemical recombination seems to be significant and cannot be neglected in the view point of performance, thermal protection and flow physics.

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Numerical Study on a Reaction Wheel and Wheel-Disturbance Modeling (반작용휠 및 휠 교란 모델링에 관한 해석적 연구)

  • Kim, Dae-Kwan;Oh, Shi-Hwan;Yong, Ki-Lyuk;Yang, Koon-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.7
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    • pp.702-708
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    • 2010
  • Reaction wheel assemblies(RWA) are expected to be one of the largest high frequency disturbance sources to the optical payload of satellites. To ensure the tight pointing-stability budget and high image quality of satellites, a vibration isolation device should be applied to the main disturbances. For developing the isolating system, the disturbances need to be identified and modeled accurately. In the present study, a modeling technique of RWA and its disturbance was described. The micro-vibration disturbances were generated numerically by using an analytical wheel and disturbance model. The parameter estimation scheme of the model was suggested, and the RWA and disturbance modeling technique was verified through the numerical example analysis. The analytical results show that the wheel and disturbance model can be accurately established by using the modeling technique proposed in the present study. The wheel and disturbance model is expected to be useful for development of the RWA isolator system.