• 제목/요약/키워드: Reaction parameter

검색결과 477건 처리시간 0.029초

Attitude Control of a Vehicle under the Disturbances by Sliding Mode Controller with Reaction Jets

  • Son, Sung-Han;Kim, Jinsu;Park, Kang-Bak;Teruo Tsuji;Tsuyoshi Hanamoto
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.166.6-166
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    • 2001
  • An attitude control of an air vehicle based on the variable structure control is proposed. For an air vehicle, minimum weight is required. Thus, it is desired to reduce the input energy. The optimal state portrait curve using time-varying sliding surface is proposed to reduce the control energy. Tracking performance of the closed loop system is guaranteed under the existence of parameter variation and external disturbances.

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BIFURCATIONS IN A HUMAN MIGRATION MODEL OF SCHEURLE-SEYDEL TYPE-II: ROTATING WAVES

  • Kovacs, Sandor
    • Journal of applied mathematics & informatics
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    • 제16권1_2호
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    • pp.69-78
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    • 2004
  • This paper treats the conditions for the existence of rotating wave solutions of a system modelling the behavior of students in graduate programs at neighbouring universities near each other which is a modified form of the model proposed by Scheurle and Seydel. We assume that both types of individuals are continuously distributed throughout a bounded two-dimension spatial domain of two types (circle and annulus), across whose boundaries there is no migration, and which simultaneously undergo simple (Fickian) diffusion. We will show that at a critical value of a system-parameter bifurcation takes place: a rotating wave solution arises.

SPATIAL INHOMOGENITY DUE TO TURING BIFURCATION IN A SYSTEM OF GIERER-MEINHARDT TYPE

  • Sandor, Kovacs
    • Journal of applied mathematics & informatics
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    • 제11권1_2호
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    • pp.125-141
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    • 2003
  • This paper treats the conditions for the existence and stability properties of stationary solutions of reaction-diffusion equations of Gierer-Meinhardt type, subject to Neumann boundary data. The domains in which diffusion takes place are of three types: a regular hexagon, a rectangle and an isosceles rectangular triangle. Considering one of the relevant features of the domains as a bifurcation parameter it will be shown that at a certain critical value a diffusion driven instability occurs and Turing bifurcation takes place: a pattern emerges.

Verification of Kinetic Theoretical Prediction of Diffusion-influenced Reversible

  • 양민오;신국재
    • Bulletin of the Korean Chemical Society
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    • 제21권1호
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    • pp.93-96
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    • 2000
  • A diffusion-influenced pseudo-first order reversible reaction A + B ⇔C + B is investigated by the molecular dynamics (MD) simulation method. Theoretical finding that the temporal evolution of reactants [conditional probabilities] in the reversible system can be expressed by the irreversible survival probability with an effective rate parameter is confirmed even in the presence of solvent particles. We carry out molecular dynamics simulations for both the irreversible and the reversible cases to evaluate the survival and the conditional probabilities for each cases. When the resultant irreversible survival probability is inserted into the proposed relation, the conditional probabilities given by the simulation are exactly reproduced.

Behavior and Analysis of Laterally Loaded Model Pile in Nak-dong River Fine Sand

  • Kim, Young-Su;Seo
    • 한국지반공학회지:지반
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    • 제14권3호
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    • pp.25-46
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    • 1998
  • 본 논문은 낙동강 유역의 사질토 지반에 매입되어 수평 하중을 받는 모형 강관 말뚝의 수평 거동의 결과를 관찰하였다. 본 연구의 목적은 말뚝의 수평 거동에 대한 말뚝의 근입길이, 지반 상대밀도, 하중 재하속도, 말뚝두부의 구속조건, 그리고 지반내의 이질층의 영향에 관하여 실험적인 연구를 수행하고 이러한 영향들을 정량화 할 수 있는 실험결과를 얻었다. 또한, 수치해석 (p-y method. modifiled Vlasov method, Characteristic Load Method:CLM) 결과들과 비교 되었다. 본 연구에서 Vlasov 해석법에 기초한 new parameter는 깊이에 비례하는 지반반력 (KhD=nhizn)에 대하여 적용할 수 있도록 개발하였다. p-V해석 모델은 비선형 거동이며, 수평하중을 받는 깊은 기초의 설계에 유효한 방법이다. Characteristic load method (CLM)이라 불 리는 새로운 방법은 P-V해석법 보다 간편하며, p-V해석법에 의한 결과와 잘 일치하고 있다. CLM방법은 무차훤 변수들의 관계들로부터 수평 하중을 받는 말뚝들의 비선형 거동을 특성화 하기 위하여 차원 해석을 이용하고 있다. p-y해석법과 수정 Vlasov방법에 이용하는 지반반력 계수와 극한 지반반력들은 직접 전단시험 결과들을 역 해석하여 구하였다. 직접전단 시험에 의한 지반반력 계수와 극한 지반반력들의 수평거동 예측에 이용하기 위한 수정계수들은 각각 0.014~0.05, 0.2~0.4로 나타났다. p-y analysis. modified Vlasov method (new ${\gamma}$ parameter), CLM에 의한 수치해석 결과들은 상대밀도가 증가할수록 실험결과들과 잘 일치하는 것으로 나타났다. 또한 y/D=0.2 이하에서 CLM 방법의 적용성이 입증되었다.

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Fertilization Promoting Peptide가 사람 정자의 운동양태, 수정능력획득 및 첨체반응에 미치는 영향 (Effect of Fertilization Promoting Peptide on Kinematic Parameters, Capacitation and Acrosome Reaction in Human Spermatozoa)

  • 강희규;김묘경;김동훈;한성원;최도연;이호준;김문규
    • Clinical and Experimental Reproductive Medicine
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    • 제27권2호
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    • pp.201-209
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    • 2000
  • Objective: This study has been carried out to evaluation the effect of fertilization promoting peptide (FPP) on the kinematic parameters, capacitation and acrosome reaction of the frozen-thawed human spermatozoa. Methods: After FPP treatment, we examined kinematic parameters, capacitation and acrosome reaction, using the methods of computer-aided sperm analysis (CASA) and chlortetracycline (CTC) fluorescence analysis. Results: We have obtained the evidence that FPP can promote the capacitation and inhibit the spontaneous acrosome reaction of frozen-thawed human spermatozoa in vitro. FPP ($25{\sim}100$ nM) induced a significant increase in the proportion of B-pattem capacitated spermatozoa, and a significant decrease in the proportion of F-pattem uncapacitated ones without significant stimulation of acrosomal exocytosis. In the kinematic parameters treatment, FPP treated groups maint3ined higher LIN, BCF and STR than those of control. The VAP, VSL, VCL and ALH were not different. Therefore it is suggested that FPP in human seminal plasma may play a positive role in promoting human sperm function.

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Some Calculated (p,α) Cross-Sections Using the Alpha Particle Knock-On and Triton Pick-Up Reaction Mechanisms: An Optimisation of the Single-Step Feshbache-Kermane-Koonin (FKK) Theory

  • Olise, Felix S.;Ajala, Afis;Olaniyi, Hezekiah B.
    • Nuclear Engineering and Technology
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    • 제48권2호
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    • pp.482-494
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    • 2016
  • The Feshbache-Kermane-Koonin (FKK) multi-step direct (MSD) theory of pre-equilibrium reactions has been used to compute the single-step cross-sections for some (p,${\alpha}$) reactions using the knock-on and pick-up reaction mechanisms at two incident proton energies. For the knock-on mechanism, the reaction was assumed to have taken place by the direct ejection of a preformed alpha cluster in a shell-model state of the target. But the reaction was assumed to have taken place by the pick-up of a preformed triton cluster (also bound in a shell-model state of the target core) by the incident proton for the pick-up mechanism. The Yukawa forms of potential were used for the proton-alpha (for the knock-on process) and proton-triton (for the pick-up process) interaction and several parameter sets for the proton and alpha-particle optical potentials. The calculated cross-sections for both mechanisms gave satisfactory fits to the experimental data. Furthermore, it has been shown that some combinations of the calculated distorted wave Born approximation cross-sections for the two reaction mechanisms in the FKK MSD theory are able to give better fits to the experimental data, especially in terms of range of agreement. In addition, the theory has been observed to be valid over a wider range of energy.

겔화 반응 시간 조절을 통한 상온에서의 폴리우레탄 폼 합성 (Synthesis of Polyurethane Foam at Room Temperature by Controlling the Gelling Reaction Time)

  • 이호준;오충익;;김소연;한영준;오민석;주형욱;장수호;홍승범
    • 공업화학
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    • 제31권6호
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    • pp.630-634
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    • 2020
  • We developed a processing recipe to synthesize flexible polyurethane foam with a pore size of 335 ± 107 ㎛. The gelling reaction time was varied from 0 to 30 minutes and the physical properties of the foam were evaluated. The gelling reaction where the polypropylene glycol and tolylene 2,4-diisocyanate (TDI) were reacted to form urethane prepolymer, proceeded until a chemical blowing agent, deionized water, was introduced. Fourier transform infrared (FT-IR) spectra showed that the composition of the foam did not change but the foam height reached a peak value when the gelling reaction time was 10 minutes. We found that increasing the gelling time lessened the coalescence and helped the formation of cells. Lastly, the repeatability of polyurethane foam was confirmed by one-way analysis of variance (ANOVA) by synthesizing ten identical polyurethane foams under the same experimental conditions, including the gelling reaction time. Overall, the new time parameter in-between the gelling and blowing reactions will give extra stability in manufacturing identical polyurethane foams and can be applied to various polyurethane foam processes.

졸-겔법에 의한 TiO2미분말 합성과 반응메카니즘(II): Titanium n-propoxide의 가수분해 (Synthesis of TiO2 Fine Powder by Sol-Gel Process and Reaction Mechanism(II) : Hydrolysis of Titanium n-Propoxide)

  • 명중재;박진구;정용선;경진범;김호건
    • 공업화학
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    • 제8권5호
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    • pp.777-783
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    • 1997
  • n-propanol 용매내에서 titanium n-propoxide($Ti(O^nPr)_4$)의 가수분해반응에 의하여 $TiO_2$ 미분말을 합성하였고, 가수분해속도를 자외선 분광법에 의하여 측정하였다. 분말합성은 water/alkoxide의 농도비가 약 300정도에서 실시하였으며, 물농도, 반응온도, 반응시간 및 반응용액의 산 염기효과에 의한 합성조건을 조사하였다. 반응은 $Ti(O^nPr)_4$의 농도에 비하여 물농도를 과량으로 하여 유사일차반응으로 진행시켰고, 반응속도상수를 Guggenheim method로 계산하였다. 또한 물의 동위원소효과($D_2O$)를 측정하여 반응에 관여하는 물분자의 촉매성을 확인하였다. 실험결과 중성 및 염기성 용액 조건에서 $TiO_2$미분말이 합성되었고, 미세구조 관찰로부터 $TiO_2$입자는 직경 $0.4-0.7{\mu}m$ 정도의 구형입자로 확인되었으며, 물의 농도와 반응온도가 증가할수록, 반응시간이 감소할수록 입자크기는 작아지는 경향을 보였다. 물의 동위원소효과로부터, 물분자는 nucleophilic catalysis로 작용하고 있으며, 반응속도로부터 전이상태에 참여하는 n-value와 열역학적 파라미터를 계산한 결과, $Ti(O^nPr)_4$의 가수분해반응은 이분자 반응인 associative $S_N2$ mechanism으로 진행하는 것으로 추정되었다.

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Dynamic Modeling of Lactic Acid Fermentation Metabolism with Lactococcus lactis

  • Oh, Euh-Lim;Lu, Mingshou;Choi, Woo-Joo;Park, Chang-Hun;Oh, Han-Bin;Lee, Sang-Yup;Lee, Jin-Won
    • Journal of Microbiology and Biotechnology
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    • 제21권2호
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    • pp.162-169
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    • 2011
  • A dynamic model of lactic acid fermentation using Lactococcus lactis was constructed, and a metabolic flux analysis (MFA) and metabolic control analysis (MCA) were performed to reveal an intensive metabolic understanding of lactic acid bacteria (LAB). The parameter estimation was conducted with COPASI software to construct a more accurate metabolic model. The experimental data used in the parameter estimation were obtained from an LC-MS/MS analysis and time-course simulation study. The MFA results were a reasonable explanation of the experimental data. Through the parameter estimation, the metabolic system of lactic acid bacteria can be thoroughly understood through comparisons with the original parameters. The coefficients derived from the MCA indicated that the reaction rate of L-lactate dehydrogenase was activated by fructose 1,6-bisphosphate and pyruvate, and pyruvate appeared to be a stronger activator of L-lactate dehydrogenase than fructose 1,6-bisphosphate. Additionally, pyruvate acted as an inhibitor to pyruvate kinase and the phosphotransferase system. Glucose 6-phosphate and phosphoenolpyruvate showed activation effects on pyruvate kinase. Hexose transporter was the strongest effector on the flux through L-lactate dehydrogenase. The concentration control coefficient (CCC) showed similar results to the flux control coefficient (FCC).