• 방사성폐기물학회지
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• 제19권2호
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• pp.271-278
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• 2021

In this study, a chlorination technique for recycling Li₂ZrO₃, a reaction product of ZrO₂-assisted rinsing process, was investigated to minimize the generation of secondary radioactive pyroprocessing waste. It was found that the reaction temperature was a key parameter that determined the reaction rate and maximum conversion ratio. In the temperature range of 400-600℃, an increase in the reaction temperature resulted in a profound increase in the reaction rate. Hence, according to the experimental results, a reaction temperature of at least 450℃ was proposed to ensure a Li₂ZrO₃ conversion ratio that exceeded 80% within 8 h of the reaction time. The activation energy was found to be 102 ± 2 kJ·mol^-1·K^-1 between 450 and 500℃. The formation of LiCl and ZrO₂ as reaction products was confirmed by X-ray diffraction analysis. The experimental results obtained at various total flow rates revealed that the overall reaction rate depends on the Cl₂ mass transfer rate in the experimental condition. The results of this study prove that the chlorination technique provides a solution to minimize the amount of radioactive waste generated during the ZrO₂-assisted rinsing process.

• 항공우주기술
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• 제13권2호
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• pp.47-53
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• 2014

본 논문은 위성의 정밀 자세제어를 위해 사용하는 반작용 휠에 대한 소프트웨어 모델을 시뮬링크로 구현한 것에 대한 소개문서이다. 반작용 휠의 전기적인 특성 파라미터를 셋팅하고, 위성에 반작용 휠들이 장착되는 장착 각을 설정할 수 있는 기계적인 항목들 또한 포함하고 있다. 반작용 휠의 모델 방정식을 전기적 모터 방정식으로부터 유도하여, 이를 정리하였다. 또한, 구현한 반작용 휠 시뮬링크 모델을 강체에 적용하여 구동결과를 보여주고 있다.

• 한국세라믹학회지
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• 제33권9호
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• pp.1045-1049
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• 1996

Pressureless-sintered polycrystalline alumina and carbon steel were joined with Ag-33.5Cu-1.5Ti (wt%) brazing alloy. SEM observation revealed that two reaction layers with different thicknesses were continuously formed between the alumina and the brazing alloy. A thick layer formed on the brazing alloy side was identified as Ti3(Cu0.93Al0.07)3O phase with diamond cubic structure. Another thin layer adjacent to the alumina was revealed as $\delta$-TiO phase of which the crystal structure was HCP with a lattice parameter of a0=0.419 nm and c0=0.284 nm. It was confirmed using XPS analysis that $\delta$-TiO was formed directly by a redox reaction of alumina with titanium ir, molten brazing alloy.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제20권4호
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• pp.355-374
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• 2016

This work is devoted to investigate heat and mass transfer effects on MHD natural convection flow past an inclined plate with ramped temperature numerically. The dimensionless governing equations for this investigation are solved by using finite element method. The effects of angle inclination, buoyancy ratio parameter, permeability parameter, magnetic parameter, Prandtl number, heat generation, thermal radiation, Eckert number, Schmidt number, chemical reaction parameter and time on velocity, temperature and concentration fields are studied and presented with the aid of figures. The effects of the pertinent parameters on skin friction, rate of heat transfer and mass transfer coefficients are presented in tabular form. The numerical results are compared graphically with previously published result as special case of the present investigation and results found to be in good agreement.

• 한국진공학회지
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• 제4권3호
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• pp.334-341
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• 1995

IB-AI-VIB2 및 IB-AI-VIB2 :Co2+ 결정을 고순도 원소를 출발 물질로 하고 iodine을 수송 매체로 사용하여 chemical transport reaction method로 성장시켰다. 성장된 결정의 결정구조는 chalcopyrite 구조였으며, energy gap은 direct band gap으로 3.514~1.814 eV 정도로 주어졌으며, cobalt를 불순물로 첨가할 때 energy gap은 감소하였다. IB-AI-VIB2 :Co2+ 결정에서 첨가된 cobalt가 모체결정의 Td symmetry site에 Co2+ ion으로 위치하여, Co2+ ion의 energy 준위 사이의 전자전이에 기인하는 불순물 광흡수 peaks가 나타났다. 이 불순물 광흡수 peaks에 결정장 이론을 적용하여 구산 1st-order spin-orbit coupling parameter(λ)는 -183~ -189cm-1정도였고, 2nd-order spin-orbit coupling parameter(P)는 225~239 cm-1정도였으며, crystal field parameter(Dq)는 328~395cm-1, Racah parameter(B)는 531~552cm-1정도였다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제25권1호
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• pp.37-52
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• 2020

Sensitivity analysis of hydrodynamic and reaction parameters in conceptual model reflecting aquifer characteristics of Korea was performed to evaluate the uncertainty in the predicted concentrations. Among the hydrodynamic input parameters, both hydraulic conductivity (K_x) and hydraulic gradient (I) affected transport behaviors of contaminants, and resulted in same convergence concentrations with continuous injections of contaminant. However, longitudinal dispervisity (α_L) affected both transport behaviors and the convergence concentrations of contaminants. Compared to the hydrodynamic parameters, growth kinetic and degradation parameters (μ_m & K_c) more significantly affected both transport behaviors and the convergence concentrations of contaminants, indicating those parameters had higher sensitivity indices causing the uncertainties of model predictions. Considering that the sensitivity indices of both hydrodynamic and reaction parameters were a function of transport distance of groundwater, the parameters with higher sensitivity indices, a priori, need to be investigated using conceptual model reflecting site-specific aquifer characteristics before field investigation. After determining the parameters with higher sensitivity indices, the detail field investigations for the selected hydrodynamic and reaction parameters were warranted to reduce the uncertainties of model predictions.

• Bulletin of the Korean Chemical Society
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• 제21권1호
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• pp.49-55
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• 2000

A series of m-, and p-substituted phenyl 2-thiophenecarboxylates and benzoates was prepared by the reaction of the corresponding acyl chlorides and phenols. Their $^1H$ and $^{13}C$ NMR chemical shifts were analyzed using single substituent parameter (S SP) and dual substituent parameter (DSP) methods. The relative aromaticity index of thiophene was estimated to be 0.92 from the plot of the chemical shift of the carbonyl carbons of the thienoyl esters against chemical shift of the carbonyl carbons of the benzoyl esters.

• 한국환경과학회지
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• 제16권5호
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• pp.623-632
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• 2007

The objective of this study is analysis of Andong-Dam lake water quality with water quality model. Model parameters of the WASP applied to Lake Andong-Dam were estimated. The methodology is based on grouping water quality constituents and relevant parameters and successively estimating parameters by a trial-and-error procedure. Water qualify system for modeling consisted of BOD, DO, T-N, T-P. The results of water quality modelling using WASP. T-N was maximum affected by K71C(Organic nitrogen mineralization rate) parameter. T-P was maximum affected by K83C(Dissolved organic phosphorus mineralization) parameter, and It did not show a difference almost from the parameter of others and it omitted. BOD was maximum affected by Temperature parameter, it was visible of the reaction due to the KDC(Deoxygenation rate) in afterwords, and it did not show a difference from the parameter of others and it omitted. DO was maximum affect by Temperature parameter, and It did not show a difference almost from the parameter of others and it omitted. The parameter which it presumes from the this study uses a water quality modeling and Actual value and the result with which it compares, error rate the parameter presumption which is appropriate with 1% interior and exterior is investigated, It will reach and it uses and it will be able to apply to the suitable parameter in water quality modelling of the objective area which can be feeded by it becomes.

• 대한수학회논문집
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• 제14권2호
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• pp.441-447
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• 1999

A free boundary problem is derived from a singular limit system of a reaction diffusion equation whose reaction terms are bistable type. In this paper, we shall consider a free boundary problem with two layers satisfying the zero flux boundary condition and shall show that the Hopf bifurcation can not occur as a parameter varies.

• Journal of applied mathematics & informatics
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• 제27권3_4호
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• pp.517-529
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• 2009

In this paper, a singularly perturbed reaction-convection-diffusion problem with two parameters is considered. A parameter-uniform error bound for the numerical derivative is derived. The numerical method considered here is a standard finite difference scheme on piecewise-uniform Shishkin mesh, which is fitted to both boundary and initial layers. Numerical results are provided to illustrate the theoretical results.