• Title/Summary/Keyword: Reaction parameter

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End-Gas Temperature Measurments in a DOHC Spark-Ignition Engine Using CARS (CARS를 이용한 DOHC 스파크 점화 기관의 말단 가스 온도 측정)

  • 최인용;전광민;박철웅;한재원
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.7
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    • pp.122-128
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    • 1999
  • CARS(Coherent anti-Stokes Raman Spectroscopy) temperature measurement under engine-like condition was validated by measuring unburned gas temperatures of premixed propane-air flame in a constant volume combustion chamber. The measured temperatures were compared with predictions of 2 zone flame propagation model. End-gas temperatures were measured were measured by CARS technique in a conventional 4 cylinder DOHC spark-ignition engine fueled with PRF 80. Cylinder pressure was measured simultaneously with CARS signal and used as a parameter on fitting CARS spectrum to library of theoretical spectra. There was a good agreement between the measured temperature and adiabatic core temperature calculated from measured cylinder pressure. Significant heating by pre-flame reaction in the gas was observed in the late part of compression stroke.

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Synthesis and Coloration Control of α-FeOOH Rods using Closed System

  • Yu, Ri;Lee, NaRi;Kim, YooJin
    • Journal of the Korean Ceramic Society
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    • v.56 no.3
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    • pp.298-301
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    • 2019
  • This paper details the synthesis of α-FeOOH (goethite) rods through the reaction of iron (III) nitrate with KOH as a strong base, and shape control of the particles for use as a yellow inorganic pigment. The crystal phase of the α-FeOOH crystal with OH content according to the addition of KOH and the change in morphology were investigated. The optical properties varied with the aspect ratios, and the yellowness increased with increasing aspect ratio. However, the enhanced chromaticity characteristics reversed beyond a certain critical aspect ratio. Thus, the relative optimal aspect ratio of the α-FeOOH rods as a vivid yellow inorganic pigment was derived. The morphology and coloration of the prepared rods were investigated in detail using X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis spectroscopy, and CIE Lab color parameter measurements.

Optimization of Quartz Crystal Microbalance-Precipitation Sensor Measuring Acetylcholinesterase Activity

  • Kim, Nam-Soo;Park, In-Seon;Kim, Dong-Kyung
    • Journal of Microbiology and Biotechnology
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    • v.16 no.10
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    • pp.1523-1528
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    • 2006
  • The optimization of a batch-type quartz crystal microbalance (QCM)-precipitation sensor measuring acetylcholinesterase (AChE) activity was conducted. To covalently bind AChE onto the gold electrode of a QCM surface, glutaraldehyde cross-linking to a cystamine self-assembled monolayer was tried at different cystamine concentrations. At the optimum conditions of the QCM-precipitation sensor, 0.1 M potassium phosphate buffer (pH 8.0), containing 0.01% Tween 80, was used as the reaction buffer, with the enzyme amount of 5 units for immobilization and the substrate concentration of 50 mg/ml. The current biosensor might find a future applicability to the sum parameter detection on organophosphorus and carbamate pesticides.

Electrochemical Properties of Polypyrrole Nanotubules Enzyme Electrode Immobilized with Glucose Oxidase (포도당 산화효소가 고정화된 Popyrrole Nanotubules 효소전극의 전기화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.909-912
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    • 2000
  • We synthesized polypyrrole (PPy) nanotubules by oxidative polymerization of the pyrrole monomer within the pores of a polycarbonate template. The electrochemical behavior was investigated using cyclic voltammetry. The redox potential was about -0.5 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for PPy film. It is considered as the backbone grows according to the pore wall. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. By electrochemical doping of glucose oxidase (GOx) on PPy nanotubules, an enzyme electrode has been fabricated. The kinetic parameter of biochemical reaction with glucose was evaluated. The formal Michaelis constant and maximum current calculated by computer were about 11.4 mmol $dm^3$ and 170.85 A respectively. Obviously, an affinity for the substrate and current response of the PPy nanotubules enzyme electrode are rather good, comparing with that of PPy film.

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Power Conversion and Design of Permanent Magnet Generator for Wind Power Applications (영구자석형 풍력용 발전기의 설계 및 전력 변환)

  • Jang, Seok-Myeong;Choi, Jang-Young;Cho, Han-Wook;Yoon, Ki-Kab;Kim, Byeong-Han;Kyung, Nam-Ho;Jeong, Sang-Sub
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1756-1758
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    • 2005
  • This paper deals with the power conversion and design of permanent magnet generator for wind power applications. This paper derives analytical solutions for open-circuit field, armature reaction field, torque, back-emf, inductance and resistance of permanent magnet generators for wind power applications. And then, by presenting the variation of torque according to design parameters and by applying restrict conditions to it, we determine proper design parameter appropriate to rated power and speed. Finally, this paper also presents power conversion system resonable in wind power applications.

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A Study on the Realization of the High Efficiency LCD Photoresist Removal Technology (고효율 LCD 감광막 제거기술 구현 연구)

  • Son, Young-Su;Ham, Sang-Yong;Kim, Byoung-Inn;Lee, Sung-Hwee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.11
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    • pp.977-982
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    • 2007
  • The realization of the photoresist(PR) removal method with vaporized water and ozone gas mixture has been studied for the LCD TFT array manufacturing. The developed PR stripper uses the water boundary layer control method based on the high concentration ozone production technology. We develop the prototype of PR stripper and experiment to find the optimal process parameter condition like as the ozone gas flow/concentration, process reaction time and thin boundary layer formation. As a results, we realize the LCD PR strip rate over the 0.4 ${\mu}m/min$ and this PR removal rate is more than 5 times higher than the conventional immersion type ozonized water process.

An Electrical Characteristics Analysis of Electronic Blood Pressure Depressor (전자혈압강하기의 전기적 특성 분석)

  • Lee, K.S.;Suh, J.H.;Lee, J.W.
    • Journal of Power System Engineering
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    • v.10 no.1
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    • pp.83-89
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    • 2006
  • Recently, the seriousness of high blood pressure was appeared as the most frequent disease of a the whole sickness in the world. However, the treatment of this disease is uncertain and produces an adverse reaction of a medicine therapy. Also, the patients are burdened with a fee for medical treatment. Therefore, in this paper, we studied effectively and financially to execute the treatment of high blood pressure using the Chinese medicine theorem that is recently arousing the great interest of the people. The main theories in this paper are blood vessel theory and acupuncture, respectively. Especially, the composed circuit systems are classified the blood pressure depressor part and the meridian points discrimination part, respectively. The blood pressure depressor part is composed generally of low-frequency generation circuit, charging-discharging circuit, and micro-computer circuit. Finally, this research have the advantage of discrimination parts such as regular voltage generating circuit, stimulus circuit, amplifying circuit, and alarm circuit.

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Kinetic Approaches to Measuring Peroxiredoxin Reactivity

  • Winterbourn, Christine C.;Peskin, Alexander V.
    • Molecules and Cells
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    • v.39 no.1
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    • pp.26-30
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    • 2016
  • Peroxiredoxins are ubiquitous thiol proteins that catalyse the breakdown of peroxides and regulate redox activity in the cell. Kinetic analysis of their reactions is required in order to identify substrate preferences, to understand how molecular structure affects activity and to establish their physiological functions. Various approaches can be taken, including the measurement of rates of individual steps in the reaction pathway by stopped flow or competitive kinetics, classical enzymatic analysis and measurement of peroxidase activity. Each methodology has its strengths and they can often give complementary information. However, it is important to understand the experimental conditions of the assay so as to interpret correctly what parameter is being measured. This brief review discusses different kinetic approaches and the information that can be obtained from them.

Separation of Palladium(II) and Ruthenium(IV) from Hydrochloric Acid Solution by Solvent Extraction (염산용액에서 용매추출에 의한 팔라듐(II)과 루테늄(IV)의 분리)

  • Lee, Man-seung;Ahn, Jong-Gwan
    • Korean Journal of Metals and Materials
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    • v.47 no.6
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    • pp.349-355
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    • 2009
  • In the solvent extraction of Ru(IV) with Alamine336, it was found that Ru took part in the reaction as $RuCl_{6}_^{2-}$ in the HCl concentration range of 1 to 5 M. Interaction parameter between hydrogen ion and $RuCl_{6}_^{2-}$ was estimated by applying Bromley equation to the extraction data. From the mixed solutions of Pd(II) and Ru(IV), the distribution coefficients of Pd were found to be higher than those of Ru in the experimental ranges. Separation factor between Pd and Ru rapidly increased with the decrease of Alamine336 concentration. About 60% of the Ru from the mixed solutions was extracted by TBP at 8.3 M HCl, while Pd was not extracted in the HCl concentration range of 1.6 to 8.3 M.

UNIFORMLY CONVERGENT NUMERICAL SCHEME FOR A SINGULARLY PERTURBED DIFFERENTIAL-DIFFERENCE EQUATIONS ARISING IN COMPUTATIONAL NEUROSCIENCE

  • DABA, IMIRU TAKELE;DURESSA, GEMECHIS FILE
    • Journal of applied mathematics & informatics
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    • v.39 no.5_6
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    • pp.655-676
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    • 2021
  • A parameter uniform numerical scheme is proposed for solving singularly perturbed parabolic partial differential-difference convection-diffusion equations with a small delay and advance parameters in reaction terms and spatial variable. Taylor's series expansion is applied to approximate problems with the delay and advance terms. The resulting singularly perturbed parabolic convection-diffusion equation is solved by utilizing the implicit Euler method for the temporal discretization and finite difference method for the spatial discretization on a uniform mesh. The proposed numerical scheme is shown to be an ε-uniformly convergent accurate of the first order in time and second-order in space directions. The efficiency of the scheme is proved by some numerical experiments and by comparing the results with other results. It has been found that the proposed numerical scheme gives a more accurate approximate solution than some available numerical methods in the literature.