• Title/Summary/Keyword: Reaction model

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Tacho Pulse Non-uniformity Effects on Pulse Count Method (타코펄스 불균일성으로 인한 펄스개수측정방법 영향성)

  • Son, Jun-Won
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.4
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    • pp.301-309
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    • 2021
  • Pulse count method is the classical reaction wheel speed detection method. In this study, we represent the pulse count method as mathematical equations. Instead of rotation speed, we model the reaction wheel rotation through rotation angle during sampling periods. We verified the effectiveness of the proposed model by comparing the pulse counts variation and averaging method effects from the model and previous research results. Then, we add tacho pulse non-uniformity to this verified model, and examine the errors of pulse count method. We express the measurement error increasement due to non-uniformity as mathematical equations, and also shows the requirement of moving average numbers to offset the measurement errors.

Development of Analysis Model for Down Scaled Two Phase Catalytic Reactor (초소형 촉매 이상 분해 반응기 해석 모델 개발)

  • Lee, Dae-Hoon;Kwon, Se-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.1
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    • pp.24-30
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    • 2004
  • Analysis model for the two-phase catalytic reactor is presented. With the progress in development of micro thermofluidic devices, needs fur understanding of the phenomena in two phase reaction in cm scale has been arisen. To investigate thermal and reactive performance of down scaled two phase reactor simple analysis model that is a kind of lumped flow model is proposed. Analysis model presented is based on the experiment on mm scale model reactor. Target experiment is catalytic decomposition of 70wt% hydrogen peroxide with existence of perovskite L $a_{0.8}$S $r_{0.2}$Co $O_3$ catalyst. It is composed of balance equations of mass and energy. Each phase is considered to be a species fur the simplicity. Axial diffusion and transversal distribution of properties are neglected. Two phase catalytic reaction is modeled as successive gasification of liquid lump around catalyst and reaction in gas phase. Heat transfer is modeled by model function ofNu number. Modeled Nu is expressed as Nu=N $u_{0}$ (1+ $a_1$( $a_2$ $T^{-}$ $a_3$)exp( $a_4$ $T^{-1}$)exp( $a_{5}$ z). Transfer coefficients are determined by the comparison of experimental results. With the model, heat transfer characteristics are investigated. Also by the mass transfer coefficient, characteristics in mass transfer is investigated. With the result basic understanding on design and analysis of mm scale two-phase reactive device is obtained. Also it can be further applied to micro scale reactive device fabricated by micromachining.ing..

Peptide Synthesis in Microaqueous System with Free and Immobilized Thermolysin (미수계내에서의 유리 및 고정화 Thermolysin에 의한 펩티드 합성)

  • 김남수
    • Microbiology and Biotechnology Letters
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    • v.20 no.6
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    • pp.704-706
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    • 1992
  • A model peptide, N-carbobenzoxy-L-phenylalanyl-L-phenylalanine methyl ester, was synthersized with free and immobilized thermolysin in a microaqueous system. The model peptide was formed mostly during the initial phase of the reaction. The yields of the compound with free and immobilized thermolysin after 4hr of reaction were 77.8 and 71.2, respectively.

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BIOECONOMIC HARVESTING OF A SCHOOLING FISH SPECIES:A DYNAMIC REACTION MODEL

  • Pradhan, T.;Chaudhuri, K.S.
    • Journal of applied mathematics & informatics
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    • v.6 no.1
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    • pp.127-142
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    • 1999
  • This paper develops a methematical model for growth and exploitation of a schooling fish species using a realistic catch-rate function and imposing a tax on the catch to control harvesting. Fishing effort is assumed to depend on the net revenue. The steady states of the system are determined and their local and global stabil-ity are discussed. Taking the tax as a control variable; the optimal harvest policy is formulated and solved as a control problem. The results are illustrated with the help of a numerical example.

GLOBAL STABILITY OF SOLUTIONS OF AN ELECTROCHEMISTRY MODEL WITH A SINGLE REACTION

  • Kim, Eu-Hee
    • Communications of the Korean Mathematical Society
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    • v.14 no.2
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    • pp.429-440
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    • 1999
  • In this paper an electrochemistry model which consists of three charged species is considered. A dissociation-association reaction is allowed to take place between these species. The species of ions diffuse owing to concentration gradients and migrate because of electric forces. We prove that any initial distribution of species concentrations will settle down to the unique steady state as time becomes large.

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Application of Reaction Path Smoluchowski Equation Formalism to the Photoisomerization of Trans-Stilbene

  • Kim, Dong-Sup;Lee, Sang-Youb
    • Bulletin of the Korean Chemical Society
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    • v.12 no.6
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    • pp.692-698
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    • 1991
  • The reaction path Smoluchowski equation approach developed in a recent work to calculate the rate constant for a diffusive multidimensional barrier crossing process is extended to incorporate the configuration-dependent diffusion matrix. The resulting formalism is then applied to the investigation of stilbene photoisomerization dynamics. Adapting a model two-dimensional potential and a model diffusion matrix proposed by Agmon and Kosloff [J. Phys. Chem.,91 (1987) 1988], we derive an eigenvalue equlation for the relaxation rate constant of the stilbene photoisomerization. This eigenvalue equation is solved numerically by using the finite element method. The advantages and limitations of the present method are discussed.

Modeling of a Pulverized Coal Combustion With Applying WSGGM (희체가스 가중합산모델을 적용한 미분탄 연소의 해석)

  • Yu, Myoung-Jong;Baek, Seung-Wook
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.155-163
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    • 1999
  • A numerical study for simulating a swirling pulverized coal combustion in axisymmetric geometry is done here by applying the weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard ${\kappa}-{\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase for soot. The eddydissipation model is employed for the reaction rate for gaseous mixture, and the single-step first-order reaction model for the devolatilization process for coal. By comparing the numerical results with experimental ones, the models used here are confirmed and found to be one of good alternatives for simulating the combustion as well as radiative characteristics.

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Development of Powertrain Model for Vehicle Dynamic Analysis Program, AutoDyn7 (차량동역학 해석 프로그램 AutoDyn7의 동력전달장치 모델)

  • 손정현;유완석;김두현
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.2
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    • pp.185-191
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    • 2001
  • In many papers, the powertrain system generally has been madeled as one-dimensional torque model. One-dimensional powertrain model may calculate the torque correctly but it does not consider the non-rotational degrees-of-freedom of the powertrain components and the interaction of these degrees-of-freedom with the vehicle body frame and suspension. To consider the non-rotational degrees of freedom, the differential is modeled as a three-dimensional rigid body in this paper. A constant velocity joint is newly formulated and a relative constraint is also formulated to model the motion transfer due to gear ratio of the differential. Implementing the proposed powertrain system in the multibody model, more detail dynamic responses can be obtained. Obtained outputs such as reaction torques on the constant velocity joint and reaction forces on the rack can be useful data in the design of a powertrain.

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Conformity Enhancement of Methane Generation Model for In-Service Landfill Site (운영 중인 매립장에서의 메탄가스 발생 모델의 정합도 향상)

  • Chun, Seung-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.213-223
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    • 2016
  • The validity of landfill gas models is an important problem considering that they are frequently used for landfill-site-related policy making and energy recovery planning. In this study, the Monte Carlo method was applied to an landfill gas generation model in order to enhance conformity. Results show that the relative mean deviation between measured data and modeled results (MD) decreased from 19.8% to 11.7% after applying the uncertainty range of Intergovernmental Panel on Climate Change (IPCC) to the methane-generation potential and reaction constants. Additionally, when let reaction constant adjust derived errors from all other modeling components, such as model logic, gauging waste, and measured methane data, MD decreased to 6.6% and the disparity in total methane generation quantity to 2.1%.

A Study of Intercalations-complexes of Montmorillonite as Model-Systems (Model-system으로서의 몬트모릴로나이트의 층간화합물에 관한 연구 (I))

  • Jo, Seong-Jun;Kim, Jong-Ok
    • The Journal of Natural Sciences
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    • v.5 no.1
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    • pp.77-86
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    • 1992
  • By cation-exchange-reaction long-chain organic cationic tensides can be intercalated in the montmorillonite layer space, and thus intercalations-complexes of montmorillonite with different properties of materials can be obtained. Such intercalations-complexes are finding strong technical appliances in many areas and are also used very often as model-systems for studying behaviors of materials. Therefore in this research intercalations-complexes of montmorillonite with organic cationic tensides ad model-systems were synthesized and their behabiors under various different conditions were studied.

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