• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.914-920
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• 2018

The intrinsic kinetic parameters of steam-methane reforming reactions over commercial nickel-based catalyst were determined. The reaction rate equations were derived from the reaction mechanism-based Langmuir-Hinshelwood chemisorption theory. As the experimental variables for the kinetic study, the reaction temperature ranged from 630 to $750^{\circ}C$ and the steam-to-carbon ratio also varied from 2.7 to 3.5. Based on the experimental data, the efficient optimization algorithm was used to determine the intrinsic kinetic parameters due to the high-dimensional objective function. It is confirmed that the parameter estimation results showed good agreement with the experimental values. Thus, this proposed mathematical reaction model can be used as the basic information to design a catalytic reactor and to optimize operating conditions.

• Journal of the Korean Society of Combustion
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• v.21 no.4
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• pp.23-29
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• 2016

Reactivity of gasification defined by bouardard reaction is critical parameter in efficiency of the gasifier. In this study, char reactivity of the gasification was derived from the experiments using the intrinsic reaction kinetics model. Pressurized wire mesh heating reactor (PWMR) can produce high temperature and high pressure conditions up to 50 atm and 1750 K, respectively and PWMR was designed to evaluate the intrinsic reaction kinetics of $CO_2$ gasification. In this study, Kideco and KCH (sub-bituminous Indonesian coal) were pulverized and converted into char. Experiments used the PWMR were conducted and the conditions of the temperature and pressure were 1373~1673 K, 1~40 atm. To distinguish the pressure effect from high pressurized condition, internal and external effectiveness factors were considered. Finally, the intrinsic kinetics of the Kideco and KCH coal char were derived from $n^{th}$ order reaction rate equations.

• Journal of Drive and Control
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• v.12 no.4
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• pp.35-40
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• 2015

A gas spring provides support force for lifting, positioning, lowering, and counterbalancing weights. It offers a wide range of reaction force with a flat force characteristic, simple mounting, compact size, speed controlled damping, and cushioned end motion. The most common usage is as a support on a horizontally hinged automotive tail gate. However, its versatility and ease of use has been applied in many other industrial applications ranging from office equipment to off-road vehicles. The cylinder of a gas spring is filled with compressed nitrogen gas, which is applied with equal pressure on both sides of the piston. The surface area of the rod side of the piston is smaller than the opposite side, producing a pushing force. The magnitude of the reaction force is determined by the cross-sectional area of the piston rod and the internal pressure inside the cylinder. The reaction force is influenced by many design parameters such as initial chamber volume, diameter ratio, etc. In this paper, we investigated the reaction force characteristics and carried out parameter sensitivity analysis for the design parameters of a gas spring.

• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.380-385
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• 2009

The absorption rate of carbon dioxide with 2-amino-2-methyl-1-propanol(AMP) was measured in such non-aqueous solvents as methanol, ethanol, n-propanol, n-butanol, ethylene glycol, propylene glycol, and propylene carbonate, and in water at 298 K and 101.3 kPa using a semi-batch stirred tank with a plane gas-liquid interface. The overall reaction rate constant, obtained under the condition of fast reaction regime, from the measured rate of absorption was used to get the elementary reaction rate constants in complicated reactions represented by reaction mechanism of carbamate formation and the order of overall reaction of $CO_2$ with amine. The correlation between the elementary reaction rate constant and the solubility parameter of the solvent was also presented.

• 한국연소학회:학술대회논문집
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• 1997.06a
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• pp.163-173
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• 1997

This article presents an application of a large-scale structural mixing model (Broadwell et al. 1984) to the blowout of turbulent reacting jets discharging perpendicularly into an unconfined cross air-flow. In an analysis of a common stability curve, a plausible explanation can be made that the phenomenon of blowout is related only to the mixing time scale of the two flows. The most notable observation is that the blowout distance is traced at fixed positions at all times according to the velocity ratio R. Measurements of the lower blowout limits in the liftable flame agree qualitatively with the blowout parameter ${\varepsilon}$, proposed by Broadwell et al. Good agreement between the results calculated by a modified blowout parameter ${\varepsilon}^'$ and experimental results confirms the important effect of a large-scale structure in specifying the stabilization feature of blowouts.

• Structural Engineering and Mechanics
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• v.37 no.1
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• pp.61-77
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• 2011

Static and dynamic responses of a completely free elastic beam resting on a two-parameter tensionless Pasternak foundation are investigated by assuming that the beam is symmetrically subjected to a uniformly distributed load and concentrated load at its middle. Governing equations of the problem are obtained and solved by paying attention on the boundary conditions of the problem including the concentrated edge foundation reaction in the case of complete contact and lift-off condition of the beam ina two-parameter foundation. The nonlinear governing equation of the problem is evaluated numerically by adopting an iterative procedure. Numerical results are presented in figures to demonstrate the non-linear behavior of the beam-foundation system for various values of the parameters of the problem comparatively by considering the static and dynamic loading cases.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2011.04a
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• pp.490-491
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• 2011

• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.163.2-163
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• 2002

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.3
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• pp.45-50
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• 2004

The design of reaction wheel control logic is critical to achieve the spacecraft attitude stabilization and performance requirements for the successful mission. Due to various uncertainties on orbit there exist limitation to obtain the model parameters through the ground tests and to design the associated control logic. Thus, the model parameter correction using on-orbit data is essential to the control performance on orbit. This paper performs the system identification using KOMPSAT-1 telemetry data and extracts the model parameters of the reaction wheel. Moreover, the reaction wheel is remodeled and compared with the ground test results.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.6
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• pp.1047-1052
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• 2002

The impact value, the interfacial shear strength, the tensile strength and the fracture strain of Nb/MoSi$_2$laminate composites, which were associated with the interfacial reaction layer, have been investigated. Three types of Nb/MoSi$_2$ laminate composites alternating sintered MoSi$_2$ layers and Nb foils were fabricated as the parameter of hot press temperature. The thickness of interfacial reaction layer of Nb/MoSi$_2$ laminate composites increased with increasing the fabrication temperature. The growth of interfacial reaction layer increased the interfacial shear strength and led to the decrease of impact value in Nb/MoSi$_2$ laminate composites. It was also found that in order to maximize the fracture energy of Nb/MoSi$_2$ laminate composites, interfacial shear strength and the thickness of interfacial reaction layer must be secured appropriately.