• Environmental Mutagens and Carcinogens
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• v.24 no.1
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• pp.33-39
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• 2004

To validate and to estimate the chemical hazard playa very important role to environment and human health. The detection of many synthetic chemicals including agrochemicals that may pose a genetic hazard in our environment is of great concern at present. Since these substances are not limited to the original products, and enter the environment, they have become widespread environmental pollutants, thus leading to a variety of chemicals that possibly threaten the public health. Pyrazosulfuron-ethyl [Ethyl-5-(4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl)-1-methylpyrazole-4-carboxylate, $C_{14}H_{18}N{6}O_{7}S,$ M.W. =414.39, CAS No. 93697-74-6], is one of well known rice herbicide belong in the sulfonyl urea group. To clarify the genotoxicity of this agrochemical, Ames bacterial reversion assay, in vitro chromosomal aberration assay with Chinese hamster lung (CHL) fibroblast and bone marrow micronucleus assay in mice were subjected. In Ames assay, although pyrazosulfuron-ethyl revealed cytotoxic at 5,000-140 $\mug/plate$ in Salmonella typhimurium TA100, no dose-dependent mutagenic potential in 4.4～70 $\mug/plate$ of S. typhimurium TA 98, TA 100, TA1535 and TA 1537 both in the absence and presence of S-9 metabolic activation system was observed. Using CHL fibroblasts, the 50% cell growth inhibition concentration $(IC_{50})$ of pyrazosulfuron-ethyl was determined as 1,243 $\mug/mL,$ and no chromosomal aberration was observed both in the absence and presence of S-9 mixture in the concentration range of 311-1,243 $\mug/mL.$ And also, in vivo micronucleus assay using mouse bone marrow, pyrazosulfuron-ethyl revealed no remarkable induction of MNPCE (micronucleated polychromatic erythrocytes/1000 polychromatic erythrocytes) in the dose range of 625-2,500 mg/kg body weight when administered orally. Consequently, Ames bacterial gene mutation with Salmonella typhimurium, in vitro chromosome aberration with mammalian cells and in vivo bone marrow micronucleus assay revealed no clastogenic potential of pyrazosulfuron-ethyl in this study.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.9 no.6
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• pp.617-623
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• 2016

Recently, IoT technology has been applied to the control of appliances in the home, and information about temperature, humidity, etc. is collected and the application of the system to control the indoor environment automatically is increasing. Currently, the network configuration of IoT devices is mainly used to connect IoT devices to the Internet through wireless gateways. Since such a method is dependent on a gateway, there are limitations in providing various services. Therefore, this paper proposes an independent method of gateway by using IoT network without using gateway by applying long distance wireless communication technology. IoT devices using the proposed long distance wireless internet technology can connect to a remote server and provide mobility that can not be supported by existing methods, thereby providing more various services. The performance evaluation of the proposed network configuration method is compared with the delay time and the amount of data generated in the existing network method constituted by the gateway and the proposed network configuration method respectively. Experimental results show that the proposed method decreases the delay time and the amount of data generated by the gateway.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.04a
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• pp.55-56
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• 2006

This thesis describes the use of measured aerosol size distributions and size-resolved hygroscopic growth to examine the physical and chemical properties of several particle classes. The primary objective of this work was to investigate the optical and cloud forming properties of a range of ambient aerosol types measured in a number of different locations. The tool used for most of these analyses is a differential mobility analyzer / tandem differential mobility analyzer (DMA / TDMA) system developed in our research group. To collect the data described in two of the chapters of this thesis, an aircraft-based version of the DMA / TDMA was deployed to Japan and California. The data described in two other chapters were conveniently collected during a period when the aerosol of interest came to us. The unique aspect of this analysis is the use of these data to isolate the size distributions of distinct aerosol types in order to quantify their optical and cloud forming properties. I used collected data during the Asian Aerosol Characterization Experiment (ACE-Asia) to examine the composition and homogeneity of a complex aerosol generated in the deserts and urban regions of China and other Asian countries. An aircraft-based tandem differential mobility analyzer was used for the first time during this campaign to examine the size-resolved hygroscopic properties of particles having diameters between 40 and 586 nm. Asian Dust Above Monterey (ADAM-2003) study was designed both to evaluate the degree to which models can predict the long-range transport of Asian dust, and to examine the physical and optical properties of that aged dust upon reaching the California coast. Aerosol size distributions and hygroscopic growth are measured in College Station, TX to investigate the cloud nucleating and optical properties of a biomass burning aerosol generated from fires on the Yucatan Peninsula. Measured aerosol size distributions and size-resolved hygroscopicity and volatility were used to infer critical supersaturation distributions of the distinct particle types that were observed during this period. The predicted CCN concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction coefficients are calculated at a wavelength of 550 nm.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.6_3
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• pp.1289-1295
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• 2023

Polyurethane foam insulation required for storing and transporting cryogenic liquefied gas is already widely used as a thermal insulation material for commercial LNG carriers and onshore due to its stable price and high insulation performance. These polyurethane foams are reported to have different mechanical performance depending on the density, and the density parameter is determined depending on the amount of the blowing agent. In this study, density-dependent polyurethane foam was fabricated by adjusting the amount of blowing agent. The mechanical properties of polyurethane foam were analyzed in the room temperature and cryogenic temperature range of -163℃ at 1.5 mm/min, which is a quasi-static load range, and the cells were observed through microstructure analysis. The characteristics of linear elasticity, plateau, and densification, which are quasi-static mechanical behaviors of polyurethane foam, were shown, and the correlation between density and mechanical properties in a cryogenic environment was confirmed. The correlation between mechanical behavior and cell size was also analyzed through SEM morphology analysis. Polyurethane foam with a density of 180 kg/m³ had a density about twice as high as that of a polyurethane foam with a density of 96 kg/m³, but yield strength was about 51% higher and cell size was about 9.5% smaller.

• Asian Journal of Atmospheric Environment
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• v.11 no.2
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• pp.71-78
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• 2017

Monthly characteristics of rainwater chemistry at a coastal site in southwestern Japan were examined based on an eight year record. In the period November-May when rain was mainly caused by cyclones, the monthly mean concentrations of $nss-{SO_4}^{2-}$, ${NO_3}^-$, ${NH_4}^+$, $nss-Ca^{2+}$, $Na^+$ and $Cl^-$ over the eight years were 25.1-57.8, 9.9-25.0, 11.3-31.4, 5.5-18.7, 24.2-154.9 and $30.0-178.5{\mu}eq\;L^{-1}$, respectively. In June and July when rain was mainly caused by stationary fronts, i.e. Meiyu fronts, the concentrations were 14.4-20.7, 7.2-9.5, 7.7-12.9, 4.1-6.8, 21.7-33.6 and $26.4-40.5{\mu}eq\;L^{-1}$, respectively. In August and September when typhoons contributed substantial rainfall, the respective concentrations of $Na^+$ and $Cl^-$ were as high as 97.7-105.3 and $116.8-122.9{\mu}eq\;L^{-1}$, while the concentrations of other ions were low. These results indicate a large variation of monthly rainwater chemistry, which is basically dependent on the synoptic weather patterns causing rain. From later autumn to early spring, rain contains ions in high concentration and large variation ranges. In the Meiyu season, rain contains less ions which vary in a range much smaller than that in later autumnearly spring. In summer and autumn, the concentrations are low, except $Na^+$ and $Cl^-$ which can be large due to typhoons' contribution.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.2
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• pp.113-126
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• 2002

This study was carried out to evaluate the temporal (daily, weekly, and seasonal) variations of volatile organic compounds (VOCs) concentrations at a road-side site in a heavy-traffic central area of Metropolitan Taegu. Ambient air sampling was undertaken continuously for 14 consecutive days in each of four seasons from the spring of 1999 to the winter of 2000. The VOC samples were collected using adsorbent tubes, and were determined by thermal desorption coupled with GC/MS analysis. A total of 10 aromatic VOCs of environmental concern were determined, including benzene, toluene, ethylbenzene, m＋p-xylenes, styrene, o-xylene, 1,3,5-trimethylbenzene, 1,2,4-trimethylbenzene, and naphthalene. Among 10 target VOCs, the most abundant compounds appeared to be toluene (1.5 ∼ 102 ppb) and xylenes (0.1 ∼ 114 ppb), while benzene levels were in the range of 0.3 ∼6 ppb. It was found that the general trends of VOC levels were significantly dependent on traffic conditions at the sampling site since VOC concentrations were at their maximum during rush hours (AM 7∼9 and PM 7 ∼9). However, some VOCs such as toluene, xylenes, and ethylbenzene were likely to be affected by a number of unknown sources other than vehicle exhaust, being attributed to the use of paints, and/or the evaporation of solvents used nearby the sampling site. In some instances, extremely high concentrations were found for these compounds, which can not be explained solely by the impact of vehicle exhaust. The results of this study may be useful for estimating the relative importance of different emission sources in large urban areas. Finally, it was suggested that the median value might be more desirable than the arithmetic mean as a representative value for the VOC data group, since the cumulative probability distribution (n=658) does not follow the normal distribution pattern.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.6
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• pp.621-628
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• 2013

It is already recognized, the fleet crew of Korean Coast Guard(KCG) have come to perform a wide range of roles that they carry on duties on inferior working conditions. Therefore a research on leadership is seemed necessary to improve organizational effectiveness for them. This study is to examine whether leadership style with transformation is appropriate in organizational commitment for the fleet crew of KCG. In this study transformational leadership is fixed as independent variables and organizational commitment as dependent variables and also five factors as demographic characteristics. Intellectual stimulation is turned out to be the most influential factor in organizational objective(t=6.664, p=0.000) and continuance commitment(t=4.057, p=0.000), but individualized consideration are uninfluential factors concerning organizational commitment.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.5
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• pp.534-544
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• 2011

The secondary aerosol forming potential of ambient air was first measured with the Potential Aerosol Mass(PAM) chamber at Gosan supersite on Jeju island from October 22 to November 5, 2010. PAM chamber is a small flowthrough photo-oxidation chamber with extremely high OH and $O_3$ levels. The OH exposure in the PAM chamber was $(2{\pm}0.4){\times}10^{11}{\sim}(6{\pm}1.2){\times}10^{11}$ molecules $cm^{-3}$ s and was similar to 2 to 5 days of aging in the atmosphere. By periodically turning on and off UV lamps in the PAM chamber, ambient aerosol and newly formed aerosol (e.g. called as PAM aerosol) was alternately measured. Aerosol number and mass concentration in the range of 10~487 nm in diameter was measured by SMPS 3034. With UV lamps on, the nucleation mode particles smaller than 50 nm in diameters were formed. Their number concentration was greater than 105 $cm^{-3}$, leading to increase in aerosol mass by 0~8 ${\mu}gm^{-3}$. The variations of PAM and ambient aerosols were greatly dependent on characteristics of air masses such as precursor concentrations and degree of aging. This preliminary results suggests that PAM chamber is useful to assess the aerosol formation potential of air mass and its impact on the air quality. The further analysis of data with gaseous and particulate measurements will be done.

• Journal of Korean Society on Water Environment
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• v.25 no.5
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• pp.713-719
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• 2009

A natural wetland in the Nakdong River basin which effectively removes non-point source pollutants was investigated for 2 years to understand wetland topography, vegetation types, and water quality characteristics. The water depth of the natural wetland was in the range of 0.5~1.9 m which is suitable for the growth of non-emergent hydrophytes. The wetland has a high length to width ratio (3.3:1) and a relatively large wetland to watershed area ratio (0.057). A broad-crested weir at the outlet increases the retention time of the wetland whose hydrology is mainly dependent on storm events. The concentrations of dissolved oxygen in the growing season and the winter season showed anoxic and oxic conditions, respectively. Diurnal variations of DO and pH in the growing season were also observed due to weather change and submerged plants. COD and TP concentrations were low in the winter season due to low inflow rate and increased retention time. Increased TP concentrations in the spring season were caused by degradation of dead wetland plants. Nitrogen in the wetland was mostly in organic nitrogen form (>75%). During the growing season, ammonium concentration was high but nitrate nitrogen concentration was low, possibly due to anoxic and low pH conditions which are adverse conditions for ammonificaiton and nitrification. The results of this study can be used as preliminary data for design, operation, monitoring and management of a constructed wetland which is designed to treat diffuse pollutants in the Nakdong river watershed.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.1
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• pp.23-30
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• 2013

The fleet crew of Korea Coast Guard(KCG) have a wide range of roles to perform. It is already recognized that they carry dutie in inferior working conditions. Therefore, a research on leadership that concerns organizational effectiveness seemed necessary for them. This study examines whether transformational leadership style is appropriate in job satisfaction for the fleet crew of KCG. This study also proves the effect of a leadership style on job satisfaction by suggesting a hypothesis from preceding studies. In this study transformational leadership is fixed as independent variables and job satisfaction as dependent variables and six factors as demographic characteristics. It is found that Intellectual stimulation is the most influential factor, but individualized consideration is an uninfluential factor concerning job satisfaction.