• 제목/요약/키워드: Reaction factor

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고온자전합성과 확산 열처리를 이용한 V 이 첨가된 TiAl계 금속간화합물 복합판재의 제조 (Formation of a V-Added Ti Aluminide Multilayered Sheet by Self-Propagating High-Temperature Synthesis and Diffusion Annealing)

  • 김연욱
    • 한국재료학회지
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    • 제12권9호
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    • pp.696-700
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    • 2002
  • The Ti-aluminide intermetallic compound was formed from high purity elemental Ti and Al foils by self-propagating, high-temperature synthesis(SHS) in hot press. formation of $TiAl_3$ at the interface between Ti and Al foils was controlled by temperature, pressure, heating rate, and so on. According to the thermal analysis, it is known in this study that the heating rate is the most important factor to form the intermetallic compound by this SHS reaction. The V layer addition between Al and Ti foils increased SHS reaction temperatures. The fully dense, well-boned inter-metallic composite($TiA1/Ti_3$Al) sheets of 700 m thickness were formed by heat treatment at $1000^{\circ}C$ for 10 hours after the SHS reaction of alternatively layered 10 Ti and 9 Al foils with the V coating layer. The phases and microstructures of intermetallic composite sheets were confirmed by EPMA and XRD.

200 t/d급 MHI 석탄 가스화기의 석탄 및 공기 배분에 따른 가스화 특성 평가 (Influence of coal and air flow rate distribution on gasification characteristics in 200 t/d scale MHI coal gasifier)

  • 도윤영;예인수;김봉근;류창국
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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    • pp.93-96
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    • 2015
  • Commercial coal gasifiers typically use entrained flow type reactors, but have unique features in terms of reactor shape, gasifying agent, coal feeding type, ash/slag discharge, and reaction stages. The MHI gasifier is characterized as air-blow dry-feed entrained reactor, which incorporates a short combustion stage at the bottom and a tall gasification stage above. This study investigates the flow and reaction characteristics inside a MHI gasifier by using computational fluid dynamics (CFD) in order to understand its design and operation features. For its pilot-scale system at 200 ton/day capacity, the distribution of coal and air supply between the two reaction stages was varied. It was found that the syngas composition and carbon conversion rate were not significantly influenced by the changes in the distribution of coal and air supply. However, the temperature, velocity and flow pattern changed sensitively to the changes in the distribution of coal and air supply. The results suggest that one key factor to determine the operational ranges of coal and air supply would be the temperature and flow pattern along the narrower wall between the two reaction stages.

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전기자동차 파워모듈용 질화규소 기판의 열기계적 특성 및 열응력 해석에 대한 연구 (A Study of Thermo-Mechanical Behavior and Its Simulation of Silicon Nitride Substrate on EV (Electronic Vehicle)'s Power Module)

  • 서원;정청하;고재웅;김구성
    • 반도체디스플레이기술학회지
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    • 제18권4호
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    • pp.149-153
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    • 2019
  • The technology of electronic packaging among semiconductor technologies is evolving as an axis of the market in its own field beyond the simple assembly process of the past. In the field of electronic packaging technology, the packaging of power modules plays an important role for green electric vehicles. In this power module packaging, the thermal reliability is an important factor, and silicon nitride plays an important part of package substrates, Silicon nitride is a compound that is not found in nature and is made by chemical reaction between silicon and nitrogen. In this study, this core material, silicon nitride, was fabricated by reaction bonded silicon nitride. The fabricated silicon nitride was studied for thermo-mechanical properties, and through this, the structure of power module packaging was made using reaction bonded silicon nitride. And the characteristics of stress were evaluated using finite element analysis conditions. Through this, it was confirmed that reaction bonded silicon nitride could replace the silicon nitride as a package substrate.

Determination of reaction kinetics during vitrification of radioactive liquid waste for different types of base glass

  • Suneel, G.;Rajasekaran, S.;Selvakumar, J.;Kaushik, Chetan P.;Gayen, J.K.;Ravi, K.V.
    • Nuclear Engineering and Technology
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    • 제51권3호
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    • pp.746-754
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    • 2019
  • Vitrification of radioactive liquid waste (RLW) provides a feasible solution for isolating radionuclides from the biosphere for an extended period. In vitrification, base glass and radioactive waste are added simultaneously into the melter. Determination of heat and mass transfer rates is necessary for rational design and sizing of melter. For obtaining an assured product quality, knowledge of reaction kinetics associated with the thermal decomposition of waste constituents is essential. In this study Thermogravimetry (TG) - Differential Thermogravimetry (DTG) of eight kinds of nitrates and two oxides, which are major components of RLW, is investigated in the temperature range of 298-1273 K in the presence of base glasses of five component (5C) and seven component (7C). Studies on thermal behavior of constituents in RLW were carried out at heating rates ranging from 10 to $40\;K\;min^{-1}$ using TG - DTG. Thermal behavior and related kinetic parameters of waste constituents, in the presence of 5C and 7C base glass compositions were also investigated. The activation energy, pre-exponential factor and order of the reaction for the thermal decomposition of 24% waste oxide loaded glasses were estimated using Kissinger method.

The Effects of Gamisipjeon-tang on the Skin Regeneration of Deep Second Degree Burns in Mice

  • Yu, Hyun-Jung;Hong, Seung-Ug
    • 대한한의학회지
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    • 제31권3호
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    • pp.107-121
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    • 2010
  • Objective: This study aimed to ascertain the curative effects of Gamisipjeon-tang (GST) used for wound healing on the skin regeneration of deep second degree burns in mice. Material & Methods: In vitro, the $I{\kappa}B$ kinase (IKK) mRNA expression, inducible nitric oxide synthase (iNOS) mRNA expression, and cyclooxygenase-2 (COX-2) mRNA expression in the GST concentration from 1 mg/$m{\ell}$ to 10 mg/$m{\ell}$ were measured. In vivo, the mice were divided into four groups : the normal group, the BE group (burn-elicited group, control group), the DC group (Duoderm CGF-treated group after burn elicitation), and the GST group (Gamisipjeon-tang treated group after burn elicitation). To determine the anti-inflammatory effects, nuclear factor (NF)-${\kappa}B$ p65, iNOS, COX-2 positive reaction were measured by immunohistochemistry. To estimate the skin regenerative effects, change of burn area, 5-bromo-2'-deoxyuridine (BrdU), and fibroblast growth factor (FGF) positive reaction were analyzed. Results: In vitro, the iNOS, IKK, COX-2 mRNA expression decreased according to the increase of GST concentration. The significant decrease of COX-2, iNOS, NF-${\kappa}B$ positive reaction were the highest in the GST group, followed by the DC group and the BE group (p<0.05). The diameter of burn area was significantly decreased in the GST group as compared to that in the DC and BE group (p<0.05). The BrdU and FGF positive reaction increased more significantly in the GST group than in the DC group, and more significantly in the DC group than in the BE group on the 3rd and 7th day after burn (p<0.05). FGF positive reaction increased in the BE and DC group, whereas it decreased significantly in the GST group on the 14th day (p<0.05). The BrdU positive reaction increased in the BE group, whereas it decreased significantly in the DC and GST group on the 14th day (p<0.05). Conclusions: This study shows that GST could decrease the inflammatory response and accelerate the skin regeneration as compared to the duoderm CGF in mice with deep second degree burns.

전기화학반응을 수반한 유로채널 형상에 따른 마찰계수에 대한 연구 (Friction Factor in Micro Channel Flow with Electrochemical Reactions in Fuel Cell)

  • 조선아;이필형;한상석;최성훈;황상순
    • 전기화학회지
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    • 제10권4호
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    • pp.245-251
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    • 2007
  • 주어진 연료전지면적에서 반응면적이 넓을수록 성능이 향상되는 연료전지는 좁은 폭의 채널을 여러 개 존재하게 하는 구조를 선호하지만 채널 폭이 좁아질수록 압력이 커지는 문제가 고려되어져야 한다. 그러나 현재 채널 구조에 따른 압력에 대한 연구는 많이 진행되어져 왔지만 대부분 반응을 고려하지 않았으며, 반응을 고려한 경우에 어떤 경향을 나타내는지 알아보는 것이 연료전지 유로설계에 있어 매우 중요하다. 본 논문에서 화학반응을 고려한 평행류, 90도 밴드형, serpentine 세가지 종류의 유로채널를 가진 연료전지를 수치 해석하여 반응을 고려하지 않은 경우와 마찰계수(fRe), 속도, 압력강하를 비교하여 본 결과 parallel과 bend 형태의 채널은 반응을 고려한 경우 반응에 의한 밀도의 감소에 따라 근소하게 감소한 것을 알 수 있었다. 그러나 serpentine채널은 다공성매체인 확산층을 통해 인접한 채널로 가스가 이동하는 bypass flow 영향에 의하여 상대적으로 낮은 압력강하를 나타내는 것을 알 수 있었다.

$Pb(Mn_{1/3}Sb_{2/3})O_3-Pb(Zr_{0.52}Ti_{0.48})O_3$계 세라믹스의 전기적 특성과 미세구조에 미치는 ZnO 첨가영향 (The Effect of ZnO Addition on the Electric Properties and Microstructure of $Pb(Mn_{1/3}Sb_{2/3})O_3-Pb(Zr_{0.52}Ti_{0.48})O_3$Ceramics)

  • 김민재;최성철
    • 한국세라믹학회지
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    • 제36권10호
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    • pp.1108-1114
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    • 1999
  • Microstructure and electrical properties of ZnO-doped (0-5 mol%) 0.05 Pb(Mn1/3Sb2/3)O3-0.95 PZT ceramics were investigated. Sintering temperature was decreased to 100$0^{\circ}C$ due to eutetic reaction between PbO and ZnO. Grain-size increased up to adding 1mol% ZnO and then decreased. Compositions of grain and grain-boundary were investigated by WDS. Lattice parameter was decreased with ZnO addition. Density increased with ZnO addition and reached to the maximum of 7.84(g/cm2) at 2 mol% ZnO. The effect of ZnO on electrical properties of PMS-PZT was investigated. At 3mol% ZnO addition electromechanical coupling factor(kp) was about 50% and relative dielectric constant($\varepsilon$33/$\varepsilon$0) was 997 Mechanical quality factor(Qm) decreased with ZnO addition. Lattice parameters and tetragonality(c/a) were measured to investigate relationship between the electric properties and substitution of Zn2+. At 3 mol% ZnO tetragonality was maximiged at c/a=1.0035 Curie temperature (Tc) decreased slightly with ZnO addition.

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Effect of Electrochemical Redox Reaction on Growth and Metabolism of Saccharomyces cerevisiae as an Environmental Factor

  • Na, Byung-Kwan;Hwang, Tae-Sik;Lee, Sung-Hun;Ahn, Dae-Hee;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제17권3호
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    • pp.445-453
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    • 2007
  • The effect of an electrochemically generated oxidation-reduction potential and electric pulse on ethanol production and growth of Saccharomyces cerevisiae ATCC 26603 was experimented and compared with effects of electron mediators (neutral red, benzyl viologen, and thionine), chemical oxidants (hydrogen peroxide and hypochlorite), chemical reductants (sulfite and nitrite), oxygen, and hydrogen. The oxidation (anodic) and reduction (cathodic) potential and electric pulse activated ethanol production and growth, and changed the total soluble protein pattern of the test strain. Neutral red electrochemically reduced activated ethanol production and growth of the test strain, but benzyl viologen and thionine did not. Nitrite inhibited ethanol production but did not influence growth of the test strain. Hydrogen peroxide, hypochlorite, and sulfite did not influence ethanol production and growth of the test strain. Hydrogen and oxygen also did not influence the growth and ethanol production. It shows that the test strain may perceive electrochemically generated oxidation-reduction potential and electric pulse as an environmental factor.