• Title/Summary/Keyword: Reaction characteristic

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Reaction Mechanixm of Cyclodextrin formation from Swollen Extrusion Starch by cyclocextrin Glucanotransferase (팽윤 전분을 기질로 한 Cyclodextrin Glucanotransferase의 Cyclodextrin 생성반응 기작)

  • 이용현;조명진;박동찬
    • Microbiology and Biotechnology Letters
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    • v.23 no.4
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    • pp.416-424
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    • 1995
  • Mechanism of the cyclodextrin (CD) production reaction by cyclodextrin glucanotransferase (CGTase) using swollen extrusion starch as substrate was investigated emphasizing the structural features of starch granule. The degree of gelatinization was identified to be the most representative structural characteristic of swollen starch. The most suitable degree of gelatinization of swollen starch for CD production was around 63.52%. The structural transformation of starch granule during enzyme reaction was also followed by measuring the changes of the degree of gelatinization, microcrystallinity, and accessible and inaccessible portion to CGTase action of residual swollen starch. The adsorption phenomenon of CGTase to swollen starch was also examined under various conditions. The inhibition mechanism of CGTase by various CDs was identified to be competitive, most severely by a-CD. The mechanism elucidated will be used for development of a kinetic model describes CD production reaction in heterogeneous enzyme reaction system utilizing swollen extrusion starch.

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Induction of Delayed-Type Hypersensitivity Reaction to Staphylococus aureus in Mice (황색포도상구균에 대한 마우스의 지연성과민반응 발현)

  • Lee, Hern-Ku;Choi, Tai-Hoon;Ha, Tai-You
    • The Journal of the Korean Society for Microbiology
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    • v.21 no.1
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    • pp.145-149
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    • 1986
  • The development of delayed-type hypersensitivity(DTH) reaction to Staphylococcus aureus in mice was studied, Mice received 3 injections of $10^8$ viable S. aureus subcutaneously showed a marked footpad swelling when mice were challenged with $10\;{\mu}g$ staphylococcal protein antigen into footpad(The percent increase of footpad thickness at 24 h after challenge wsa 35% approximately). Histological observation of footpad of immunized mice showed a marked thickness of subcutaneous tissue due to edematous reaction and massive infiltration of lymphocytes and neutrophils which are characteristic cells in DTH reaction. Intensity of DTH reaction of mice immunized with viable bacteria was much higher than that of mice immunized with staphylococcal protein or heat-killed bacteria. The DTH reaction to S. aureus could be transferred to normal recipient mice by both spleen cells and lymph node cells.

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An Analysis on the Characteristic and Origin of the Exhaustion Method (실진법의 특성과 기원에 대한 분석)

  • Park, Sun-Yong
    • Journal for History of Mathematics
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    • v.32 no.1
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    • pp.27-44
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    • 2019
  • This study analyses and discusses on the characteristic and the origin of the exhaustion method caused by the controversy over whether that method succeeded to the Antiphone's complete exhaustion idea and whether that method is similar to the method of limits. First, this study analyses 'principle of exhaustion method' which play an important role in that method in order to grasp the local characteristic of it. And this study speculates the origin of the exhaustion method by considering the time and situation of appearance and looking through the local characteristic of it. Also, this study takes a view of the overall characteristic of the exhaustion method by inquiring into the process of actual application of 'principle of exhaustion method' in a proof. As these results, this study reveals that the exhaustion method uprose not as a succession of Antiphone's idea but as a reaction to its idea, and that the exhaustion method has the recognized character of 'finitude' as distinct from the method of limits.

An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part 3 : The Influence of the Innocuous Aggregate Content and Pozzolanic Materials to the Alkali-Silica Reaction) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제3보 : 무해골재 치환량 및 포졸란물질이 알칼리-실리카 반응에 미치는 영향))

  • 이양수;정재동;노재호;조일호;윤재환;이영수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.04a
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    • pp.169-173
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    • 1994
  • Recently, the use of crushed stones is increased due to the shortage of natural aggregates. In the previous papers of part 1 and 2, we got the conclusions that some of crushed stones have the characteristic of alkali-silica reaction(ASR). And these reactions are influenced by the amount and type of alkali in cement. The purpose of this paper is how to prepare for the prevention against alkali-silica reaction. As a solution of problems, we have conducted the experiments of two methods. One was the replacement of innocuous aggregates instead of reactive aggregates, the other was the addition of various pozzolanic materials. As a result, we found that the expansion by alkali-silica reaction in mortar bar could be effectively decredsed by upper methods.

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Linear and Hyperbranched Polymers via Electrophilic Substitution Reaction in Polyphosphoric $Acid/P_{2}O_{5}$

  • Choi, Ja-Young;Jeon, In-Yeop;Tan, Loon-Seng;Baek, Jong-Beom
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.195-195
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    • 2006
  • A superior electrophilic substitution reaction medium that is non-toxic, relatively less corrosive, and non-volatile electrophilic substitution reaction to afford high molecular weight linear and hyperbranched polyetherketones (PEK' s) was developed. The system has very strong driving force to give extra ordinary high molecular weight linear and hyperbranched PEK' s. The reaction medium was further extended to prepare various types of copolymers and covalently grafted polymers onto carbon nanotube (CNT) or carbon nanofiber (CNF). By using characteristic hydrophilic nature of the reaction medium, hyperbranched PEK' s could be synthesized from commercially available $A_3\;+\;B_2$ monomers without network formation via selective solubility of the monomers.

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Kinetic and Molecular Orbital Stuides on the Reaction of 5-nitrofurfural Hydrazone Formation

  • Lee, Kyung-Hee;Jee, Jong-Gi
    • Bulletin of the Korean Chemical Society
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    • v.6 no.5
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    • pp.280-284
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    • 1985
  • Kinetic measurements of the 5-nitrofurfural-hydrazine reaction in various pH ranges of aquous solution were carried out by ultraviolet spectrophotometry at $25^{\circ},\;35^{\circ}\;and\;45^{\circ}C$. The observed rate of the reaction varies with the change in pH, which gives characteristic "bell-type" rate acidity profile. The maximum rate is shown in the vicinity of pH 4. This reaction procceds with rate-determining attack of hydrazine on the 5-nitrofurfural at low pH and undergoes a change in rate-determining step to dehydration of the addition intermediate as pH increases. The reaction has a "reactant-like transition state" which precedes intermediate in low pH and "product-like transition state" which follows it in neutral pH. The geometry of 5-nitrofurfural-hydrazine intermediate was estimated with PCILO method associated with CNDO/2 scheme.

Combustion Characterisitics of a Catalytic Combustorfor an Automotive Ceramic Gas Turbine (세라믹 가스 터빈용 촉매연소기의 연소특성)

  • Kim, Young-Il
    • Journal of the Korean Society of Industry Convergence
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    • v.1 no.2
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    • pp.49-54
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    • 1998
  • In the catalytic combustor, combustion characteristic and deterioration of catalysts were affected by non-uniformity of pre-mixed gas, Therefore, formation of uniform pre-mixed gas is one of important subjects. In this study, the effect of uniformity and non-uniformity of pre-mixed gas supplied to the catalyst was examined to clarify reaction acceleration and combustion characteristic of the catalytic combustion. It was clarified that static mixer or vaporizer tube length of about 150mm and weak swirl to a combustion air were effictive expedient to make uniform pre-mixed gas. And catalystic inlet temperature needs more than $600^{\circ}C$ with rich pre-mixed gas to active reaction.

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Characteristic Analysis of a Linear Induction Motor for a Lightweight Train According to Various Secondary Schemes

  • Lee, Hyung-Woo;Lee, Sung-Gu;Park, Chan-Bae;Lee, Ju;Park, Hyun-June
    • International Journal of Railway
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    • v.1 no.1
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    • pp.6-11
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    • 2008
  • This paper presents a performance characteristic analysis methodology for a linear induction motor used for a lightweight train. In general, an analytical method cannot provide accurate results in a linear motor because of large airgap, end effect, transverse edge effect, 3-dimensional configurations, large leakage, and so on. Besides, a numerical method requires lots of memory and solving time for transient analysis. However, the suggested methodology which is a kind of hybrid solution with an analytical method and a numerical method is very fast and accurate. Based on the methodology, 3-D FEM analyses for various design schemes of the secondary reaction plate have been done and from the analysis results, the best configuration for an urban railway transit is chosen.

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Study on the Bioflocculant by Bacillus megaterium. #2 Characteristic of Production Condition for Bioflocculant by Bacillus megaterium (Bacillus megaterium 이 생산하는 응집제에 관하여 제 2보 Bacillus megaterium에 의한 응집제 생산특성)

  • 김도영
    • The Korean Journal of Food And Nutrition
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    • v.12 no.3
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    • pp.240-245
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    • 1999
  • The purpose of this study was to develop the new microbial bioflocculant available in a food and fer-mentation industal. This study was reported the results of the composition for optimum culture medium and elemental characteristic of crude purification bioflocculant following the previous report(I). The maximum production of the flocculant from Bacillus megaterium was observated in the culture medium containing 2% sucrose 0.3% NaNO3 0.01% tryptone 0.01% beef extract 0.05% MgSO4 ·7 H2O 0.005% CaCO3 Addition of the sucrose as carbon sources and inorganic salt such as MgSO4, CaCO3 significantly increased the production of flocculant more than nitrogen sources. In the result of color reaction of the crude purified bioflocculant it was investgated that anthrone was positive and benedict burette and nin-hydrin was negative. These result were indicated that the flocculant produced from Bacillus megaterium was a kind of exopolysaccharide.

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Effects of Hydrophilic Treatment by IAR Method on the Packing Characteristic Value (이온 보조 반응법에 의한 친수성 처리가 충전재 특성값에 미치는 영향)

  • Kim, Jin-Ho;Choe, Chung-Hyeon;Gang, Byeong-Ha;Lee, Jae-Heon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.554-560
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    • 2001
  • Hydrophilic treatment of the packing materials in a cooling tower has been made by the ion assisted reaction (IAR) method to increase the wettability of the packing materials. The effects of hydrophilic treatment of packing materials on the performance of a cooling tower have been investigated in a wide range of operating parameters, such as water flow rate, air flow rate, and the water inlet temperature. A pilot cooling tower has been designed and built to model a counter-flow cooling tower. The results obtained indicate that the packing characteristic value with hydrophilic packing could be substantially increased by 6∼19.3% than that with conventional packing in the operating ranges considered. The correlations of the packing characteristic value as a function of water-to-air ratio are suggested for a counter-flow cooling tower with hydrophilic packing as well as with conventional packing.