• Title/Summary/Keyword: Reaction Cross Section

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A Study on Neutron Resonance Energy of 180Ta below 1eV Energy (1 eV 이하 에너지 영역에서의 180Ta 동위원소의 중성자공명에 대한 연구)

  • Lee, Samyol
    • Journal of the Korean Society of Radiology
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    • v.8 no.6
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    • pp.287-292
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    • 2014
  • In this study, the neutron capture cross section of $^{180}Ta$(natural existence ratio: 0.012 %) obtain by measuring has been compared with the evaluated data for the capture data. In generally, the neutron capture resonance is defined as Breit-Wigner formula. The formula consists of the resonance parameters such as neutron width, total width and neutron width. However in the case of $^{180}Ta$, these are very poor experimental neutron capture cross section data and resonance information in below 10 eV. Therefore, in the study, we analyzed the neutron resonance of $^{180}Ta$ with the measuring the prompt gamma-ray from the sample. And the resonance was compared with the evaluated data by Mughabghab, ENDF/B-VII, JEFF-3.1 and TENDL 2012. Neutron sources from photonuclear reaction with 46-MeV electron linear accelerator at Research Reactor Institute, Kyoto University used for cross section measurement of $^{180}Ta(n,{\gamma})^{181}Ta$ reaction. $BGO(Bi_4Ge_3O_{12})$ scintillation detectors used for measurement of the prompt gamma ray from the $^{180}Ta(n,{\gamma})^{181}Ta$ reaction. The BGO spectrometer was composed geometrically as total energy absorption detector.

Shapes of ZnO Nanostructures Grown in the Aqueous Solutions (수용액에서 합성한 ZnO 나노구조체의 형상)

  • Jang Yeon-Ik;Park Hoon;Lee Seung-Yong;Ahn Jae-Pyoung;Park Jong-Ku
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.284-290
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    • 2005
  • ZnO nanostructures with various shapes were synthesized under ambient pressure condition by a wet chemical reaction method. Nanorods of ZnO with hexagonal cross-section and their aggregates with radiate shape were synthesized. Precursor concentration affected considerably the shape evolution of ZnO nanorods. Low precursor concentration was proved to be more preferable to the growth of ZnO nanorods, which is attributed to the intrinsic characteristics of chemical reaction in the synthesis of ZnO from zinc compounds.

Estimation of the neutron production of KSTAR based on empirical scaling law of the fast ion stored energy and ion density under NBI power and machine size upgrade

  • Kwak, Jong-Gu;Hong, S.C.
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2334-2337
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    • 2022
  • Deuterium-tritium reaction is the most promising one in term of the highest nuclear fusion cross-section for the reactor. So it is one of urgent issues to develop materials and components that are simultaneously resistant to high heat flux and high energy neutron flux in realization of the fusion energy. 2.45 MeV neutron production was reported in D-D reaction in KSTAR and regarded as beam-target is the dominant process. The feasibility study of KSTAR to wide area neutron source facility is done in term of D-D and D-T reactions from the empirical scaling law from the mixed fast and thermal stored energy and its projection to cases of heating power upgrade and DT reaction is done.

On-Site Construction Method for U-Girder with Pre-tension and Verification of Analytical Performance of Anchoring Block (프리텐션 U형 거더 현장 제작 방법 및 정착 블록 해석적 성능 검증)

  • Park, Sangki;Kim, Jaehwan;Jung, Kyu-San;Seo, Dong-Woo;Park, Ki-Tae;Jang, Hyun-Ock
    • Journal of Korean Society of Disaster and Security
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    • v.15 no.3
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    • pp.67-77
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    • 2022
  • In South Korea, U-type girder development was attempted as a means to increase the length of I-type girder, but due to the large self-weight according to the post-tension method, the application of rail bridges of 30m or less is typical. There are not many examples of application of pre-tension type girder. This study does not limit the post-tension method, but applies the pre-tension method to induce a reduction in self-weight and materials used due to the reduction of the cross-section. In addition, we intend to apply the on-site pre-tensioning method using the internal reaction arm of the U-type girder. The prestressed concrete U-type girder bridge is composed of a concrete deck slab and a composite section. Compared to the PSC I-type, which is an open cross-section because the cross section is closed, structural performance such as resistance and rigidity is improved, the safety of construction is increased during the manufacturing and erection stage, and the height ratio is reduced due to the reduction of its own weight. Therefore, it is possible to secure the aesthetic scenery and economical of the bridge. As a result, it is expected that efficient construction will be possible with high-quality factory-manufactured members and cast-in-place members. In this paper, the introduction of the pre-tension method on-site and the analytical performance verification of the anchoring block for tension are included.

A Study on the Formation Mechanism of Titanium Sponge in the Kroll Process (Kroll법에 의한 타이타늄 스폰지 생성기구에 관한 연구)

  • Jung, Jae-Young;Sohn, Ho-Sang
    • Resources Recycling
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    • v.26 no.5
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    • pp.54-60
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    • 2017
  • In this study, we investigated the effect of $TiCl_4$ injection time on the Kroll reaction at a given weight ratio of $TiCl_4$ and Mg. The reduction reaction was investigated by measuring the temperature change according to $TiCl_4$ injection time and observing the cross section and appearance of the Ti sponge after the reaction. The temperature increment due to Kroll reaction heat generation was found to be linearly proportional to the $TiCl_4$ feed rate. In the graph of $TiCl_4$ injection time and reduction tank temperature, initial temperature peaks were observed irrespective of the injection conditions. This is interpreted to mean a temporary interruption of reaction due to $MgCl_2$ formation after the initial Kroll reaction. In addition, when the cross section of the sponge was observed, a large amount of spherical Mg particles was observed in $MgCl_2$. We can infer that this is the process of continuously feeding the unreacted Mg surface, so that a continuous Kroll reaction takes place. The sponge appearance showed that the coalescence or growth of the Kroll reacted Ti particles can be controlled by the cooling rate.

Design and Optimization for the Windowless Target of the China Nuclear Waste Transmutation Reactor

  • Cheng, Desheng;Wang, Weihua;Yang, Shijun;Deng, Haifei;Wang, Rongfei;Wang, Binjun
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.360-367
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    • 2016
  • A windowless spallation target can provide a neutron source and maintain neutron chain reaction for a subcritical reactor, and is a key component of China's nuclear waste transmutation of coupling accelerator and subcritical reactor. The main issue of the windowless target design is to form a stable and controllable free surface that can ensure that energy spectrum distribution is acquired for the neutron physical design when the high energy proton beam beats the lead-bismuth eutectic in the spallation target area. In this study, morphology and flow characteristics of the free surface of the windowless target were analyzed through the volume of fluid model using computational fluid dynamics simulation, and the results show that the outlet cross section size of the target is the key to form a stable and controllable free surface, as well as the outlet with an arc transition. The optimization parameter of the target design, in which the radius of outlet cross section is $60{\pm}1mm$, is verified to form a stable and controllable free surface and to reduce the formation of air bubbles. This work can function as a reference for carrying out engineering design of windowless target and for verification experiments.

Quantum Mechanical Study of the O(1D) + HCl → OH + Cl Reaction

  • Lin, Shi-Ying;Park, Seung-C.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.229-240
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    • 2002
  • Quantum mechanical calculation is performed for the $O(^1D)$ + HCl ${\rightarrow}$OH + Cl reaction using Reactive Infinite Order Sudden Approximation. Shifting approximation is also employed for the l ${\neq}$ 0 partial wave contributions. Various dynamical quantities are calculated and compared with available experimental results and quasiclassical trajectory results. Vibrational distributions agree well with experimental results i.e. product states mostly populated at $v_f$ = 3, 4. Our results also show small peak at $v_f$ = 0, which indicates bimodal vibrational distribution. The results show two significant broad peaks in ${\gamma}_i$ dependence of the cross section, one is at ${\gamma}_i$ = $15^{\circ}-35^{\circ}$ and the another is at ${\gamma}_i$= $55^{\circ}-75^{\circ}$ which can be explained as steric effects. At smaller gi, the distribution is peaked only at higher state ($v_f$ = 3, 4) while at the larger gi, both lower state ($v_f$ = 0) and higher state ($v_f$ = 3, 4) are significantly populated. Such two competing contributions (smaller and larger ${\gamma}_i$) result in the bimodal distribution. From these points we suggest two mechanisms underlying in current reaction system: one is that reaction occurs in a direct way, while the another is that reaction occurs in a indirect way.

Cross-sectional radiation type micromixer to mixed interface using PZT (PZT를 이용한 계면 교차 방향 방사형 마이크로믹서)

  • Heo, Pil-Woo;Kim, Deok-Jong;Kim, Jae-Yun;Park, Sang-Jin;Yun, Eui-Soo;Koh, Kwang-Sik
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.121-125
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    • 2003
  • Micromixer plays an important role in Bio-MEMS or ${\mu}-TAS$. Mixing is generally generated by turbulence and interdiffusion of two fluids. Because of low Reynolds number(Re << 2000) in ${\mu}-channel$, it is difficult to generate turbulence, so mixing mainly depends on interdiffusion. Thus long channel distance is required to mix two different fluids. To reduce the channel length required for mixing, we propose the a new active ${\mu}-mixer$ that two fluids are effectively mixed in ${\mu}-channel$ by the ultrasonic wave which is generated by PZT. The ultrasonic wave is radiated into a chamber in the cross-section directional direction to interface with the two fluids. The two fluids are positioned one on top of the other. Mixing state is measured by the changing of color due to the reaction of NaOH and phenolphtalein.

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Dissociative Recombination Rates of O₂+ Ion with Low Energy Electrons

  • 성정희;선호성
    • Bulletin of the Korean Chemical Society
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    • v.17 no.11
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    • pp.1065-1073
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    • 1996
  • The dissociative recombination of O2+(v+)+e-→O(1S)+O(1D) has been theoretically investigated using the multichannel quantum defect theory (MQDT). Cross sections and rate coefficients at various electron energies are calculated. The resonant structures in cross section profile, which are hardly measurable in experiments, are also determined and the existence of Rydberg states is found to affect the rates. The theoretical rate coefficients are computed to be smaller than experimental ones. The reasons for this difference are explained. The two-step MQDT procedure is found to be very useful and promising in calculating the state-to-state rates of the dissociative recombination reaction which is a very important and frequently found phenomenon in Earth's ionosphere.

Numerical Analysis of Steam-methane Reforming Reaction for Hydrogen Generation using Catalytic Combustion (촉매 연소를 열원으로 한 수증기-메탄개질반응 전산유체해석)

  • Lee, Jeongseop;Lee, Kanghoon;Yu, Sangseok;Ahn, Kookyoung;Kang, Sanggyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.113-120
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    • 2013
  • A steam reformer is a chemical reactor to produce high purity hydrogen from fossil fuel. In the steam reformer, since endothermic steam reforming is heated by exothermic combustion of fossil fuel, the heat transfer between two reaction zones dominates conversion of fossil fuel to hydrogen. Steam Reforming is complex chemical reaction, mass and heat transfer due to the exothermic methane/air combustion reaction and the endothermic steam reforming reaction. Typically, a steam reformer employs burner to supply appropriate heat for endothermic steam reforming reaction which reduces system efficiency. In this study, the heat of steam reforming reaction is provided by anode-off gas combustion of stationary fuel cell. This paper presents a optimization of heat transfer effect and average temperature of cross-section using two-dimensional models of a coaxial cylindrical reactor, and analysis three-dimensional models of a coaxial cylindrical steam reformer with chemical reaction. Numerical analysis needs to dominant chemical reaction that are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming(DSR) reaction. The major parameters of analysis are temperature, fuel conversion and heat flux in the coaxial reactor.