• Title/Summary/Keyword: Rare

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Environmental Applications of Rare-Earth Manganites as Catalysts: A Comparative Study

  • Alami, D.
    • Environmental Engineering Research
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    • v.18 no.4
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    • pp.211-219
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    • 2013
  • Rare-earth manganites have a great potential for environmental applications based on their chemical and physical properties. The use of rare-earth manganites as catalysts for environmentally essential reactions was reviewed. Artificial neural networks were used to assess the catalytic activity in oxidation reactions. Relative catalytic activities of the catalysts were further discussed. We concluded that cerium manganite is the most practicable catalyst for technological purposes.

Rare earth oxide luminescence materials via electrospinning: synthesis and characteristics

  • Hou, Zhiyao;Lin, Jun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.200-203
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    • 2009
  • One-dimensional rare earth oxide luminescence nano materials have been prepared by a combination method of sol-gel process and electrospinning. Systematic studie s on optical properties indicate that electrospinning is a facile and novel route for development luminescen ce materials that are useful in fluorescent lamps an d field emission dispalys.

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Analysis of Changes in Trade Structure of the Raw Materials of Rare Metals in Korea (국내 희유금속 원재료 교역구조 변화 분석 연구)

  • Hwa Suk Lee;Yu Jeong Kim
    • Resources Recycling
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    • v.32 no.6
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    • pp.67-78
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    • 2023
  • The rare metals used as raw materials in high-tech industries undergo changes in demand structures and supply chains following domestic industrial structural shifts and technological advancements, exhibiting high price volatility. Therefore, it is necessary to periodically analyze changes in the demand structures of rare metals. Since domestic demand for most rare metals relies on imports in Korea, the changes in domestic demand for rare metals can be identified by analyzing changes in their trade structure. In the present study, we analyze the changes in trade volume, trade growth rate, trade rankings, and trading countries from 2000 to 2022 for 35 rare metals, categorized into five types-ores, metals, alloys, compounds, and scrap. The trade of the raw materials of rare metals in Korea has generally increased since the 2000s, except for a significant decline in 2009 and 2016. The total trade volume, encompassing both exports and imports, has increased by approximately tenfold in 2022 compared to 2001. Until the mid-2010s, the trade of the raw materials of rare metals was primarily focused on those used in steel-manufacturing such as silicon, nickel, chrome, molybdenum, manganese, and others. However, after that period, there has been an increase in the trade of platinum group metals like palladium, rhodium, platinum, and the raw materials of rare metals for secondary battery-manufacturing such as lithium and cobalt. Particularly in 2022, lithium has become the largest share in trade of the raw materials of rare metals in Korea, due to the price surge and increase in demand.

A Study on Addition of Rare Earth Element in the Spent Permanent Magnet Scrap to Gray Cast Iron (회주철에서의 폐 영구자석 스크랩을 활용한 희토류 원소 첨가 영향 연구)

  • Park, Seung-Yeon;Noh, Jung-Hyun;Kim, Hyo-jung;Lim, Kyoung-Mook
    • Resources Recycling
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    • v.27 no.3
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    • pp.48-57
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    • 2018
  • In this study, we developed a method for manufacturing high strength gray cast irons by adding a rare earth element (R.E.) included in a spent permanent magnet scrap to gray cast irons. The improvement of the mechanical properties of gray cast irons is attributed to A-type graphite formation promoted by complex sulfide, which was formed by R.E. in the spent magnets during a solidification process. The cast specimen inoculated by R.E. in the spent magnet scrap showed excellent tensile strength up to 306 MPa, and is similar to that of the specimen inoculated by expensive misch-metal. In this regards, we concluded that the cheap spent magnets scrap is a very efficient inoculation agent in fabrication of high performance gray cast irons.

Development of The Criticality Evaluation System for Rare Metals Stockpiling (희유금속 비축 적정성 평가체계 수립)

  • Kim, Yu-Jeong;Kim, Dae-Hyung;Kim, Jinsoo;Kim, Juhan
    • Resources Recycling
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    • v.27 no.3
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    • pp.66-77
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    • 2018
  • The import amount of rare metal in Korea is about 6,034 million USD, but the self-sufficiency of rare metals is about only 1%. In order to secure the stable supply of rare metals, it is necessary to operate an efficient stockpile system. In this study, we established a system to assess the adequacy of stockpiles by quantifying the risk factors of tangible and intangible risks in order to establish an efficient stockpile strategy. The model developed in this study aims to select the rare metals that need to be stockpiled first and to suggest the direction of the stockpiling policy in accordance with technological change and market change from the mid and long term viewpoint. The evaluation results derived from the model can quantitatively measure the security level of each rare metal and enable relative comparison between the rare metals using criticality matrix. Therefore, it is expected that more efficient stockpile policy will be possible if the proposed model is utilized in the future policy making.

Immobilization of Radioactive Rare Earth oxide Waste by Solid Phase Sintering (고상소결에 의한 방사성 희토류산화물의 고화)

  • Ahn, Byung-Gil;Park, Hwan-Seo;Kim, Hwan-Young;Lee, Han-Soo;Kim, In-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.49-56
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    • 2010
  • In the pyroprocessing of spent nuclear fuels, LiCl-KCl waste salt containing radioactive rare earth chlorides are generated. The radioactive rare earth oxides are recovered by co-oxidative precipitation of rare earth elements. The powder phase of rare eath oxide waste must be immobilized to produce a monolithic wasteform suitable for storage and ultimate disposal. The immobilization of these waste developed in this study involves a solid state sintering of the waste with host borosilicate glass and zinc titanate based ceramic matrix(ZIT). And the rare-earth monazite which synthesised by reaction of ammonium di-hydrogen phosphate with the rare earth oxides waste, were immobilzed with the borosilicate glass. It is shown that the developed ZIT ceramic wasteform is highly resistant the leaching process, high density and thermal conductivity.

A Pre-processing Study to Solve the Problem of Rare Class Classification of Network Traffic Data (네트워크 트래픽 데이터의 희소 클래스 분류 문제 해결을 위한 전처리 연구)

  • Ryu, Kyung Joon;Shin, DongIl;Shin, DongKyoo;Park, JeongChan;Kim, JinGoog
    • KIPS Transactions on Software and Data Engineering
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    • v.9 no.12
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    • pp.411-418
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    • 2020
  • In the field of information security, IDS(Intrusion Detection System) is normally classified in two different categories: signature-based IDS and anomaly-based IDS. Many studies in anomaly-based IDS have been conducted that analyze network traffic data generated in cyberspace by machine learning algorithms. In this paper, we studied pre-processing methods to overcome performance degradation problems cashed by rare classes. We experimented classification performance of a Machine Learning algorithm by reconstructing data set based on rare classes and semi rare classes. After reconstructing data into three different sets, wrapper and filter feature selection methods are applied continuously. Each data set is regularized by a quantile scaler. Depp neural network model is used for learning and validation. The evaluation results are compared by true positive values and false negative values. We acquired improved classification performances on all of three data sets.

Responses of Soil Rare and Abundant Sub-Communities and Physicochemical Properties after Application of Different Chinese Herb Residue Soil Amendments

  • Chang, Fan;Jia, Fengan;Guan, Min;Jia, Qingan;Sun, Yan;Li, Zhi
    • Journal of Microbiology and Biotechnology
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    • v.32 no.5
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    • pp.564-574
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    • 2022
  • Microbial diversity in the soil is responsive to changes in soil composition. However, the impact of soil amendments on the diversity and structure of rare and abundant sub-communities in agricultural systems is poorly understood. We investigated the effects of different Chinese herb residue (CHR) soil amendments and cropping systems on bacterial rare and abundant sub-communities. Our results showed that the bacterial diversity and structure of these sub-communities in soil had a specific distribution under the application of different soil amendments. The CHR soil amendments with high nitrogen and organic matter additives significantly increased the relative abundance and stability of rare taxa, which increased the structural and functional redundancy of soil bacterial communities. Rare and abundant sub-communities also showed different preferences in terms of bacterial community composition, as the former was enriched with Bacteroidetes while the latter had more Alphaproteobacteria and Betaproteobacteria. All applications of soil amendments significantly improved soil quality of newly created farmlands in whole maize cropping system. Rare sub-communitiy genera Niastella and Ohtaekwangia were enriched during the maize cropping process, and Nitrososphaera was enriched under the application of simple amendment group soil. Thus, Chinese medicine residue soil amendments with appropriate additives could affect soil rare and abundant sub-communities and enhance physicochemical properties. These findings suggest that applying soil composite amendments based on CHR in the field could improve soil microbial diversity, microbial redundancy, and soil fertility for sustainable agriculture on the Loess Plateau.

An Improved Selective Isolation of Rare Actinomycetes from Forest Soil

  • Seong, Chi-Nam;Park, Ji-Heok;Baik, Keun-Shik
    • Journal of Microbiology
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    • v.39 no.1
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    • pp.17-23
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    • 2001
  • Various pretreatment procedures and selective media were applied to assess the optimal conditions for the isolation of rare actinomycetes from soil. Pretreatment of wet-heating for 15 min at 70$^{\circ}C$ and phenol treatment of soil suspension were the most effective methods for the isolation of these microorganisms. Hair hydrolysate vitamin agar (HHVA) was the most suitable medium for the recovery of rare actinomycetes. Thirty-five rare actinomycete strains were chosen using selective isolation approaches, then morphological and chemical properties of the isolates were determined. The isolates belonged to one of the following genus, Micromonospora, Microbispora, Actinoplanes and Streptosporangium.

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Studies on the Stability constants of complexes between rare earth elements and ethylenediaminediacetic acid (몇가지 희토류원소와 Ethylenediaminediacetic acid간의 착물의 안정도상수 측정)

  • Cha, Ki-Won;Hyun, In-Seong;Choi, Hyun-Chol
    • Analytical Science and Technology
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    • v.14 no.4
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    • pp.371-375
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    • 2001
  • The stability constants of complexes between rare earth elements(Yb, Dy, Sm, Nd, Pr, Ce, La) and ethylenediaminediacetic acid(EDDA) have been measured for the separation of rare earth elements by potentiometric method. The $pk_1s$ of $MA^+$ complexes are in the range of 8.80-6.72 and the $pk_2s$ of $MA_2^-$ complexes are in the range of 7.43-4.37. The magnitude sequences of the stability constants are the reverse of the ionic size of rare earth elements.

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