• Title/Summary/Keyword: Reaction Time Analysis

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TiO2 Photocatalytic Reaction on Glass Fiber for Total Organic Carbon Analysis (총유기탄소 분석을 위한 유리섬유를 이용한 이산화티타늄 광촉매 반응)

  • Park, Buem Keun;Lee, Young-Jin;Shin, Jeong Hee;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.31 no.2
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    • pp.102-106
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    • 2022
  • Currently, the demand for real-time monitoring of water quality has increased dramatically. Total organic carbon (TOC) analysis is a suitable method for real-time analysis compared with conventional biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods in terms of analysis time. However, this method is expensive because of the complicated internal processes involved. The photocatalytic titanium dioxide (TiO2)-based TOC method is simpler as it omits more than three preprocessing steps. This is because it reacts only with organic carbon (OC) without extra processes. We optimized the rate between the TiO2 photocatalyst and binder solution and the TiO2 concentration. The efficiency was investigated under 365 nm UV exposure onto a TiO2 coated substrate. The optimized conditions were sufficient to apply a real-time monitoring system for water quality with a short reaction time (within 10 min). We expect that it can be applied in a wide range of water quality monitoring industries.

Effects of Catalytic Reaction and Natural Convection on the Hot Surface Ignition of Methane-Air Mixtures (메탄-공기 예혼합기의 열면점화에 미치는 촉매반응 및 자연대류의 영향)

  • Kim, H.M.;Jurng, J.S.
    • Journal of the Korean Society of Combustion
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    • v.2 no.1
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    • pp.29-38
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    • 1997
  • In this study, the experimental and numerical investigations of the ignition of methane-air mixtures by a electrically heated wire have been carried out. In order to define the initial condition and make the analysis simple, the following control unit was developed; which heats the wire to the setting temperature in a very short time, and maintains the wire temperature constant until ignition. Experiments with the feedback control have been performed using nickel and platinum wires in normal gravity and microgravity. From experimental results, ignition temperatures in normal gravity are higher than those in microgravity, however, the dependences of ignition temperature on equivalence ratio are not affected by natural convection. Numerical calculations, including catalytic reaction for platinum, have been performed to analyze the experimental results in microgravity. Numerical results show that reactants near platinum wire are consumed by catalytic reaction, therefore, the higher temperature is needed to ignite the mixture with platinum wire.

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One-pot Synthesis of Nickel and Tungsten Carbide Nanoparticles Supported Mesoporous Carbon Electrocatalyst for Oxygen Reduction Reaction (산소환원반응을 위한 니켈-텅스텐 카바이드 나노입자 담지 메조포러스 카본 촉매의 단일 합성 및 그 특성 평가)

  • Kim, Hyemin
    • Journal of Surface Science and Engineering
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    • v.51 no.3
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    • pp.179-184
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    • 2018
  • In this study, Ni and tungsten carbide (WC) nanoparticles are simultaneously synthesized with the mesoporous carbon nanoparticles (CNP) using a solution plasma processing (SPP) in the benzene. The Ni and WC nanoparticles were formed through the sputtering effect of electrodes during discharge, and mean time CNP were formed through reduction reaction. TEM observation showed that loaded Ni and WC nanoparticles were evenly dispersed on the CNP. The results of electrochemical analysis demonstrated that an introduction of Ni nanoparticles promoted to improve catalytic activity for oxygen reduction reaction (ORR). Moreover, Ni-WC/CNP lead to fast electron transfer process compared to that of WC/CNP. Therefore, the inexpensive Ni-WC/CNP might be a promising as catalytic material for cathodes in fuel cell applications.

Hydration Analysis of Fine Particle and Old Mortar Attached on the Surface of Recycled Aggregate

  • Ko, Dong-Woo;Choi, Hee-Bok
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.5
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    • pp.460-467
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    • 2012
  • When recycled aggregate with old mortar and particles is used in concrete mixing, such aggregates can affect hydration reaction by promoting or inhibiting it. In this study, the possibility of hydration reaction on old mortar and particle was analyzed. Hydration reaction was carried out in old mortar that is finely crushed by an impact machine in the production of recycled aggregates, and it was found that this did have an impact on the strength development of concrete. Unlike in old cement, the hydration reaction did not progress in the particles, and it had high amounts of silica powder and calcium carbonate. In conclusion, the old mortar can have the influence of improving compressive strength, but the particles can delay the setting time of recycled aggregate concrete.

The Study of Kinetic Visual Acuity in College Students (대학생의 동적시력에 관한 연구)

  • Shim, Moon-Sik;Kim, Sang-Hyun;Kang, Hye-Sook;Shim, Hyun-Suk
    • Journal of Korean Ophthalmic Optics Society
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    • v.17 no.4
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    • pp.419-424
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    • 2012
  • Purpose: We were to obtain the basic data for studying kinetic visual acuity through the comparative analysis in kinetic visual acuity, visual acuity, refractive error, pupil size, and hand reaction time for college students. Methods: We had tested the kinetic visual acuity, visual acuity, refractive error and hand reaction time using the kinetic visual acuity tester (KOWA AS-4A), the hand reaction time program and auto-refractometer for thirty-nine male and same female optometry students with more than +0.1 LogMAR visual acuity in both eyes. And the results were examined gender differences of kinetic visual acuity and the factors correlation. Results: In the measured values of male, pupil size were 6.00 mm, hand reaction time 0.23 msec, refractive error -1.66 D, visual acuity -0.07, kinetic visual acuity 0.59 and pupil size 5.86 mm, hand reaction time 0.24 msec, refractive error -2.08 D, visual acuity -0.02, kinetic visual acuity 0.46 in female. It was significant difference for kinetic visual acuity values but other factors were not. The kinetic visual acuity and left visual acuity had the highest correlation, r=-0.406. The kinetic visual acuity indicated more excellent values in the case of increasing visual acuity and decreasing myopia amount. Conclusions: It was able to see that male college students were better than female for kinetic visual acuity and the visual acuity were related to kinetic visual acuity.

Numerical Analysis of Integrated Fuel Processing System Considering Thermo-Chemical Energy Balance (열/화학적 에너지 평형을 고려한 통합 연료 개질 시스템의 수치적 연구)

  • Noh, Junghun;Jung, Hye-Mi;Jung, Un-Ho;Yoon, Wang-Lai;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.111.1-111.1
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    • 2010
  • This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

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Optimum Conditions for Introducing Free Radical Polymerizable Methacrylate Groups on the MWCNT Surface by Michael Addition Reaction (MWCNT 표면에 Michael 부가 반응으로 자유 라디칼 중합 가능한 Methacrylate기 도입에 대한 최적 개질 조건)

  • Kim, Sunghoon;Park, Seonghwan;Kwon, Jaebeom;Ha, KiRyong
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.83-90
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    • 2015
  • In this study, we investigated optimum conditions for the introduction of a lot of free radical polymerizable methacrylate groups on the multi-walled carbon nanotube (MWCNT) surface. Carboxyl groups were introduced first on MWCNT surfaces by treating with a mixture of sulfuric acid and nitric acid with ultrasonic bath for 2 hours, and oxidized MWCNTs were reacted further with thionyl chloride followed by triethylenetetramine (TETA) to introduce amino groups on the oxidized MWCNT surface, to make MWCNT-$NH_2$. To introduce free radical polymerizable methacrylate groups on the MWCNT-$NH_2$, MWCNT-$NH_2$ was reacted with 3-(acryloyloxy)-2-hydroxypropyl methacrylate (AHM) by Michael addition reaction. We investigated progress of modification reactions for MWCNT by fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and elemental analysis (EA). We found maximum degree of Michael addition reactions between AHM and TETA grafted on MWCNT-$NH_2$ for 10:1 mol ratio and 8 hour reaction time in our reaction conditions.

Characteristic Analysis of a Linear Induction Motor for a Lightweight Train According to Various Secondary Schemes

  • Lee, Hyung-Woo;Lee, Sung-Gu;Park, Chan-Bae;Lee, Ju;Park, Hyun-June
    • International Journal of Railway
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    • v.1 no.1
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    • pp.6-11
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    • 2008
  • This paper presents a performance characteristic analysis methodology for a linear induction motor used for a lightweight train. In general, an analytical method cannot provide accurate results in a linear motor because of large airgap, end effect, transverse edge effect, 3-dimensional configurations, large leakage, and so on. Besides, a numerical method requires lots of memory and solving time for transient analysis. However, the suggested methodology which is a kind of hybrid solution with an analytical method and a numerical method is very fast and accurate. Based on the methodology, 3-D FEM analyses for various design schemes of the secondary reaction plate have been done and from the analysis results, the best configuration for an urban railway transit is chosen.

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A Non-recursive Formulation of Dynamic Force Analysis in Recursive Multibody Dynamics (순환 다물체동역학에서의 비순환적인 동하중해석 공식)

  • Kim, Seong-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.5
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    • pp.809-818
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    • 1997
  • An efficient non-recursive formulation of dynamic force analysis has been developed for serially connected multibody systems. Although derivation of equations of motion is based on a recursive dynamic formulation with joint relative coordinates, in the proposed formulation, dynamic forces such as joint reaction forces and driving force are computed non-recursively for specified joints. The efficiency of the proposed formulation has been proved by the operational count and the CPU time measure, comparing with that of the conventional recursive Newton-Euler formulation. A simulation of 7-DOF RRC robot arm has been carried out to validate solutions of reaction forces by comparing with those from a commercial dynamic analysis program DADS.

Biomechanical Analysis of Lower Limbs on Speed of Nordic Walking (노르딕워킹의 속도에 따른 하지 관절의 운동역학적인 분석)

  • Yang, Dae-Jung;Lee, Yong-Seon;Park, Seung-Kyu;Kang, Jeong-Il;Lee, Joon-Hee;Kang, Yang-Hoon
    • Korean Journal of Applied Biomechanics
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    • v.21 no.3
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    • pp.383-390
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    • 2011
  • In this study, 26 normal subjects were studied to compare the biomechanical Analysis of Lower Limbs on Speed of Nordic Walking. The biomechanical variables were determined by performing three-dimensional gait analysis, and the measurements items were spatial and temporal parameters; vertical ground reaction force; and moments of the hip, knee, and ankle joints. The purpose of this study based on the speed of Nordic Walking to the vertical ground reaction force and joint moments of each were analyzed. Nordic Walking with poles while being whether this weight is reduced to load, not the improvement of muscle activity by identify Nordic walking is to allow efficient. The results of the analysis were follows. The spatial parameters of step length, stride length significantly increased with increase in velocity(p<0.001). The temporal parameters of step time, stride time, the duration of double support use, and the duration of single support use also significantly decreased with increase in velocity(p<0.001), but cadence significantly increased(p<0.01). Analysis of the changes in ground reaction force revealed that vertical ground reaction force significantly increased at the initial contact and the terminal stance and decreased at the mid stance with increase in velocity(p<0.001). Moments of the hip and knee joints significantly in creased with increase in velocity whereas that of the ankle joint did not. Gait analysis revealed that weight-bearing decreased and moments of the hip and knee joints increased with increase in velocity(p<0.01). The results of this study may help people perform Nordic walking efficiently and Nordic walking can be used in the gait training of people with an abnormal gait.