• 제목/요약/키워드: Reaction characteristic

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Properties of Bismuthoxynitrate as a Synthetic Pearl Pigment (인공 진주 안료로서 염기성 질산비스무트에 관한 연구)

  • 이계주;유병설
    • YAKHAK HOEJI
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    • v.22 no.1
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    • pp.22-26
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    • 1978
  • The purposes of this investigation were to study the characteristic properties of bismuthoxynitrate formed by hydrolysis of bismuthnitrate according to various reaction conditions and to propose the property difference between synthesized pearl pigment and bismuthsubnitrate as pharmaceuticals by means of X-ray diffraction, IR, DTA and TGA. The pearl pigment could be obtained by reaction of bismuth nitrate-diluted nitric acid solution with cold water (5.deg.) agitation at lower pH. The pearl pigment was BiO. NO$_{3}$. 2H$_{2}$O. in composition and crystalline form was thin plate of monoclinic system and its combination with water was assumed to be hydrated hydrous form between Bi-H$_{2}$O bond. On the other hand, bismuthsubnitrate was 5BiO.4NO$_{3}$.6H$_{2}$O in composition and crystalline form was pillar of rhombic system and the bond between Bi and H$_{2}$O molecules was assumed to be hydrous form. The different properties between two compounds in structure are presumed to be caused by the hydrolysing conditions of bismuthnitrate respectively.

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The growth of zinc oxide particles by coagulation in aerosol reactor (에어로졸 반응기에서 산화아연 입자의 응집 성장)

  • Lee, Jong Ho;Song, Shin Ae;Park, Seung Bin
    • Particle and aerosol research
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    • v.4 no.2
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    • pp.69-75
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    • 2008
  • Nanosize ZnO particles were prepared by oxidation of zinc vapor and the particle growth was modeled by a coagulation model by assuming that the characteristic time for reaction was much shorter than coagulation time and residence time (${\tau}_{reaction}{\ll}{\tau}_{coagulation}{\ll}{\tau}_{residence}$). Experimental measurement of zinc oxide particles diameter was consistent with the predicted result from the coagulation model. For practical purpose of predicting zinc oxide size in areosol reactor, the constant kernel solution is concluded to be sufficient, Uniqueness of nano-scale property of zinc oxide was confirmed by the higher photocatalytic activity of zinc oxide than nanosize titania particles.

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A Study of Ten ding Diancibo Pu Characteristic (특정전자파(TDP)의 특성에 관한 고찰)

  • Bae Sung-Soo;Nam Sung-Woo;Kim Mi-Hyun
    • The Journal of Korean Physical Therapy
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    • v.11 no.2
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    • pp.5-9
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    • 1999
  • The electromagnetic agent used in physical therapy rely far their effects on tissue heating and photo reaction of the body, Infrared has a thermal and analgesic effect, Ultra violet produces direct photo chemical reaction when it interacts with the body. Laser has broad effect on medicine, Ten ding Diancibo Pu (TDP) is in the infrared ray. The wave range is 20,000-250,000, as a far infrared. The effects of the TDP are number of white and red blued cell, capacity of animal immunization activity of enzyme in the organ and blood sugar density.

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Photodegradation of Paper Treated by Photostabilizer (광안정제(光安定劑)를 처리(處理)한 종이의 광열화(光劣化))

  • Kim, Bong-Yong
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.3
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    • pp.23-27
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    • 1995
  • Several characteristic results of physical and optical properties of paper treated by UV light were obtained in the previous papers(Kim et al. 1988). In this paper, folding endurance and brightness of paper prepared by spraying photostabilizer were examined in order to elucidate photodegradation phenomena, UV light absorber and radical scavenger were most effective in preventing of folding endurance decrease. These results may be indicated that depolymerization of cellulose and hemicellulose chains leading to degradation of paper mechanical properties mainly caused by radical reaction. Ineffective hydroperoxide decomposer may be explained because of auto-oxidation reactions before forming stable compound from hydroperoxide.

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Tribological Properties of Clay Bonded SiC (점토 결합 SiC 소결체의 마찰 마모 특성)

  • 한상준;이경희;이재한;김홍기
    • Journal of the Korean Ceramic Society
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    • v.32 no.9
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    • pp.1027-1032
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    • 1995
  • SiC had been widely applied for mechanical sealing as a sealing material. SiC sintering is commonly made of reaction sintering, presureless sintering, and hot isostatic pressing (HIP) sintering. In this investigation, however, clay bonded sintering was used to avoide any complications of the special sintering methods as mentioned above. In order to prevent harmful SiC oxidation in the clay bonded sintering, clay and frit were used to form the SiC oxidation protecting layer and graphite was added to provide high solid lubricity. As a result, the material with 6% clay (clay 5.4% and frit 0.6%) and 2~4% graphite (45 mesh) sintered at 140$0^{\circ}C$ for 3 hours, showed the following physical properties; porosity 6%, static friction coefficient 0.15, kinematic coefficient 0.1,. and specific wear rate 4.8$\times$10-8 $\textrm{mm}^2$kgf-1. On the other hand, the flexural strength was 900kgf/$\textrm{cm}^2$. This tribological characteristic properties were similar to those of the reaction sintered SiC except the flexural strength.

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Thermal Cycling Control System Design for Polymerase Chain Reaction(PCR) Machine (중합효소연쇄반응 기기의 온도 사이클링 제어시스템 설계)

  • Kim Jong-Hae;Cho Yong-Seuk;Oh Do-Chang
    • Journal of Institute of Control, Robotics and Systems
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    • v.12 no.5
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    • pp.419-424
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    • 2006
  • In this study, a thermal control system which applied a Peltier device for the polymerase chain reaction(PCR) machine is to be designed. Here in order for it to easily follow the characteristics of the thermal cycle existing for gene amplification of the PCR sample, a PCR control board utilizing a thermal sensor, a Peltier, and a 8 bit microprocessor is made up. Especially a fuzzy type PD control algorithm is applied periodically in time response, and control system is implemented. For that matter, the characteristic data of subject system is obtained and analysed to begin with. Based on this analysed data, the proposed control algorithm is applied and an evaluation of the performance of the whole system take place through the PC.

Kinetic Features of the Cobalt Dihalide/Methylaluminoxane Catalytic System in 1,3-Butadiene Polymerization

  • Nath Dilip Chandra Deb;Fellows Christopher M.;Shiono Takeshi
    • Macromolecular Research
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    • v.14 no.3
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    • pp.338-342
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    • 2006
  • The kinetic features of polymerization with an active site comprising cobalt dihalides ($CoX_2$, where X=Cl, Br, I) activated by methylaluminoxane (MAO) were investigated in 1,3-butadiene polymerization. The catalytic system exhibited the characteristic features of living polymerization. The initiation ($k_i$) and propagation ($k_p$) rate coefficients were estimated using the kinetic model for slow initiation previously reported by Shiono et al. The energy of activation fur the propagation reaction was calculated to be 27-30 $kJmol^{-1}$. The marked changes in reaction rate observed with different halides could be adequately described in terms of variations in the initiation process, with the same Arrhenius curve fitting propagation rate coeffcients estimated from all three halides, suggesting that the halide does not participate in the growing chain end.

Synthesis and Antiviral Evaluation of Novel Methyl Branched Cyclopropyl Phosphonic Acid Nucleosides

  • Kim, Jin-Woo;Ko, Ok-Hyun;Hong, Joon-Hee
    • Archives of Pharmacal Research
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    • v.28 no.7
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    • pp.745-749
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    • 2005
  • A simple synthetic route for the synthesis of novel methyl branched cyclopropyl phosphonic acid nucleosides is described. The characteristic cyclopropyl moiety 8 was constructed by employing Simmons-Smith reaction as a key step. The condensation of mesylate 11 with natural nucleosidic bases (A,C,T,U) under standard nucleophilic substitution conditions ($K_2CO_3$, 18-Crown-6, DMF) and after subsequent hydrolysis resulted in the formation of target nucleosides, 16, 17, 18, and 19. In addition, the antiviral evaluations of the synthesized nucleotides against various viruses were also performed.

Change of Substructure Design with Changed Angle of Skew Bridges (사교의 사각에 따른 하부구조 설계변화)

  • 이주호;염종윤;박경래;배한욱
    • Journal of the Korea Concrete Institute
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    • v.11 no.3
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    • pp.3-12
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    • 1999
  • This study presents a suggestion of regulation of skewed slab bridge. In order to find the characteristic behavior of skew bridge, many cases of skew bridges were analyzed with changed angle of skew. The comparison of design methods for cantilever part in pier was also made. It was found that : (1) The lower the skew angle was, the higher the maximum support reaction forces at the end point were. (2) The higher the ratio of L/B was, the higher the maximum support reaction force at the point was. (3) The effect of skew may be neglected for skew angles of $70^{\circ}$or more. (4) If elastic springs are applied to the boundary conditions to simulate the rubber pad bearings, the results will be more reasonable. (5) The shear deformation effect must be considered in the analysis of cantilever part of substructure. (6) Using strut and tie model to design cantilever part of pier, it will be more simple than finite element method with same accuracy and more accurate than using frame element.

A study on thrust and normal force by air-gap variation of a linear induction motor used for an urban railway transit (철도차량용 LIM의 공극변화에 따른 추력/수직력 특성 분석)

  • Yang, Won-Jin;Park, Chan-Bae;Lee, Hyung-Woo;Kwon, Sam-Young;Park, Hyun-June;Won, Chung-Youn
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.316-320
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    • 2008
  • A light rail transit, using a linear induction motor, is generally composed with reaction plates along railroad track and the three phase primary on the vehicle. This linear induction motor is driven to keep clearance between the primary and the secondary of the ground for preventing any contact. Therefore efficiency and power factor is very low. In addition, the reaction plate installed on the ground throughout entire railway is impossible to keep uniform gap and it may cause system deterioration. In this paper, A rotary-type small-scale model of a linear induction motor for various characteristic analysis is designed. Thrust force, normal force and input current of the model by air-gap variation have been analyzed by using a Finite Element Method (FEM). The effects of air-gap variation on system performance have been considered by analysis results.

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