• Title/Summary/Keyword: Rate-capability

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Evaluation of the Stress Corrosion Cracking Behavior of Inconel G00 Alloy by Acoustic Emission (음향 방출에 의한 인코넬 600 합금의 응력 부식 균열 거동 평가)

  • Sung, Key-Yong;Kim, In-Sup;Yoon, Young-Ku
    • Journal of the Korean Society for Nondestructive Testing
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    • v.16 no.3
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    • pp.174-183
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    • 1996
  • Acoustic emission(AE) response during stress corrosion cracking(SCC) of Inconel 600 alloy has been monitored to study the AE detectability of crack generation and growth by comparing the crack behavior with AE parameters processed, and to evaluate the applicability as a nondestructive evaluation(AE) by measuring the minimum crack size detectable with AE. Variously heat-treated specimens were tensioned by constant extension rate test(CERT) in various extension rate to give rise to the different SCC behavior of specimens. The AE amplitude level generated from intergranular stress-corrosion cracking(IGSCC) is higher than those from ductile fracture and mechanical deformation, which means the AE amplitude can be a significant parameter for distinguishing the An source. AE can also provide the effective means to identify the transition from the small crack initiation and formation of dominant cracks to the dominant crack growth. Minimum crack size detectable with AE is supposed to be approximately 200 to $400{\mu}m$ in length and below $100{\mu}m$ in depth. The test results show that AE technique has a capability for detecting the early stage of IGSCC growth and the potential for practical application as a NDE.

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Performance Evaluation of FDS for Predicting the Unsteady Fire Characteristics in a Semi-Closed ISO 9705 Room (반밀폐된 ISO 9705 화재실에서 비정상 화재특성 예측을 위한 FDS의 성능평가)

  • Mun, Sun-Yeo;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.21-28
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    • 2012
  • The objective of this study is to evaluate the prediction accuracy of FDS(Fire Dynamic Simulator) for the thermal and chemical characteristics of under-ventilated fire with unsteady fire growth in a semi-closed compartment. To this end, a standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time (until maximum 2.0 MW based on ideal heat release rate) using a spray nozzle located at the center of enclosure. To verify the capability of FDS, the predicted results were compared with a previous experimental data under the identical fire conditions. It was observed that with an appropriate grid system, the numerically predicted temperature and heat flux inside the compartment showed reasonable agreement with the experimental data. On the other hand, there were considerable limitations to predict accurately the unsteady behaviors of CO and $CO_2$ concentration under the condition of continuous fire growth. These results leaded to a discrepancy between the present evaluation of FDS and the previous evaluation conducted for steady-state under-ventilated fires. It was important to note that the prediction of transient CO production characteristics using FDS was approached carefully for the under-ventilated fire in a semi-closed compartment.

Electrochemical Characteristics of Lithium Battery Anode Materials Using Petroleum Pitches (석유계 피치를 사용한 리튬전지 음극소재의 전기화학적 특성)

  • Hwang, Jin Woong;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.534-538
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    • 2017
  • In this study, the molecular weight controlled pitches derived from pyrolyzed fuel oil (PFO) were prepared using solvent extraction and were carbonized. Electrochemical characteristics of lithium battery anode materials were investigated using these petroleum pitches. Three pitch samples prepared by the thermal reaction were 3903 (at $390^{\circ}C$ for 3 h), 4001 (at $400^{\circ}C$ for 1 h) and 4002 (at $400^{\circ}C$ for 2 h). The prepared hexane insoluble pitches were analysed by XRD, TGA, SEM and Gel permeation Chromatography (GPC). The electrochemical characteristics of the PFO-derived pitch as an anode material were investigated by constant current charge/discharge, cyclic voltammetry and electrochemical impedance tests. The coin cell using pitch (4001) and the electrolyte of $LiPF_6$ in organic solvents (EC : DMC = 1 : 1 vol%, VC 3 wt%) has better initial capacity (310 mAh/g) than that of other pitch coin cells. Also, this carbon anode showd a high initial efficiency of 82%, retention rate capability at 2 C/0.1 C of 90% and cycle retention of 85%. It was found that modified pitches improved the cycling and rate capacity performance.

The Effects of Partial Substitution of Mo and Heat Treatment on the Electrode Characteristics of ZrV0.1Mn0.7Ni1.2 Hydrogen Storage alloy (Ni-MH 2차 전지용 ZrV0.1Mn0.7Ni1.2 수소저장합금의 전극특성에 미치는 Mo의 부분치환과 열처리의 영향)

  • Han, Dongsoo;Oh, Myunghark;Jeong, Chigyu;Chung, Wonsub;Kim, Ingon
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.1
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    • pp.16-24
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    • 1998
  • Recently Zr-based $AB_2$ type hydrogen absorbing alloy has received much attention as a negative electrode material for the Ni-MH batteries because of its high capacity. In this study $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ alloy was chosen and the effects of heat treatment and a partial substitution of the Mo in Mn site on the various electrode properties were investigated. The alloys was prepared by arc melting (as-cast sample). Some of them were heat treated at $1,100^{\circ}C$ for 4 hours. After this they were differentiated by the different cooling rates of slow cooling and quenching. Various electrode characteristics such as activation process, high rate dischargeability and self discharge characteristic were investigated with the three types of electrodes. It was found that heat treated alloys resulted in an increase in plateau flatness of P-C isotherms however both discharge capacity and high rate capability were decreased. And the partial substitution of Mo for Mn in $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ alloy improved the self-discharge characteristic without the loss of discharge capacity (300mAh/g).

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Residual Energy-Aware Duty-Cycle Scheduling Scheme in Energy Harvesting Wireless Sensor Networks (에너지 생산이 가능한 무선 센서 네트워크에서 잔여 에너지 인지 듀티-사이클 스케줄링 기법)

  • Lee, Sungwon;Yoo, Hongseok;Kim, Dongkyun
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39B no.10
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    • pp.691-699
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    • 2014
  • In order to increase network lifetime, duty-cycle MAC protocols which can reduce energy consumption caused by idle listening is proposed for WSNs. In common duty-cycle MAC protocols, each sensor node calculates its duty-cycle interval based on the current amount of residual energy. However, in WSNs with the capability of energy harvesting, existing duty-cycle intervals based on the residual energy may cause the sensor nodes which have high energy harvesting rate to suffer unnecessary sleep latency. Therefore, a duty-cycle scheduling scheme which adjust the duty-cycle interval based on both of the residual energy and the energy harvesting rate was proposed in our previous work. However, since this duty-cycle MAC protocol overlooked the performance variation according to the change of duty-cycle interval and adjusted the duty-cycle interval only linearly, the optimal duty-cycle interval could not be obtained to meet application requirements. In this paper, we propose three methods which calculate the duty-cycle interval and analyse their results. Through simulation study, we verify that network lifetime, end-to-end delay and packet delivery ratio can be improved up to 23%, 44% and 31% as compared to the existing linear duty-cycle scheduling method, respectively.

Accelerated Formation of Surface Films on the Degradation of LiCoO2 Cathode at High Temperature (표면 피막 형성이 LiCoO2 양극의 고온 열화에 미치는 영향)

  • Sung, Jong Hun;Hasan, Fuead;Yoo, Hyun Deog
    • Journal of the Korean Electrochemical Society
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    • v.23 no.3
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    • pp.57-65
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    • 2020
  • It is crucial to investigate the thermal degradation of lithium-ion batteries (LIBs) to understand the possible malfunction at high temperature. Herein, we investigated the effects of surface film formation on the thermal degradation of lithium cobalt oxide (LiCoO2, LCO) cathode that is one of representative cathode materials. Cycling test at 60℃ exhibited poorer cycleability compared with the cycling at 25℃. Cathodes after the initial 5 cycles at 60℃ (60-LCO) exhibited higher impedance compared to the cathode after initial 5 cycles at 25℃ (25-LCO), resulting in the lower rate capability upon subsequent cycling at 25℃, although the capacity values were similar at the lowest C-rate of 0.1C. In order to understand degradation of the LCO cathode at the high temperature, we analyzed the cathodes surface using X-ray photoelectron spectroscopy (XPS). Among various peaks, intensity of lithium hydroxide (LiOH) increased substantially after the operation at 60℃, and the C-C signal that represents the conductive agent was distinctly lower on 60-LCO compared to 25-LCO. These results pointed to an excessive formation of cathode-electrolyte interphase including LiOH at 60℃, leading to the increase in the resistance and the resultant degradation in the electrochemical performances.

Recommendation of Nitrogen Fertilization for Cucumber from Relationship between Soil Nitrate Nitrogen and Yield (토양의 질산태 질소와 수량과의 관계를 통한 오이의 질소 시비량 설정)

  • Lim, Tae-Jun;Hong, Soon-Dal;Kim, Seung-Heui;Park, Jin-Myeon
    • Korean Journal of Environmental Agriculture
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    • v.26 no.3
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    • pp.223-227
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    • 2007
  • This study was carried out to establish the reasonable level of nitrogen (N) fertilization based on soil nitrate nitrogen $(NO_3-N)$ content for cucumber (Cucumis sativus L.) under plastic film house. Cucumber plants were cultivated with standard and free N fertilization in eight soils which had various amount of $NO_3-N$ ranging from 67 to 343 mg/kg. The yield of cucumber was in the range of 1006 to 2369 g/plant depending on the nitrogen supplying capability of soils. The amount of $NO_3-N$ in the soil was negatively correlated with agronomic efficiency (AE) and N use efficiency (NUE). The critical level of soil $NO_3-N$ content for cucumber in N free fertilization was found to be about 260 mg/kg in Cate-Nelson analysis of variance between soil $NO_3-N$ and AE or NUE. Also the same critical soil $NO_3-N$ content was found in the yield and amount of N uptake of cucumber under N free fertilization. A standard N fertilization was required when soil $NO_3-N$ content was below 70 mg/kg. The optimal application rate of N fertilizer for cucumber in the soils containing $NO_3-N$ between 260-70 mg/kg could be recommended by the equation Y=-1.032X+269.2 (Y: N fertilization rate, kg/ha; X : soil $NO_3-N$ content mg/kg).

A Study of Nurses' Knowledge, Attitude on the Nurses' Law and Nurses' Perception on the Causes, Coping Patterns with the Nursing Accidents (간호사의 간호관련법에 대한 지식$\cdot$태도 및 간호사고에 대한 원인$\cdot$대처양상에 관한 연구)

  • Mun Heui Ja;Lee Mi Aie
    • Journal of Korean Public Health Nursing
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    • v.13 no.1
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    • pp.41-62
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    • 1999
  • Recently the request of the patients to participate in the medical courses has been expanding due to elevated sense of right on the people's health. merchandised medical treatment by mass supply, human right declaration of the patients, generalized medical informations by the mass media and the change of human relation between the medical personnels and the patients. Under these phenomena the accident by the nurses have been increasing by the area of the nurses having been expanded and their independent roles having been increased. Such nursing accidents are the important subject which the professional occupation of the nurses has been facing but legal protective capability of the nurses has been very weak. Therefore this study has examined the degree of the experience of the nursing accident that happens in the clinical nursing scenes in the general hospital to provide the basic materials for the protection and the counter measures of the nursing accidents. The following is the conclusion based by the above examination. 1) The general characters of the subjects of this study is that they are mostly single in their twenties and graduate from nursing college. Their total clinical career is above 5 years$(44.8\%)$ and their current clinical parts' career is between 1-3 years$(40.1\%)$. So these facts suggest that most hospitals has taken the working rotation policy on nurses. 2) The level of nurses' knowledge on the nursing law is accurate partially but isn't it patially. So it is suggested that nurses need the accurate information and education about the nursing law. But the nurses' attitude is very approved of the establishment of a unilateral nursing law. 3) The relation between the demographic characters of the subjects and their attitudes on the nursing law shows that there is no significant differences except the relation between the attitude 6(the sufficient level of education on nursing law in formal education course) and age. total clinical career. 4) The perception of the nurses shows that the cause of the nursing accident has been due to the heavy work$(78.2\%)$. short of professional knowledge and skill$(60.2\%)$, discordance with Doctors. patients and patients' families. They report the accident to the head nurse first$(81.8\%)$ and within 30 minute$(75.1\%)$. The hour of nursing accident frequently happened is regardless of service hour with $49.4\%$ in response rate. the highest rate. and the nursing accident happens in the night more than the daytime. Even though most nurses think that they are themselves responsible for nursing accident. it is found that the chief cause of the nursing accident is due to the nurses' heavy work$(78.2\%)$. So the causes of nursing accidents is analysed. it may be suggested that the endeavor of hospital and nursing organizations to decrease nursing accidents is very important. 5) The coping patterns of patients with nursing accidents are mostly active attitude such as a violent words$(69\%)$. sue or accusation$(36.4\%)$, monetary compensation $(35.6\%)$ except a understanding cases$(38.7\%)$. But the coping patterns of hospitals with nursing accidents are mostly to investigate the accurate cause.

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Anti-cancer Activity of Lentinus edoeds and Pleurotus astreatus (표고버섯과 느타리 버섯의 항암효과)

  • Park, Moo-Hyun;Oh, Kook-Yong;Lee, Byung-Woo
    • Korean Journal of Food Science and Technology
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    • v.30 no.3
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    • pp.702-708
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    • 1998
  • The effects of mushrooms such as Lentinus edodes and Pleurotus ostreatus on anti-cancer activity through in vivo and in vitro experiments were powders of protein-bound polysaccharides in mushrooms were solubilized in 0, 5, 25 mg/kg saline, respectively and were used in vitro experiments. The in vivo experiments were carried out as followed: i) anti-cancer activities on Leukemia $(L_{1210})$, Hepatlicus cancer $(H_{22})$ and Sarcoma180/(S180), and ii) the effect on immune system through changes in intestine weight and the number of hemolytic plague forming cells. Protein-bound polysaccharides of all showed anti-cancer activity on $L_{1210}$ and fruit body of Lentinus edodes 25 mg/kg treatment group showed the highest inhibition rate (86%). Pleurotus ostreatus mycelial in medium of cultivate 25 mg/kg treatment. Fruid body of Lentinus edodes 25 mg/kg treatment group showed the highest inhibition rate (86% and 71%, respectively) on $H_{22}$ among them. The inhibition rates of fruit body and mycelial of Lentinus edodes 25 mg/kg treatment groups on S180 were 33.9% and 30.9%, respectively. Each samples of 50, 100, 200, $400\;{\mu}g/{\mu}L$ on in vitro cell toxicity test did not show significantly different cell death rates at P<0.05. In immune test, weights of liver and spleen were increased according to increase in conc. but were not significantly different at P<0.05. The weights of thymus were heavy in fruit body and mycelial of Lentinus edodes treatment group but were not significantly different at P<0.05. Hemolytic plague forming cells with antibody formation capability were significantly high in fruit body and mycelial of Lentinus edodes treatment samples.

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Estimation of Water Quality Environment in Youngsan and Seumjin River Basins (영산강과 섬진강 유역의 하천 수질환경 평가)

  • 양해근;최희철
    • Journal of the Korean Geographical Society
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    • v.38 no.1
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    • pp.16-31
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    • 2003
  • The water quality environment in Youngsan and Seumjin river basins was investigated based on the concept of the comprehensive Water Quality Index (WQI) and a spacial pollution source. Artificial factors influencing to river water quality have been analyzed. The specific delivery load of Youngsan river basin was found to be 8.34~97.25 kg/day/$\textrm{km}^2$, Gomagwon stream and Gwangju stream showed the relatively high rates as 97.25 kg/day/$\textrm{km}^2$ and 86.06 kg/day/$\textrm{km}^2$, respectively. The specific delivery load in Seumjin river basin was estimated to be 10.98∼19.51 kg/day/$\textrm{km}^2$, Suggesting no Significant Contribution of pollution. WQI of Youngsan watershed revealed 1.36~3.45, whereas Seumjin watershed showed a relatively low value of 0.5~1.47 And it is concluded that the specific delivery load suggested in this study provides the essential core data of the upper limit of pollutants receptor in the watershed area studied. From this study, it is suggested that the integrated environmental management of river basin requires the analysis of pollutants generation rate of the basin and the receptor capability for the self-purification.