• Title/Summary/Keyword: Rare-earth garnet

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Geochemical Relationship Between Shore Sediments and Land Geology in Keum River Area, West Coast of Korea (한반도 서해안 금강하구 연안퇴적물과 육상지질과의 지화학적 상관관계)

  • 지정만;장윤호;오재경;이연희
    • Economic and Environmental Geology
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    • v.33 no.6
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    • pp.447-467
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    • 2000
  • This study was carried out geochemically and mineralogically to define how Kunsan shore sediments are related to their terrestrial source rocks in the region of Keum River Basin, western Korea. As a whole the chemical composition for major elements, trace elements and rare earth elements analysis from shore sediments and river bed sediments doesn't show the big difference, and especially rare earth elements chondrite normalized patterns are almost same. Heavy minerals of shore sediments are identified as hornblende, epidote, ilmenite, garnet, hematite, magnetite, sphene and rutile. Compared with Taean Area of Seo et al. (1998) and Byeonsan Area of Kwon et al. (1999), Kunsan shore sediments of this study area were origined mostly from Keum River Basin.

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Petrology of Charnockite in Sancheong Area (산청지역에 분포하는 챠노카이트의 암석학적 연구)

  • Lee, Sang-Won;Ock, Soo-Seck;Lee, Young-Taek
    • Journal of the Korean earth science society
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    • v.25 no.4
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    • pp.251-264
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    • 2004
  • The Charnockite in Sancheong region is quarzofeldspathic rock containing orthopyroxene and garnet with a color dark than common granitic rocks. The Chamockite are mostly massive and medium to coarse-grained with K-feldspar phenocryst, but reveal weak foliation. The rock consist mainly of quartz, K-feldspar, plagioclase and orhopyroxene, with biotite, garnet, and anthophyllite. In petrochemistry, the Chamockite has 61-65% $SiO_2$ contents, varying gradually into the margin contacted with orthogneiss, which have compositions of felsic igneous rocks. Major element show almost systematical variation with those of the marginal orthogneisses, except the hornblende gneiss and anorthosite. The Charnockite and orthogneisses show the tholeiitic differentiational trend. Trace and rare earth element abundance patterns in the Charnockite show remarkable negative Sr and Eu anomalies similar to orthogneisses, but different from the hornblende gneiss and anorthosite. Eu contents of the Charnockite are richer than that of orthogneisses. The metamorphic condition of the Charnockite were tested by an orthopyroxene-garnet geotherrnorneter and a plagioclase-garnet geobarometer. Estimated P-T conditions are about $761^{\circ}C$ and 7 kbar at peak metamorphism, but $653^{\circ}C$ and 6.4 kbar at retrograde metamorphism. This suggests that the Charnockite have from an early stage of high-grade metamorphism to represent the granulite facies and then to a late stage medium-grade metamorphism belonging to the amphibolite facies.

Microstructure Related to the Growth of Rare-earth Mineral in the Eoraesan Area, Chungju, Korea (충주 어래산 지역에서 희토류 광물의 성장과 관련된 미구조)

  • Kang, Ji-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.28 no.2
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    • pp.129-141
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    • 2019
  • The Eoraesan area, Chungju, which is located in the northwestern part of Ogcheon Metamorphic Zone, Korea, mainly consists of the Neoproterozoic Gyemyeongsan Formation and the Mesozoic igneous rocks which intruded it. The metaacidic rocks (MAR) of the Gyemyeongsan Formation show a maximum radioactive value, and the Early Jurassic biotite granite is regionally distributed in this area. In this paper is researched the microstructure related to the growth of rare-earth mineral of allanite in the MAR, and is considered the source and occurrence time of rare-earth element (REE) mineralization. The MAR is mainly composed of alkalic feldspar (mainly microcline), quartz, iron-oxidizing mineral, biotite, muscovite, plagioclase, hornblende, allanite, zircon, epidote, fluorite, apatite, garnet, (clino)zoisite etc. The radioactive elements contained in the allanite cause a dark brown hale in the surrounding biotite, and the allinte also occurs as aggregate along the regional foliation. The deflection of regional foliation and the strain shadows, which are common to the pre-tectonic porphyroblast grown before the formation of regional foliation, can't be observed around most allanites (aggregates). The grain size and orientation of ironoxidizing mineral included in the allanite aggregate are the same as those in the matrix. It is recognized the hydrothermal conversion of hornblende to biotite due to the intrusion of igneous rock, and the secondary biotite occurs and contacts with allanite, zircon, epidote etc. These microstructures indicate that the rare-earth mineral of allanite (aggregate) grew by the hydrothermal alteration due to the intrusion of igneous rock after the formation of regional foliation. It is considered that the REE mineralization is closely related to the intrusion of Early Jurassic biotite granite which is regionally distributed in this area.

Temperature Dependent Cation Distribution in Tb2Bi1Ga1Fe4O12

  • Park, Il-Jin;Park, Chu-Sik;Kang, Kyoung-Soo;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.13 no.3
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    • pp.110-113
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    • 2008
  • In this study, heavy rare earth garnet $Tb_2Bi_1Ga_1Fe_4O_{12}$ powders were fabricated by a sol-gel and vacuum annealing process. The crystal structure was found to be single-phase garnet with a space group of Ia3d. The lattice constant $a_0$ was determined to be 12.465 ${\AA}$. From the analysis of the vibrating sample magnetometer (VSM) hysteresis loop at room temperature, the saturation magnetization and coercivity of the sample are 7.64 emu/g and 229 Oe, respectively. The N$\acute{e}$el temperature($T_N$) was determined to be 525 K. The M$\ddot{o}$ssbauer spectrum of $Tb_2Bi_1Ga_1Fe_4O_{12}$ at room temperature consists of 2 sets of 6 Lorentzians, which is the pattern of single-phase garnet. From the results of the M$\ddot{o}$ssbauer spectrum at room temperature, the absorption area ratios of Fe ions on 24d and 16a sites are 74.7% and 25.3%(approximately 3:1), respectively. These results show that all of the non-magnetic Ga atoms occupy the 16a site by a vacuum annealing process. Absorption area ratios of Fe ions are dependent not only on a sintering condition but also on the temperature of the sample. It can then be interpreted that the Ga ion distribution is dependent on the temperature of the sample. The M$\ddot{o}$ssbauer measurement was carried out in order to investigate the atomic migration in $Tb_2Bi_1Ga_1Fe_4O_{12}$.

Scintillating properties of Bi-doped $Y_3Ga_5O_{12}$

  • Novoselov, Andrey;Yoshikawa, Akira;Nikl, Martin;Fukuda, Tsuguo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.6
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    • pp.233-235
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    • 2004
  • Shaped single crystals of Bi : $Y_3Ga_5O_{12}$(Bi = 0.041, 0.047 and 0.061 mol%) were grown by the micro-pulling-down method. Optical absorption spectra show an absorption band at 288 nm ascribed to the lowest energy $6s^2$ \longrightarrow 6s6p transition of $Bi^{3+}$ , while luminescence spectra demonstrate the band at 314 nm ascribed to the reverse radiative transition of the excited $Bi^{3+}$ centres. At room temperature, dominant decay time component was found to be about 440 ns with a minor slower component 580 ns.

Detect to Impulse Large Current based on faraday Effect (파라데이효과를 이용한 임펄스 대전류 측정)

  • Park, Hae-Soo;Kim, Yo-Hee
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.505-507
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    • 1995
  • Applications of the fiber optic sensing are glowing rapidly, particularly in situations where size, weight, speed, and immunity to electromagnetic interference are important considerations. The fiber optic current sensors have been developed for low frequency(60Hz) metering in electric power systems. But we try measure to high frequency large current by fiber optic current sensor based on Bi substituted rare earth iron garnet. In this paper, we report the linearity to 500 amperes and frequency response of signal processor and a result of detection the standard impulse large current of fiber optic impulse sensor system.

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Petrochemical Characteristics of the Duibaejae Volcanic Rocks from Goseong, Gangwon-do, Korea (강원도 고성 뒤배재 화산암의 암석화학적 특성)

  • Kim, Hwa Sung;Kil, Youngwoo;Lee, Moon Won
    • Journal of the Korean earth science society
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    • v.34 no.2
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    • pp.109-119
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    • 2013
  • Duibaejae basalts from Goseong, Gangwon-do, are divided into the lower basalt and the upper basalt depending on the properties, such as occurrence, mineral compositions, and major and trace compositions of the basalts. The lower basalts have characteristics of agglomerate rocks as well as contain, crustal and mantle xenoliths, and olivine, pyroxene, and plagioclase xenocrysts. The upper basalts with columnar joints contain relatively more mantle xenolith and olivine xenocryst than the lower basalts. The major and trace element compositions suggest that the composition of the upper basalts is close to primary magma composition. Enrichment and depletion patterns of the trace and the rare-earth elements of the lower basalts are similar to those of the upper basalts, whereas the lower basalts are more LREE enriched than the upper basalts. The source magmas of the lower and upper basalts from Duibaejae volcanic edifice were generated from about 0.8-1.2% and 3.7-4.0% batch melting of garnet peridotite, respectively. The abundance of granite xenolith, and plagioclase and quartz xenocrysts with reaction rim indicates that the lower basalts, compared with upper basalts, might have been assimilated with the crustal materials during ascending to surface.

Geochemical Relationship Between Stream Sediments and Regional Geology of the Upstream for the Hahn River Drainage Basin, Korea. (한강상류 하상퇴적물과 인근유역육상지질과의 지화학적 상관관계)

  • 이연희;지정만;오재경
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.153-171
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    • 2004
  • This study was carried out to define the geochemical and mineralogical relationship between stream sediments and regional geology on upstream of Hahn river area. Geochemical characteristic including for major elements, trace elements and rare earth elements of the South and North Hahn river bed sediments are similar to those of acid igneous rocks which are distributed around both Hahn river basin. The chemical variation of major elements against SiO$_2$ and trace elements contents between South and North Hahn river bed sediments doesn't show the difference. REE patterns of both area show a distinct negative Eu anomaly, but total contents of rare earth elements are higher in North Hahn river sediments than South Hahn river sediments. The heavy minerals in the river bed sediments in this study area are identified as tremolite-actinolite, hematiteㆍmagnetite, common hornblende, ilmenite, garnet, epidote, rutile and sphene. In conclusion, it is elucidated that South and North Hahn river bed sediments are being originated from igneous rocks or metamorphic rocks which contains medium-high grade metamorphic minerals and components of originated from sedimentary rocks those of politic or calcareous rocks are eroded away as solution or suspended load.

Mineralogy of Sea Sand Near Ongjingun through the Separation Processes (옹진군 해사의 선별공정에 따른 광물학적 특성)

  • Chae, Soo-Chun;Shin, Hee-Young;Bae, In-Kook;Kwon, Sung-Won;Lee, Chun-Oh;Kim, Jung-Yoon;Jang, Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.1
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    • pp.1-17
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    • 2011
  • Mineralogical study was carried out for heavy minerals in the sea sand near Ongjingun bay, Kyonggi-do separated using the gravity and magnetic separators. Ilmenite, zircon and minor monazite and garnet were valuable minerals with gangue minerals of quartz, K-feldspar, plagioclase, muscovite, hornblende, epidote and chlorite. Quantitative analysis with SIROQUANT program showed that the contents of ilmenite separated with the gravity separation (the shaking table separation), the 1st step magnetic separation (rare earth magnetic separation) and the 2nd step magnetic separation (the Eddy current magnetic separation) were increased into 0.8, 18.3, and 48.7%, respectively. The content of ilmenite, monazite and zircon were recalculated based on the chemical composition of the representative and heavy fraction products of raw sand, the 1 step and 2 step gravity separations, and the 1 step and 2 step magnetic separations. The content increased to 0.23, 0.55, 5.22, 16.17, and 44.99% in ilmenite, 0.11, 0.02, 0.16, 0.51, and 1.19% in monazite. Although the zircon content did not differ over the processes (0.13, 0.12, 0.11, 0.15, and 0.10%), the improved recovery of zircon is expected by applying sieving process because of its high content (27%) in the fine grain size fraction (< 140#) of the 2 step gravity separation.

Separation and Mineralogy of Marine Sand Near Haeju bay, North Korea (북한 해주만 부근 해사의 선별 및 광물학적 특성)

  • Chae, Soo-Chun;Shin, Hee-Young;Bae, In-Kook;Kwon, Sung-Won;Lee, Soo-Jung;Kim, Wan-Tae;Lee, Chun-Oh;Jang, Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.3
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    • pp.217-227
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    • 2009
  • Heavy minerals in the marine sand near Haeju bay, Hwanghae-do, North Korea were separated using the gravity and the magnetic separators. And their mineralogical study was carried out. Ilmenite, magnetite, hematite, zircon and monazite were observed as the valuable minerals, and quartz, orthoclase, muscovite, hornblende and garnet existed as gangue minerals. In the result of quantitative analysis with SIROQUANT program, the contents of the valuable minerals separated with the 2nd gravity separation (the shaking table separation), the 1st magnetic separation (rare earth magnetic separation) and the 2nd magnetic separation (the Eddy current magnetic separation) were increased into 4%, 10% and 76~89% (under the condition of 7000 G and 10000 G in magnetic strength), respectively. The contents of ilmenite, monazite and zircon recalculated from the chemical composition differed from the results of the quantitative analyses by SIROQUANT program, but the entire tendency bears some analogy with it. Under the conditions of 7000 G and 10000 G in 2nd magnetic separation the contents of ilmenites were concentrated with 53% and 66%, respectively. The content of monazite was 1.2% in the magnetic fractions of the 1st magnetic separation. The content of zircon was shown 1.4% under the condition of 10000 G in the 2nd magnetic separation, and was displayed 9% in +50 mesh of non-magnetic fraction of 1st magnetic separation, especially.