Browse > Article
http://dx.doi.org/10.4191/kcers.2014.51.4.312

Joining Behavior of Ceramics to Metal by Using Lead-bismate Heavy Metal Glass Frit  

Choi, Jin Sam (School of Advanced Materials Engineering, University of Ulsan)
Publication Information
Abstract
The joining behavior of forsterite ceramics to SUS304 alloy using $8PbO-78Bi_2O_3-8B_2O_3-4ZnO-2SiO_2$ (wt%) system glass frit was investigated. The contact angle was smaller than $90^{\circ}$ at a temperature of $460^{\circ}C$. Redox reaction at the interface between forsterite and SUS304 was found to appear when the electrons in the metal part moved toward the glass part and the oxygen ions in glass moved to the metal side. The decrease of the surface tension due to the PbO solubility on the forsterite side contributed to the better wetting behavior at low temperature.
Keywords
Forsterite; SUS304; Glass frit; Redox reaction; Solubility; Joining;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 J. S. Choi, D. W. Shin, and W. T. Bae, "Effect of an Additive on the Physical and Electrical Properties of the $B_2O_3$-$Bi_2O_3$-ZnO Glass System for a Sheath Heater Module(in Korean)," J. Kor. Ceram. Soc., 50 [1] 57-62 (2013).   과학기술학회마을   DOI   ScienceOn
2 E. M. Levin, C. R. Robbins, and H. F. McMurdie, "Phase Diagrams for Ceramists," Am. Ceram. Soc., 1 712 (1979).
3 W. D. Kingery, "Role of Surface Energies and Wetting in Metal-ceramics Sealing," Bull. Am. Ceram. Soc., 35 108-12 (1956).
4 A. Zanchetta, P. Lortholary, and P. Lefort, "Ceramic to Metal Sealing: Interfacial Reactions Mechanism in a Porcelain-Kovar Junction," J. All. Comp., 228 86-95(1995).   DOI   ScienceOn
5 W. C. Wagner, K. Asgar, W. C. Bigelow, and R. A. Flinn, "Effect of Interfacial Variables on Metal-porcelain Bonding," J. Biomed. Mat. Res., 27 [4] 531-37 (1993).   DOI   ScienceOn
6 C. E. Hoge, J. J. Brennan, and J. A. Pask, "Inerfacial Reaction and Wetting Behavior of Glass Iron System," J. Am. Ceram. Soc., 56 [2] 51-54 (1973).   DOI   ScienceOn
7 J. A. Pask, "New Techniques in Glass-to-Metal Sealing," Proc. IRC, 36 [2] 286-89 (1948).   DOI
8 W. D. Kingery, "Role of Surface Energies and Wetting in Metal-ceramics Sealing," Bull. Am. Ceram. Soc., 35 108-112 (1956).
9 W. Gąsior, Z. Moser, and J. Pstrus, "Density and Surface Tension of the Pb-Sn Liquid Alloys," J. Phas. Equ., 22 [1] 20-25 (2001).   DOI
10 A. G. M. Othman and N. M. Khalil, "Sintering of Magnesia Refractories though the Formation of Periclase-Forsterite-Spinel Phase," Ceram. Inter., 31 [8] 1117-21 (2005).   DOI   ScienceOn
11 W. D. Kingery, H. K. Bowen, and D. R. Uhlmann, "Introduction to Ceramics," 2nd Ed. pp. 207-10 and pp. 304-11, John Wiley & Sons, New Jersey, 1976.
12 C. Chanmung, M. Naksata, T. C. Chairuangsri, H. Jain, and C. E. Lyman, "Microscopy and Strength of Borosilicate Glass-to-Kovar Alloy Joints," Mater. Sci. Eng., A, 474 [1-2] 218-24 (2008).   DOI   ScienceOn
13 T. S. Chern and H. L. Tsai, "Wetting and Sealing of Interface between 7056 Glass and Kovar Alloy," Mat. Chem. Phy., 104 [2-3] 472-78 (2007).   DOI   ScienceOn
14 J. S. Choi, D. Y. Jeong, D. W. Shin, and W. T. Bae, "Characteristics of the PbO-$Bi_2O_3$-$B_2O_3$-ZnO-$SiO_2$ Glass System Doped with Pb Metal Filler(in Korean)," J. Kor. Ceram. Soc., 50 [3] 238-43 (2013).   과학기술학회마을   DOI   ScienceOn