• Korean Chemical Engineering Research
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• 제56권6호
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• pp.914-920
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• 2018

본 연구에서는 상용 니켈-알루미나 촉매를 이용한 메탄가스-수증기 개질반응에서의 고유반응속도 상수를 결정하였다. 반응메커니즘을 반영하기 위해 Langmuir-Hinshelwood chemisorption 이론에 기반한 반응속도식을 사용하였고 반응온도($630{\sim}750^{\circ}C$) 및 반응물의 분압(S/C ratio = 2.7~3.5)을 실험변수로 설정하였다. 실험을 통해 얻어진 데이터를 기반으로 효율적인 최적화 알고리즘을 이용하여 최적 고유반응속도상수들을 결정하였다. 최종적으로 제안된 이 수학적 반응 모델은 촉매반응기의 설계 및 운전조건 최적화에 활용 가능하다.

• 한국연소학회지
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• 제21권4호
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• pp.23-29
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• 2016

Reactivity of gasification defined by bouardard reaction is critical parameter in efficiency of the gasifier. In this study, char reactivity of the gasification was derived from the experiments using the intrinsic reaction kinetics model. Pressurized wire mesh heating reactor (PWMR) can produce high temperature and high pressure conditions up to 50 atm and 1750 K, respectively and PWMR was designed to evaluate the intrinsic reaction kinetics of $CO_2$ gasification. In this study, Kideco and KCH (sub-bituminous Indonesian coal) were pulverized and converted into char. Experiments used the PWMR were conducted and the conditions of the temperature and pressure were 1373~1673 K, 1~40 atm. To distinguish the pressure effect from high pressurized condition, internal and external effectiveness factors were considered. Finally, the intrinsic kinetics of the Kideco and KCH coal char were derived from $n^{th}$ order reaction rate equations.

• 드라이브 ㆍ 컨트롤
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• 제12권4호
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• pp.35-40
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• 2015

A gas spring provides support force for lifting, positioning, lowering, and counterbalancing weights. It offers a wide range of reaction force with a flat force characteristic, simple mounting, compact size, speed controlled damping, and cushioned end motion. The most common usage is as a support on a horizontally hinged automotive tail gate. However, its versatility and ease of use has been applied in many other industrial applications ranging from office equipment to off-road vehicles. The cylinder of a gas spring is filled with compressed nitrogen gas, which is applied with equal pressure on both sides of the piston. The surface area of the rod side of the piston is smaller than the opposite side, producing a pushing force. The magnitude of the reaction force is determined by the cross-sectional area of the piston rod and the internal pressure inside the cylinder. The reaction force is influenced by many design parameters such as initial chamber volume, diameter ratio, etc. In this paper, we investigated the reaction force characteristics and carried out parameter sensitivity analysis for the design parameters of a gas spring.

• Korean Chemical Engineering Research
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• 제47권3호
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• pp.380-385
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• 2009

평판형 교반기를 사용하여 2-amino-2-methyl-1-propanol(AMP)가 용해된 methanol, ethanol, n-propanol, n-butanol, ethylene glycol, propylene glycol, 및 propylene carbonate와 같은 극성 용매에서 이산화탄소($CO_2$)의 흡수속도를 측정하였다. $CO_2$의 흡수속도와 carbamate 생성 반응 메커니즘을 사용하여 기-액 불균일반응계의 빠른 반응영역에서 $CO_2$-AMP의 반응속도론을 해석하였으며 용매의 용해도 매개변수와 반응속도상수와의 상관관계를 제시하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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• pp.163-173
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• 1997

This article presents an application of a large-scale structural mixing model (Broadwell et al. 1984) to the blowout of turbulent reacting jets discharging perpendicularly into an unconfined cross air-flow. In an analysis of a common stability curve, a plausible explanation can be made that the phenomenon of blowout is related only to the mixing time scale of the two flows. The most notable observation is that the blowout distance is traced at fixed positions at all times according to the velocity ratio R. Measurements of the lower blowout limits in the liftable flame agree qualitatively with the blowout parameter ${\varepsilon}$, proposed by Broadwell et al. Good agreement between the results calculated by a modified blowout parameter ${\varepsilon}^'$ and experimental results confirms the important effect of a large-scale structure in specifying the stabilization feature of blowouts.

• Structural Engineering and Mechanics
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• 제37권1호
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• pp.61-77
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• 2011

Static and dynamic responses of a completely free elastic beam resting on a two-parameter tensionless Pasternak foundation are investigated by assuming that the beam is symmetrically subjected to a uniformly distributed load and concentrated load at its middle. Governing equations of the problem are obtained and solved by paying attention on the boundary conditions of the problem including the concentrated edge foundation reaction in the case of complete contact and lift-off condition of the beam ina two-parameter foundation. The nonlinear governing equation of the problem is evaluated numerically by adopting an iterative procedure. Numerical results are presented in figures to demonstrate the non-linear behavior of the beam-foundation system for various values of the parameters of the problem comparatively by considering the static and dynamic loading cases.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2011년도 춘계학술대회 논문집
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• pp.490-491
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• 2011

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2002년도 추계총회 및 연구발표회 초록집
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• pp.163.2-163
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• 2002

• 한국항공우주학회지
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• 제32권3호
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• pp.45-50
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• 2004

위성의 성공적인 임무 수행을 위한 자세 안정화와 성능요구조건을 만족하기 위해서 반작용휠 제어로직의 설계가 중요하다. 실제 위성궤도 상에서 발생하는 여러 가지 불확실성으로 인해 지상실험을 통해 획득한 모델 파라미터 값들만으로 제어로직을 설계하는데 한계가 있다. 그러므로 위성이 궤도상에 있을 때의 반작용휠 입력 및 출력 데이터를 이용하여 모델 파라미터를 보정하고 자세제어기에 반영하는 것이 요구된다. 본 논문에서는 다목적실용위성의 Telemetry 데이터를 활용한 시스템인식 (System Identification)을 수행하였고, 이를 통한 반작용휠의 모델 파라미터를 추출한다. 또한, 반작용휠을 모델링 하고 또한 제어기설계에 사용된 모델 파라미터를 추출하여 지상실험 데이터와 비교분석한다.

• 대한기계학회논문집A
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• 제26권6호
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• pp.1047-1052
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• 2002

The impact value, the interfacial shear strength, the tensile strength and the fracture strain of Nb/MoSi$_2$laminate composites, which were associated with the interfacial reaction layer, have been investigated. Three types of Nb/MoSi$_2$ laminate composites alternating sintered MoSi$_2$ layers and Nb foils were fabricated as the parameter of hot press temperature. The thickness of interfacial reaction layer of Nb/MoSi$_2$ laminate composites increased with increasing the fabrication temperature. The growth of interfacial reaction layer increased the interfacial shear strength and led to the decrease of impact value in Nb/MoSi$_2$ laminate composites. It was also found that in order to maximize the fracture energy of Nb/MoSi$_2$ laminate composites, interfacial shear strength and the thickness of interfacial reaction layer must be secured appropriately.