• Title/Summary/Keyword: Reaction model

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Changes in the Anti allergic Effect of Citrus unshii Pericarpium According to Storage Period (진피(陳皮)의 저장기간에 따른 항알러지효과 비교)

  • Shin, Yong-Wook
    • The Korea Journal of Herbology
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    • v.27 no.5
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    • pp.37-44
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    • 2012
  • Objectives : The present study was undertaken to determine whether the ethanol extact of Citri Pericarpium (CP, Pericarp of Citrus unshiu Markovich, Rutaceae) is effective against atopic dermatitis according to it's storage period. Methods : To evaluate antiallergic effect of CP and OCP (Old Citri Pericarpium) evaluated in vivo their inhibitory effects against passive cutaenous anaphylaxis (PCA) reaction induced by IgE-antigen complex and scratching behaviors by compound 48/80. The Anti-atopic effects were measured by contact dermatitis, prurient animal model and PCA reaction. Contact dermatitis in mice as a model of the Type IV reaction caused by Oxazolone. Results : The results showed that anti-pruritus effects, analgesic effects of CP was depends on its hesperetin contents. And It also showed that keep longer in storage appeared to be higher in hesperetin contents. Both CP and OCP(Old CP) have a dose-dependent analgesic action in acetic acid induced writhing syndrome. OCP Potently inhibited PCA reaction in mice, although OCP weakly inhibited in long term contact dermatitis model in mice. Conclusions : These results suggest that the Proportional to the storage period, Citri Pericarpium possesses analgesic effects and anti-allergic effects.

A Study on Modelling and Attitude Control Techniques of LEO Satellite (저궤도 위성체의 모델링 및 자세제어 기법에 관한 연구)

  • Lho, Young-Hwan
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.46 no.6
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    • pp.9-13
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    • 2009
  • In the three axis control of Low Earth Orbit (LEO) satellite by using reaction wheel and gyro, a reaction wheel produces the control torque by the wheel speed or momentum, and a gyro carries out measuring of the attitude angle and the attitude angular velocity. In this paper, the dynamic modelling of LEO is consisted of the one from the rotational motion of the satellite with basic rigid body model and a flexible model, in addition to the reaction wheel model. A robust controller $(H_\infty)$ is designed to stabilize the rigid body and the flexible body of satellite, which can be perturbed due to disturbance, etc. The result obtained by $H_\infty$ controller is compared with that of the PI (Proportional and Integration) controller, which has been traditionally using for the stabilizing LEO satellite.

Effects of Additional Bubbling on RH Vacuum Degassing Process with Water Model Experiment (수모델을 사용한 RH 진공 탈가스장치에서의 추가 버블링 효과)

  • Jang, Young-Hwan;Kim, Young-Tae;Yi, Kyung-Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.424-429
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    • 2010
  • In the RH process, it is possible to obtain quicker processing times by enhancing the decarburization rates at a low carbon range of steel melt through Ar gas injection into the vacuum vessel. The RH decarburization reaction was simulated through a dissolved oxygen removal reaction by injecting nitrogen into a 1/8 scale RH water model system. The gas nozzles for the N$_{2}$ injection into the vacuum vessel were located at the lowest level of the vessel's outer wall. The nitrogen bubbling in the vacuum vessel resulted in an increase in the reaction rate constant, which rose in accordance with an increase in the bubbling flow rate and number of nozzles used. However, there was almost no variation in the reaction rate constant, which depended on the horizontal positions of the bubbling nozzles.

AN ERROR ESTIMATION FOR MOMENT CLOSURE APPROXIMATION OF CHEMICAL REACTION SYSTEMS

  • KIM, KYEONG-HUN;LEE, CHANG HYEONG
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.21 no.4
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    • pp.215-224
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    • 2017
  • The moment closure method is an approximation method to compute the moments for stochastic models of chemical reaction systems. In this paper, we develop an analytic estimation of errors generated from the approximation of an infinite system of differential equations into a finite system truncated by the moment closure method. As an example, we apply the result to an essential bimolecular reaction system, the dimerization model.

Reaction Kinetics for the Synthesis of Diphenyl Carbonate from Dimethyl Carbonate (디메틸 카보네이트(DMC)로부터 디페닐카보네이트(DPC) 합성을 위한 반응속도론)

  • Choi, Yu-Mi;Cho, Im-Pyo;Cho, Hoon;Lee, Jin-Hong;Han, Myung-Wan
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.766-771
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    • 2012
  • PC (polycarbonate) is one of the widely used engineering plastics. Polycarbonate (PC) is traditionally produced by the reaction of phosgene and bisphenol-A. This phosgene process has the disadvantage as the high toxicity and corrosiveness of phosgene. The main point of focus to overcome the disadvantage of phosgene based process has been a route through dimethyl carbonate (DMC) to diphenyl carbonate (DPC). In this paper, for the DPC synthesis reaction using PBO as a catalyst, the effect of reaction temperature, reactant ratio, catalyst concentration on the reaction yield was investigated. A kinetic model for the DPC synthesis reaction was proposed and kinetic parameters for the proposed model was determined from batch reactor experiments. The predicted results by the proposed model were in good agreement with the experimental results.

Steam Gasification Kinetics of Sawdust Char at High Temperature (톱밥 촤의 고온 수증기 가스화 특성)

  • Roh, Seon Ah;Yun, Jin Han;Keel, Sang In;Min, Tai Jin;Lee, Jung Kyu
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.821-825
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    • 2014
  • Steam gasification of sawdust char was performed in a thermobalance reactor at high temperature. Gasification temperature was changed from $850^{\circ}C$ to $1400^{\circ}C$ and steam partial pressure was 0.3, 0.5 and 0.7 atm. Three models of gas-solid reaction were applied to the reaction kinetics analysis and modified volumetric model was an appropriate model. Reaction control regime and diffusion control regime were distinct depending on the temperature. Apparent activation energy and pre-exponential factors for both of the regimes were evaluated and the effects of steam partial pressure were examined. $H_2$ concentration in the produced gas was two times higher than that of CO due to the gasification accompanying by the water gas shift reaction.

An Analysis of Capital Market Shock Reaction Effects in OECD Countries (OECD 회원국들의 자본시장 충격반응도 분석)

  • Kim, Byoung Joon
    • International Area Studies Review
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    • v.22 no.4
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    • pp.3-18
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    • 2018
  • In this study, I examined capital market shock reaction effects of 29 OECD countries with the past 24 years sample period consisting of daily stock market return using T-GARCH model focused on volatility feedback hypothesis. US daily stock market return is used as a unique independent variable in this model in consideration of its characteristics of biggest market share and as an origin country of Global Financial Crisis. As a result, France, Finland, and Mexico in order are shown to be the strongest countries in the aspect of return spillovers from US. Canada, Mexico, and France are shown to be the highest countries in the aspect of explanatory power of model. The degrees of shock reaction are proved to be higher in order in Germany, Chile, Switzerland, and Denmark and those of downside shock reaction are seen higher in order in Greece, Great Britain, Australia, and Japan. Canada and Mexico belonging to NAFTA are shown to be higher in the return spillover from US and in the model explanatory power, but they are shown to be lower in the impact of shock reaction, suggesting that regional distance effect or gravity theory cannot be applied to financial spillovers any longer. In the analysis of subsample period of Global Financial Crisis, north American three countries do not show any consistent results as in the full sample period but shock reaction in the European countries are shown to record stronger, suggesting that shocks from US in the Crisis Times are transferred mainly to European region.

Numerical Studies on the Combustion Characteristics and Pollutant Formation for the DME Fueled Diesel Engine (DME 연료 디젤엔진의 연소 및 공해물질 배출 특성 해석)

  • Yu, Yong-Wook;Lee, Jeong-Won;Kim, Yong-Mo
    • Journal of ILASS-Korea
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    • v.13 no.1
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    • pp.28-33
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    • 2008
  • The present study is mainly motivated to investigate the vaporization, auto-ignition and combustion processes in high-pressure diesel engines. In order to realistically simulate the dimethyl ether (DME) fueled diesel engine, the high pressure vaporization model is utilized and the interaction between turbulence and chemistry is treated by employing the Representative Interactive Flamelet (RIF) model. The detailed chemisty consisted of 336 elementary reaction steps and 78 species is used for DME/air reaction. Numerical results indicate that the RIF model with high pressure vaporization model successfully predicts the essential feature of the combustion processes and pollutants formations in the DME fueled diesel engines.

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Numerical study on the walking load based on inverted-pendulum model

  • Cao, Liang;Liu, Jiepeng;Zhang, Xiaolin;Chen, Y. Frank
    • Structural Engineering and Mechanics
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    • v.71 no.3
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    • pp.245-255
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    • 2019
  • In this paper, an inverted-pendulum model consisting of a point supported by spring limbs with roller feet is adopted to simulate human walking load. To establish the kinematic motion of first and second single and double support phases, the Lagrangian variation method was used. Given a set of model parameters, desired walking speed and initial states, the Newmark-${\beta}$ method was used to solve the above kinematic motion for studying the effects of roller radius, stiffness, impact angle, walking speed, and step length on the ground reaction force, energy transfer, and height of center of mass transfer. The numerical simulation results show that the inverted-pendulum model for walking is conservative as there is no change in total energy and the duration time of double support phase is 50-70% of total time. Based on the numerical analysis, a dynamic load factor ${\alpha}_{wi}$ is proposed for the traditional walking load model.

Optimization of Waste Cooking Oil-based Biodiesel Production Process Using Central Composite Design Model (중심합성계획모델을 이용한 폐식용유 원료 바이오디젤 제조공정의 최적화)

  • Hong, Seheum;Lee, Won Jae;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.559-564
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    • 2017
  • In this study, the optimization process was carried out by using the central composite model of the response surface methodology in waste cooking oil based biodiesel production process. The acid value, reaction time, reaction temperature, methanol/oil molar ratio, and catalyst amount were selected process variables. The response was evaluated by measuring the FAME content (more than 96.5%) and kinematic viscosity (1.9~5.5 cSt). Through basic experiments, the range of optimum operation variables for the central composite model, such as reaction time, reaction temperature and methanol/oil molar ratio, were set as between 45 and 60 min, between 50 and $60^{\circ}C$, and between 8 and 12, respectively. The optimum operation variables, such as biodiesel production reaction time, temperature, and methanol/oil molar ratio deduced from the central composite model were 55.2 min, $57.5^{\circ}C$, and 10, respectively. With those conditions the results deduced from modeling were as followings: the predicted FAME content of the biodiesel and the kinematic viscosity of 97.5% and 2.40 cSt, respectively. We obtained experimental results with deduced operating variables mentioned above as followings: the FAME content and kinematic viscosity of 97.7% and 2.41 cSt, respectively. Error rates for the FAME content and kinematic viscosity were 0.23 and 0.29%, respectively. Therefore, the low error rate could be obtained when the central composite model among surface reaction methods was applied to the optimized production process of waste cooking oil raw material biodiesel.