• Title/Summary/Keyword: Reaction Time Analysis

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A Study on Water Quality and THMs Formation in Lake-Waters at Kunsan (군산시 호소수에서의 수질특성과 THMs 생성에 관한 연구)

  • 황갑수;김강주;이영남;여성구;김진남
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.44-50
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    • 2001
  • This study was carried out to investigate characteristics of water quality and THMs formation in lake-waters at kunsan. Of the parameters examined for water quality, pH, alkalinity, SO$_4$$^{-2}$ and Co- reflected the characteristics according to the origin, geography and water source of lakes while COD, SS, T-P, T-N and chlorophyll-a corelatively reflected well the influence of pollution factors around factors around lakes. The result of water quality analysis showed that most lakes in Kunsan area have the severe eutropnication problem, especially in summer. In lake-waters, THMFP overally continued to increase until 48 hour with the reaction time and THMs formation was largely achieved within 24 hour of the reaction time. The average formation ratio were 68.2% for CHCl$_3$, 23.6% for CHCl$_2$Br, 7.6% for CHClBr$_3$ and 0.6% for CHBr$_3$respectively and much difference depending on the reaction time was not shown. Overally, 96h-THEFP levels in lakes were high during June~September and showed higher tencency in lakes where could be regarded more contaminated on the whole. These results suggest that THMFP may be available for the management of lake-water quality as one if the useful parameters for the general evaluation of contamination. 96h-THEMFP failed to show the strong corelation individually with pH, TOC, COD and chlorphyll-a.

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Study on the Effect of Cognitive Function by Color Light Stimulation (색채 조명 자극이 인지기능에 미치는 영향에 관한 연구)

  • Chong, Woo-Suk;Yu, Mi;Kwon, Tae-Kyu;Kim, Nam-Gyun
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.10
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    • pp.131-136
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    • 2007
  • In this paper, we estimated the effects of different color stimulation on the cognitive function of human quantitatively. For the stimulations we used color lights with 6 color filters such as red, yellow, green, blue, violet and white. The experiment was performed in a soundproof chamber. 50 young male and female subjects were participated in the experiment. To find the appropriate color cognitive function, the endogenous visuospatial attention task(EVAT) and one back working memory task(OWMT) were performed. The reaction time and accuracy degree were measured. The results showed that the reaction time of EVAT was the fastest and the accuracy degree of attention task was the highest in green environment. The reaction time of OWMT was the fastest in yellow and the accuracy degree of memory task was the highest in blue. For physiological parameters, we measured electrocardiogram(ECG) and HRV spectrum analysis, HF/LF color environment. These results can be used as an indicator in the design of color environment and clinical applications.

Production Biodiesel via In-situ Transesterification from Chlorella sp. using Microwave with Base Catalyst

  • Kalsum, Ummu;Kusuma, Heri Septya;Roesyadi, Achmad;Mahfud, Mahfud
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.773-778
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    • 2018
  • In-situ transesterification of microalgae lipids using microwave irradiation has potential to simplify and accelerate biodiesel production, as it minimizes production cost and reaction time by direct transesterification of microalgae into biodiesel with microwave as a heating source. This study was conducted to research the effect of microwave irradiation with in-situ transesterification of microalgae under base catalyst condition. The process variables (reaction time, solvent ratio, microwave power) were studied using 2% of catalyst concentration. The maximum yield of FAME was obtained at about 32.18% at the reaction time of 30 min with biomass-methanol ratio 1:12 (w/v) and microwave power of 450 W. The GC MS analysis obtained that the main component of FAME from microalgal oils (or lipids) was palmitic acid, stearic acid and oleic acid. The results show that microwaves can be used as a heating source to synthesize biodiesel from microalgae in terms of major components resulting.

A new nano-ZnO/perlite as an efficient catalyst for catalytic ozonation of azo dye

  • Shokrollahzadeh, Soheila;Abassi, Masoud;Ranjbar, Maryam
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.513-520
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    • 2019
  • In this investigation, nano ZnO was sonochemically synthesized by a novel method using a methionine precursor. A narrow size distribution (41-50 nm) of nano ZnO was achieved that was immobilized on perlite and applied as a catalyst in catalytic ozonation. The catalyst was characterized by fourier transform infrared spectroscopy, BET surface area, and field emission scanning electron microscope. The ozonation of recalcitrant Remazol black 5 (RB5) di-azo dye solution by means of the synthesized catalyst was investigated in a bubble column slurry reactor. The influence of pH values (7, 9, 11), catalyst dosage (8, 12, 15, $20g\;L^{-1}$) and reaction time (10, 20, 30, 60 min) was investigated. Although the dye color was completely removed by single ozonation at a higher reaction time, the applied nanocatalyst improved the dye declorination kinetics. Also, the degradation of the hazardous aromatic fraction of the dye was enhanced five-times by catalytic ozonation at a low reaction time (10 min) and a neutral pH. The second-order kinetics was best fitted in terms of both RB5 color and its aromatic fraction removal. The total organic carbon analysis indicated a significant improvement in the mineralization of RB5 by catalytic ozonation using the nano-ZnO/perlite catalyst.

Analysis of cure behavior of low temperature curing liquid silicone rubber (LSR) for multi-material injection molding (이중사출 성형을 위한 저온 경화 액상실리콘고무 (LSR)의 경화 거동 분석)

  • Hyeong-min Yoo
    • Design & Manufacturing
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    • v.17 no.1
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    • pp.1-5
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    • 2023
  • In multi-material injection molding, since two or more materials with different process conditions are used, it is essential to maximize process efficiency by operating the cooling or heating system to a minimum. In this study, Liquid silicone rubber (LSR) that can be cured at a low temperature suitable for the multi-material injection molding was selected and the cure behavior according to the process conditions was analyzed through differential scanning calorimetry (DSC). Dynamic measurement results of DSC with different heating rate were obtained, and through this, the total heat of reaction when the LSR was completely cured was calculated. Isothermal measurement results of DSC were derived for 60 minutes at each temperature from 80 ℃ to 110 ℃ at 10 ℃ intervals, and the final degree of cure at each temperature was calculated based on the total heat of reaction identified from the Dynamic DSC measurement results. As the result, it was found that when the temperature is lowered, the curing start time and the time required for the curing reaction increase, but at a temperature of 90 ℃ or higher, LSR can secure a degree of cure of 80% or more. However, at 80 ℃., it was found that not only had a relatively low degree of curing of about 60%, but also significantly increased the curing start time. In addition, in the case of 110 ℃, the parameters were derived from experimental result using the Kamal kinetic model.

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Effect of Reaction Time on the Rheological Properties of Dextran Formed Solution Produced by Crude Dextransucrase from Leuconostoc rnesenteroides Sikhae (Leuconostoc mesenteroides Sikhae의 Crude Dextransucrase 반응시간에 따른 Dextran 생성액의 유변성)

  • 박춘상;이철호
    • Microbiology and Biotechnology Letters
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    • v.20 no.3
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    • pp.316-323
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    • 1992
  • Studies on the changes in rheological properties, molecular weight distribution and dextran yield after being reacted in lO%(w/w) sucrose concentration were performed with crude dextransucrase produced from Leuconostoc mesenteroides isolated from Sikhae. The reaction rate of dextran formation was monitored by sugar analysis with HPLC and by the changes in apparent viscosity. According to the periodate oxidation test, the dextran produced in this experiment was estimated to have 89% $\alpha$-(1->6) main linkages and 11% $\alpha$-(1->) side linkages. The rheological properties of the dextran solution formed changed with reaction time, and it was related to the changes in molecular weight distribution of dextran as determined by GPC analysis. As the reaction proceeded, the rheological behavior changed from Newtonian to non-Newtonian, showing Binghampseudoplastic and thixothropic flow behavior. The apparent viscosity of dextran formed solution increased with increasing reaction time, reached a maximum value of 2680 cP ($\gamma$=$33.75s^{-1}$, $25^{\circ}C$) by enzyme reaction for 8 hours, and then decreased. The temperature dependency of dextran formed solutions was well expressed by the Arrhenius equation and the activation energy reached a maximum value of 1.69 kcal/mole by enzyme reaction for 8 hours.

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Comparisons of Middle- and Old-Aged Drivers' Recognition for Driving Scene Elements using Sensitivity, Response Bias, and Response Time (중년 및 고령운전자의 운전장면 개별요소에 대한 재인기억 차이: 민감도, 반응기준 및 반응시간 비교)

  • Lee, Jaesik
    • Journal of the Korean Data Analysis Society
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    • v.20 no.6
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    • pp.3185-3199
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    • 2018
  • Middle- and old-aged driver's capability in recognition for driving scene elements was compared. Central and ambient stimuli were selected from natural driving scene and sensitivity, bias and reaction time were measured as dependent measures. The results are as follows. First, in general, older drivers showed lower sensitivity than middle-aged drivers. In particular, the older drivers' sensitivity was significantly lower for the ambient stimuli than central stimuli, whereas the middle-aged drivers showed no significant difference between the two types of stimuli. Second, the older drivers tended to show more lenient responses whereas the middle-aged drivers responded more conservatively. Third, the older drivers showed longer reaction time than the middle-aged drivers, in particular, in the responses of miss and correct rejection. This results suggested that the older drivers' retention for driving scene elements in their working memory may not be stable, which can be resulted in difficulties in rapid and accurate responses in a real life driving.

Job Design for Safety by Sensibility Based on the Oriental Human Constitution (동양 체질론의 감성적 기질을 이용한 안전 직무설계)

  • 최성운;이영석
    • Journal of the Korea Safety Management & Science
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    • v.1 no.1
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    • pp.29-39
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    • 1999
  • Human sensibility ergonomics is the technique that qualities man's sensibility, measures and evaluates it Quantitatively and makes man's life comfortable, safe and delightful by applying it to products or environmental projects. This study consider the sensibility factor of Sasang constitutional medicine, five elemental properties, and Biorhythm in terms of human sensibility ergonomics. And this study measure reaction-time dependent on a temperament or a state and evaluate the differences of reaction-times objectively with the comparison and analysis using the ANOVA. We can harness it for job design.

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MONOTONE METHOD FOR NONLINEAR HILFER FRACTIONAL REACTION-DIFFUSION EQUATIONS

  • Pandurang D. Kundgar;Jagdish A. Nanware;Gunvant A. Birajdar
    • Nonlinear Functional Analysis and Applications
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    • v.29 no.3
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    • pp.753-767
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    • 2024
  • In this paper, we developed the existence and uniqueness results by monotone method for non-linear fractional reaction-diffusion equation together with initial and boundary conditions. In this text the Hilfer fractional derivative is used to denote the time fractional derivative. The employment of monotone method generates two sequences of minimal and maximal solutions which converges to lower and upper solutions respectively.

Preparation of Hydrazine Impregnated Adsorbents and Selective Adsorption Properties for Carbonyl Compounds in Cigarette Mainstream Smoke (Hydrazine 첨착 흡착제의 제조 및 담배 주류연 중 카보닐 화합물의 선택 흡착 특성)

  • Lee, John-Tae;Park, Jin-Won;Lee, Jeong-Min;Rhee, Moon-Soo;Hwang, Keon-Joong;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.210-216
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    • 2006
  • To use the filter materials for selective removal of carbonyl compounds in cigarette mainstream smoke, hydrazine such as 2,4-dinitrophenylhydrazine (2,4-DNPH) and dansylhydrazine (DAH) impregnated adsorbents were prepared with perchloric acid or phosphoric acid as an accelerator in hydrazone formation reaction. Changes of molecular structure and morphology of adsorbents in various of impregnator were investigated by FTIR/ATR and SEM. Impregnation amount caused by reaction time, acid type and impregnation reagent, and the adsorption properties of carbonyl compounds in cigarette mainstream smoke were studied. Amounts of impregnation increased with increasing reaction time. The removal amount for vapor phase carbonyl compounds by 2,4-DNPH impregnated adsorbent was higher than that of dansylhydrazine impregnated adsorbent. The selectivity of 2,4-DNPH impregnated polyacrylic type adsorbent was superior to those of other adsorbents. This result indicates that the 2,4-DNPH impregnated polyacrylic adsorbent is applicable to cigarette filter material because of its fast reactivity and porosity.