• Title/Summary/Keyword: Reaction Oxygen

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The Relationship Between Firing Modes and Nitric Oxide Emission In Highly Preheated Air Combustion

  • Choi, Gyung-Min;Katsuki, Masahi;Kim, Duck-Jool
    • Journal of Mechanical Science and Technology
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    • v.14 no.4
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    • pp.433-440
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    • 2000
  • The influence of combustion air at temperatures on nitric oxide emission was studied. The nitric oxide emission generally increases with a rise in the temperature of the combustion air. However, if combustion products for dilution of fuel or combustion air are used before the combustion reaction, then the nitric oxide emission can be reduced even when highly preheated air for combustion air is used. Combustion in low oxygen concentrations flattens the firing mode, resulting in a uniform reaction, and, thus, low nitric oxide emission can be achieved.

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The Characteristics of Iron(Fe) Floc Formation for Treatment of Acid Mine Drainage (산성 광산 배수의 처리를 위한 철(Fe) 성분의 플럭 형성 특성)

  • Song, Kun-Ho;Lee, Kwang-Rae
    • Journal of Industrial Technology
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    • v.33 no.A
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    • pp.89-92
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    • 2013
  • The characteristics of floc formation of the iron(Fe) ions was studied for developing the process treating the acid mine drainage. The metal ions in aqueous solution oxidized with oxygen in air, which generated hydrogen ion and lowered the pH of the aqueous solution. The iron(Fe) ions were formed into flocs by the acid-base reaction with the added $Ca(OH)_2$ for the neutralizing the solution. There were several variables affecting the formation, size and color of floc; whether air was present or not, air feeding rate, oxidizing time, concentration of $Ca(OH)_2$, the acid-base reaction time of the $iron(Fe)-Ca(OH)_2$. For proper formation of the $iron(Fe)-Ca(OH)_2$ flocs and developing the floc treating system, the control variables mentioned above should be considered.

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Finite Element Analysis of Combustion Reaction on Iron and Metal Oxides Interface (Fe-금속 산화물 계면에서 연소반응의 유한 요소해석)

  • Gu, Mun-Seon;Choe, Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.118.2-118.2
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    • 2017
  • Combustion behavior of Fe, CuO, NiO, ZnO and $Fe_2O_3$ powder mixture was carried out by finite element method (FEM) to understand a reaction at iron and metal oxide interface. The FEM was done by using ANSYS Fluent 17.0. Initial and boundary conditions are 1 atmosphere, room temperature, 0.1MPa of oxygen partial pressure, $T_{S1}=1127^{\circ}C$, $T_{S2}=327^{\circ}C$ for a cylindrical shape specimen with dia. $35{\times}80$ [mm]. The maximum combustion temperature is $1537^{\circ}C$ for the condition of conduction, convection and radiation. The combustion temperature and rate are about $847^{\circ}C$ and 3.9mm/sec, respectively. The combustion wave is enough to make ternary ferrite phase like $CuNiZnFe_2O_3$.

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Synthesis and Characterization of LSCF/CGO Composite Used as SOFC Cathode Materials (SOFC 용 LSCF/CGO 공기극의 제조 및 특성연구)

  • Park, Jae-Layng;Lim, Tak-Hyoung;Lee, Seung-Bok;Park, Seok-Joo;Shin, Dong-Ryul;Song, Rak-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.184-186
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    • 2009
  • Composites of LSCF($La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta}$ and CGO(gadolinium doped ceria) is an efficient candidate cathode material with CGO electrolytes. In this study, LSCF with exact perovskite structure was synthesized by using solid state reaction(SSR) method. The optimized temperature to synthesize $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta}$ with rhombohedral structure. was $1100^{\circ}C$. The polarization resistance of the LSCF/CGO(50:50 wt.%) was smaller than those of other composite cathodes. The analysis of the EIS data of LSCF/CGO suggests that the diffusion and adsorption-desorption of oxygen can be the key process in the cathodic reaction of SOFC using LSCF/CGO as cathode material.

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Chemical Reaction of $H_2$/Air Mixture Inhibited by Heptafluoropropane(HFP) during Autoignition Process (HFP가 첨가된 수소/공기 혼합기의 자연점화에서의 화학반응)

  • Lee, Eui-Ju;Oh, Chang-Bo
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.04a
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    • pp.100-103
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    • 2008
  • Autoignition suppression of hydrogen/air premixed mixtures by $CF_3CHFCF_3$(HFP) was investigated computationally. Numerical simulation was performed in isobaric and homogeneous system to evaluate the induction times. The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the similar concentrations for the major reactants such as hydrogen and oxygen during autoignition while water vapor produced at the ignition temperature was decomposed later, which leaded to the shoulder on the concentration of H, OH and O radical with time. The fluorine included from HFP was converted mainly to stable HF and the carbon was formed to various species, CF2, CF2O, CO etc. More details of chemical effects of HFP addition will be investigate with sensitivity analysis in the near future.

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Antioxidation Effect of Various Electrolyzed Water (여러 가지 전리수의 항산화 효과)

  • Lee Yoon Bae;Ryoo Kunkul;Lee Jongkwon;Lee Miyoung;Shin Eunjung;Sung Sichang;Ku Daechul
    • Proceedings of the KAIS Fall Conference
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    • 2005.05a
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    • pp.318-320
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    • 2005
  • Antioxidation effect of reduced electrolyzed water, which has been known as antiaging agent has been investigated with very simple method. Antioxidation effect of the reaction of linoleic acid with oxygen has been measured and analyzed. Alkaline reduced electrolyzed waters are better effect, rather acidic oxidized electrolyzed waters accelerates oxidation reaction.

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Joining Behavior of Ceramics to Metal by Using Lead-bismate Heavy Metal Glass Frit (중금속 창연산화납계 저온유리 분말을 이용한 세라믹스/금속의 접합거동)

  • Choi, Jin Sam
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.312-316
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    • 2014
  • The joining behavior of forsterite ceramics to SUS304 alloy using $8PbO-78Bi_2O_3-8B_2O_3-4ZnO-2SiO_2$ (wt%) system glass frit was investigated. The contact angle was smaller than $90^{\circ}$ at a temperature of $460^{\circ}C$. Redox reaction at the interface between forsterite and SUS304 was found to appear when the electrons in the metal part moved toward the glass part and the oxygen ions in glass moved to the metal side. The decrease of the surface tension due to the PbO solubility on the forsterite side contributed to the better wetting behavior at low temperature.

Conversion of Carbon Fiber into Silicon Carbide Fiber by Pack-Cementation

  • Joo, Hyeok-Jong;Kim, Jung-Il;Lee, Jum-Kyun
    • Carbon letters
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    • v.1 no.1
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    • pp.12-16
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    • 2000
  • Carbon fiber was reacted with gaseous silicon monoxide which is produced from pack-powder mixture at elevated temperature. As a result of the reaction, two kinds of SiC fiber were obtained. The first one was SiC fibers which were converted from carbon fiber. The fiber is constituted with polycrystal like fine grains or monolithic crystals that have a size from sub-micron to $10\;{\mu}m$. Their size depends on the temperature during the conversion reaction. The second one was ultra-fine SiC fibers that were found on the surface of the converted SiC fibers. The ultra-fine fibers have diameters from 0.08 to $0.2\;{\mu}m$ and their aspect ratio were larger than 100. The chemical composit ion of the ultra-fine fibers was analyzed using an Auger electron spectroscopy. In result, the fibers consist of 51% silicon, 38% carbon and 11% oxygen by weight.

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Fabrication of Metallic Tantalum Powder by Magnesium-gas Reduction of Tantalum Oxide (탄탈륨 산화물의 마그네슘 가스환원에 의한 탄탈륨 금속분말 제조)

  • Lee, Dong-Won
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.390-394
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    • 2018
  • Metallic tantalum powder is manufactured by reducing tantalum oxide ($Ta_2O_5$) with magnesium gas at 1,073-1,223 K in a reactor under argon gas. The high thermodynamic stability of magnesium oxide makes the reduction reaction from tantalum oxide into tantalum powder possible. The microstructure after the reduction reaction has the form of a mixture of tantalum and magnesium oxide, and the latter could be entirely eliminated by dissolving in weak hydrochloric acid. The powder size in SEM microstructure for the tantalum powder increases after acid leaching in the range of 50-300 nm, and its internal crystallite sizes are observed to be 11.5 to 24.7 nm with increasing reduction temperatures. Moreover, the optimized reduction temperature is found to be 1,173 K as the minimum oxygen concentration is approximately 1.3 wt.%.

The Removal of Inclusions in Molten Steel by Coating Materials for Tundish (턴디쉬용 코팅재에 의한 강중 개재물 저감효과)

  • 조문규;이석근
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.33-40
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    • 1998
  • A MgO-CaO-based coating material for ferrous melt refining is applied to the tundish operation for mol-ten steel having low carbon. The changes in the total oxygen content insoluble aluminum content and the content of inclusions in molten steel during tundish operation were measured at the pouring part strand of tundish and mold. On the basis of the experimental results the interfacial reaction occurring between the coating materials and the molten steel in tundish was discussed and compared with the theoretical con-sideration. It is concluded that interfacial reaction is not active at the strand part of tundish but is active at the pouring part because of the turbulent flow in the molten steel.

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