• Title/Summary/Keyword: Reaction modulus

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Curing Behaviors and Mechanical Properties of Unsaturated Polyester Hosing with Different Glycol Molar Ratios (글리콜 몰비가 다른 UPE 수지의 경화거동과 물성에 관한 연구)

  • 이상효;이장우
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.599-609
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    • 2000
  • In order to improve the mechanical properties of unsaturated polyester (UPE) resins, the UPE resins with different glycol molar ratios were prepared. The effects of molar ratios of the UPE resins on the curing behaviors and mechanical properties were investigated. The microgel reaction mechanism was employed to characterize the system. It was found that the final conversion increased with increasing NPG molar ratios, and the conversion at the peak of differential scanning calorimetry (DSC) thermogram appeared to decrease with increasing NPG molar ratios. The flexural strength, tensile modulus, water resistance, and infiltration increased with increasing NPG content, but the tensile strength, tensile elongation, and flexural modulus decreased. Among the UPE resins prepared from the glycols with the molar ratios (PG/NPG) of 0.5/0.5, 0.25/0.75, those of laminated composites plates showed better mechanical properties.

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A Method for Evaluation of Hollow Existence in Sublayers of Concrete Pavement Considering Pavement Stiffness (포장강성을 고려한 콘크리트 포장하부 공동유무 평가방법)

  • Sohn, Dueck Su;Lee, Jae Hoon;Jeong, Ho Seong;Park, Joo Young;Jeong, Jin Hoon
    • International Journal of Highway Engineering
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    • v.15 no.1
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    • pp.95-102
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    • 2013
  • PURPOSES: The existing method evaluating the existence of the hollows in concrete pavement does not consider the stiffness of pavement. In addition, the method uses unreasonable logic judging the hollow existence by the deflection caused by zero loading. In this study, the deflection of slab corner due to heavy weight deflectometer (HWD) was measured in concrete pavement sections where underground structures are located causing the hollows around them. METHODS: The modulus of subgrade reaction obtained by comparing the actual deflection of slab to the result of finite element analysis was calibrated into the composite modulus of subgrade reaction. The radius of relative stiffness was calculated, and the relationship between the ratio of HWD load to the radius of relative stiffness and the slab deflection was expressed as the curve of secondary degree. RESULTS: The trends of the model coefficients showing width and maximum value of the curve of secondary degree were analyzed by categorizing the pavement sections into three groups : hollows exist, additional investigation is necessary, and hollows do not exist. CONCLUSIONS: The results analyzed by the method developed in this study was compared to the results analyzed by existing method. The model developed in this study will be verified by analyzing the data obtained in other sections with different pavement structure and materials.

Prediction of the Natural Frequency of a Soil-Pile-Structure System during an earthquake (지진하중을 받는 말뚝 시스템의 고유 진동수 예측)

  • Yang, Eui-Kyu;Kwon, Seon-Yong;Choi, Jung-In;Kim, Myoung-Mo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.976-984
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    • 2009
  • This study proposes a simple method that uses a simple mass-spring model to predict the natural frequency of a soil-pile-structure system in sandy soil. This model includes a pair of matrixes, i.e., a mass matrix and a stiffness matrix. The mass matrix is comprised of the masses of the pile and superstructure, and the stiffness matrix is comprised of the stiffness of the pile and the spring coefficients between the pile and soil. The key issue in the evaluation of the natural frequency of a soil-pile system is the determination of the spring coefficient between the pile and soil. To determine the reasonable spring coefficient, subgrade reaction modulus, nonlinear p-y curves and elastic modulus of the soil were utilized. The location of the spring was also varied with consideration of the infinite depth of the pile. The natural frequencies calculated by using the mass-spring model were compared with those obtained from 1-g shaking table model pile tests. The comparison showed that the calculated natural frequencies match well with the results of the 1-g shaking table tests within the range of computational error when the three springs, whose coefficients were calculated using Reese's(1974) subgrade reaction modulus and Yang's (2009) dynamic p-y backbone curves, were located above the infinite depth of the pile.

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The Effects of Cure System on Vulcanization Reaction Constant and Physical Properties of Rubber Compounds (가황시스템 변화가 배합고무의 가황반응속도 및 물리적 특성에 미치는 영향)

  • Lee, Seag;Park, Nam Cook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.419-426
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    • 1999
  • In this study, the reaction rate constant, activation energy, total crosslinking density, elastic constant, cure properties ($t_5,\;t_{90}$), modulus, and abrasion resistance of rubber compounds were investigated as a function of cure temperatures, cure systems and reinforcing filler loadings. Reaction rate constants showed strong dependence on thc carbon black loading, cure temperature and cure system, and increased sharply with increasing the reaction temperatures. The lowest activation energy was obtained in the efficient cure (EC) system which corresponds to the high level of sulfur to accelerator ratio, and the activation energy was decreased with decreasing the carbon black loadings. The change of carbon black loadings directly affects the modulus and abrasion resistance, but the change of cure system showed various effects on the rubber compounds. Increased carbon black loadings showed the high modulus, improved abrasion resistance and short scorch time but decrease in crosslinking density and elastic constant. Higher crosslinking density and elastic constant were shown in the EC cure system regardless of carbon black loadings, but scorch timc ($t_5$) was not affected by the change of the ratio of sulfur to accelerator. Rapid optimum cure time ($t_{90}$) were showen in the EC cure system. Also, the equivalent cure curve coefficient of rubber compound was 0.96 for conventional cure (CC) system, and 0.94 for semi-efficient cure (SEC) and EC system regardless carbon black loadings. As regarding the abrasion resistance, wear volume showed the logarithmic increase for the loaded weight.

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Deformation Behaviour of Metamorphic Tuff from Plate Loading Test

  • Lee, Young-Nam;Suh, Young-Ho;Kim, Dae-Young
    • Geotechnical Engineering
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    • v.13 no.3
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    • pp.87-100
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    • 1997
  • This paper presents the results of plate loading test and discontinuum analysis, carried out to study the deformation behaviour and determine the deformation modulus of !rletamorphic andesitic tuff found at the site of a underground oil storage facility in Korea. In the plate loading test, the maximum pressure of 14MPa was applied to the bedrock by using a flat jack(1m in diameter) and the rock anchor system for the reaction against the applied pressure. The values of deformation modulus obtained from this test were compared with those of laboratory test, biaxial test and pressuremeter test. The deformation modulus from plate loading test was generally about half of the intact rock modulus, and the mass modulus of the bedrock at the test site may be affected by discontinuities and ranges between 25 and 350pa. Discontinuum analysis was also performed to simulate plate loading test and study the influence of discontinuities on the deformability of rock mass by simulating the presence of joints at the test area.

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Development of Evaluation Method for Jointed Concrete Pavement with FWD and Finite Element Analysis (FWD와 유한요소해석을 이용한 줄눈콘크리트포장 평가법 개발)

  • Yun, Kyong-Ku;Lee, Joo-Hyung;Choi, Seong-Yong
    • International Journal of Highway Engineering
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    • v.1 no.1
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    • pp.107-119
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    • 1999
  • The joints in the jointed concrete pavement provide a control against transverse or longitudinal cracking at slab, which may be caused by temperature or moisture variation during or after hydration. Without control of cracking, random cracks cause more serious distresses and result in structural or functional failure of pavement system. However, joints nay cause distresses due to its inherent weakness in structural integrity. Thus, the evaluation at joint is very important. and the joint-related distresses should be evaluated reasonably for economic rehabilitation. The purpose of this paper was to develop an evaluation system at joints of jointed concrete pavement using finite element analysis program, ILLI-SLAB, and nondestructive testing device. FWD. To develop an evaluation system for JCP, a sensitivity analysis was performed using ILLI-SLAB program with a selected variables which might affect fairly to on the performance of transverse joints. The most significant variables were selected from precise analysis. An evaluation charts were made for jointed concrete pavement by adopting the field FWD data. It was concluded that the variables which most significantly affect to pavement deflections are the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G), and limiting criteria on the performance of joints at JCP are 300pci. 500,000 lb/in. respectively. Using these variables and FWD test, a charts of load transfer ratio versus surface deflection at joints were made in order to evaluate the performance of JCP. Practically, Chungbu highway was evaluated by these evaluation charts and FWD field data for jointed concrete pavement. For Chungbu highway, only one joint showed smaller value than limiting criterion of the modulus of dowel/concrete interaction(G). The rest joints showed larger values than limiting criteria of the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G).

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Thermal Durability of Al2TiO5-Mullite Composites and Its Correlation with Microstructure

  • Kim, Hyung-Chul;Lee, Dong-Jin;Kweon, Oh-Seong;Kim, Ik-Jin
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.532-536
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    • 2005
  • Thermal shock resistance of structural ceramics is a property that is difficult to quantity, and as such is usually expressed in terms of a number of empirical resistance parameters. These are dependant on the conditions imposed, but one method that can be used is the examination of density, Young's modulus and thermal expansion retention after quenching. For high temperature applications, long-annealing thermal durability, cycle thermal stability and residual mechanical properties are very important if these materials are to be used between $1000^{\circ}C$ and $1300^{\circ}C$. In this study, an excellent thermal shock-resistant material based on $Al_2TiO_5-mullite$ composites of various compositions was fabricated by sintering reaction from the individual oxides and adjusting the composition of $Al_2O_3TiO_2/SiO_2$ ratios. The characterization of the damage induced by thermal shock was done by measuring the evolution of the Young's modulus using ultrasonic analysis, density and thermal expansion coefficients.

Evaluation of Applicability of HMS-25 as the Railroad Roadbed Material (철도 노반재로서의 수경성 입도 조정 고로슬래그(HMS-25)의 적용성 평가)

  • 황선근;이성혁;이시한;최찬용
    • Journal of the Korean Geotechnical Society
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    • v.16 no.1
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    • pp.157-165
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    • 2000
  • The applicability and performance of HMS-25 as the railroad roadbed materials were evaluated through the model and laboratory tests. The uniaxial compression test of HMS-25, model soil box test, and combined resonant column and torsional shear test were performed for static and dynamic analysis of railroad roadbed. The uniaxial compression test result of HMS-25 shows steady increase in strength due to hardening chemical reaction between HMS-25 and water. The result of model soil box test reveals that railroad roadbed of HMS-25 is better than that of soil in several aspects such as bearing capacity and settlement. The combined resonant column and torsional that shear test result indicates that shear modulus of HMS-25 increases with the power of 0.5 to the confining pressure and that shear modulus increases with the increase of curing period.

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A Study on Characteristics of TiN Thin Films Deposited by Unbalanced Magnetron Sputtering Method for the Application of Diffusion Barrier Layers in Displays (디스플레이 확산 방지층 응용을 위한 비대칭 마그네트론 스퍼터로 증착된 질화 티타늄 박막의 특성에 대한 연구)

  • Park, Yong Seob
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.2
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    • pp.129-133
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    • 2019
  • TiN thin films were fabricated using an unbalanced magnetron sputtering (UBMS) system, and their structure and surface characteristics as well as their optical and tribological properties were evaluated. The hardness, elastic modulus, adhesive force, surface roughness, and transmittance of the Ti thin films fabricated using the UBMS system were 11.5 GPa, 103 GPa, 27.5 N, 2.45 nm and 20%, respectively. The TiN films prepared with various proportions of nitrogen as the reaction gas exhibited maximum values for the hardness, elastic modulus, critical load, RMS roughness and transmittance of approximately 19.2 GPa, 182 GPa, 27.3 N, 0.98 nm, and 85%, respectively. Moreover, the TiN thin film fabricated under the condition of 30 sccm nitrogen gas showed the optimal physical properties. In summary, the TiN thin films fabricated using the UBMS system exhibited excellent hardness, elastic modulus, adhesion, and smooth surface in addition to good hydrophilic properties.

A review on dynamic characteristics of nonlocal porous FG nanobeams under moving loads

  • Abdulaziz Saud Khider;Ali Aalsaud;Nadhim M. Faleh;Abeer K. Abd;Mamoon A.A. Al-Jaafari;Raad M. Fenjan
    • Steel and Composite Structures
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    • v.50 no.1
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    • pp.15-24
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    • 2024
  • This research presents dynamical reaction investigation of pore-dependent and nano-thickness beams having functional gradation (FG) constituents exposed to a movable particle. The nano-thickness beam formulation has been appointed with the benefits of refined high orders beam paradigm and nonlocal strain gradient theory (NSGT) comprising two scale moduli entitled nonlocality and strains gradient modulus. The graded pore-dependent constituents have been designed through pore factor based power-law relations comprising pore volumes pursuant to even or uneven pore scattering. Therewith, variable scale modulus has been thought-out until process a more accurate designing of scale effects on graded nano-thickness beams. The motion equations have been appointed to be solved via Ritz method with the benefits of Chebyshev polynomials in cosine form. Also, Laplace transform techniques help Ritz-Chebyshev method to obtain the dynamical response in time domain. All factors such as particle speed, pores and variable scale modulus affect the dynamical response.