• Title/Summary/Keyword: Radicals

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ON JACOBSON AND NIL RADICALS RELATED TO POLYNOMIAL RINGS

  • Kwak, Tai Keun;Lee, Yang;Ozcan, A. Cigdem
    • Journal of the Korean Mathematical Society
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    • v.53 no.2
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    • pp.415-431
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    • 2016
  • This note is concerned with examining nilradicals and Jacobson radicals of polynomial rings when related factor rings are Armendariz. Especially we elaborate upon a well-known structural property of Armendariz rings, bringing into focus the Armendariz property of factor rings by Jacobson radicals. We show that J(R[x]) = J(R)[x] if and only if J(R) is nil when a given ring R is Armendariz, where J(A) means the Jacobson radical of a ring A. A ring will be called feckly Armendariz if the factor ring by the Jacobson radical is an Armendariz ring. It is shown that the polynomial ring over an Armendariz ring is feckly Armendariz, in spite of Armendariz rings being not feckly Armendariz in general. It is also shown that the feckly Armendariz property does not go up to polynomial rings.

Tocopherols and Tocotrienols in Cereal Grains (화곡류 종실의 토코페롤과 토코트리에놀 연구현황과 전망)

  • 이동진;이지영
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48
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    • pp.1-12
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    • 2003
  • Vitamin E is a fat-soluble vitamin that exists in eight different forms, which are $\alpha$, $\beta$, $\gamma$, and $\delta$ tocopherol, and $\alpha$, $\beta$, $\gamma$, and $\delta$ tocotrienol. Tocopherols and tocotrienols are important antioxidant in foods, feeds and their raw materials, where they scavenge lipid radicals. Each form has its own biological activity, the measure of potency or functional use in the body. Antioxidants such as vitamin E act to protect cells against the effects of free radicals, which are potentially damaging by-products of the body's metabolism. Free radicals can cause cell dam-age that may contribute to the development of cardiovascular disease and cancer, The content of tocopherols and tocotrienols vary depending on the environmental condition such as growing regions, temperature, crops and varieties. This report deals with chemical and physical properties and extends to their nutritional and health effect on the tocopherols and tocotrienols in cereal grains.

Protective Effects of a Ginseng Component, Malto1(2-Mlethyl-3-Hydrox)-4-Pyrone) against Tissue Damages Induced By Oxygen Radicals (활성산소에 의한 조직손상에 미치는 인삼성분의 보호효과)

  • Jae-Gook Shin;Jon
    • Journal of Ginseng Research
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    • v.14 no.2
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    • pp.187-190
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    • 1990
  • Maltol(2-methyl-3-hydroxy-r-pyrone), a component known to be present in Korean Ginseng root showed an antioxidant action but its potency as an antioxidant was low: about 1150th that of other antioxidants such as pphenylenediamine, BHA and BHT. However, maltol was able to protect the oxidation damages in biological systems such as adriamycin-induced membrane damage in isolated cardiomyocytes, paraquat-induced toxicities in isolated hepatocytes and reperfusion injury in isolated hearts. The antioxidant action of maltol was also shown to be effective in vivo. The antioxidant action of this compound was probably due to the removal of hydroxyl radicals. In view of the roles of oxygen radical in various pathological proceises, Korean Ginseng root which contains several antioxidants including maltol is expected to have beneficial effects on the oxygen radical-involved processes.

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Oxidation of Soot Particles with O Radicals Generated in a AC Streamer Corona Discharge (AC 스트리머 코로나 방전으로 생성된 O 라디칼과 매연 입자의 산화반응)

  • Kim, Pil-Seung;Lee, Kyo-Seung;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.8 no.1
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    • pp.9-16
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    • 2003
  • Carbon soot emission from combustion processes, especially from diesel engines, is a subject of growing concern since soot is known to seriously affect human health. Efforts have been made to oxidize soot particles utilizing Non-Thermal Plasma(NTP) techniques. When oxygen is carried into a plasma device, electrons generated by the plasma dissociate the oxygen, resulting in the formation of oxygen atoms. These highly activated atoms, called O radicals, are known as strong oxidizing agent. This paper presents concentration variations of CO and $CO_2$ at the exit of the plasma device, resulting from the soot oxidation by O radicals, with variations of inlet oxygen concentration, gas temperature, and gas flow rate. Based on the data, Arrehenious rate constants of reactions between C(s)+O and C(s)+O+O were proposed.

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A Study on the Combustion Characteristics of Lean Mixture by Radicals Induced Injection in a Constant Volume Combustor (2) (정적연소기에서 라디칼 유도분사를 이용한 희박혼합기의 연소특성에 관한 연구 (2))

  • 박종상;강병무;이명준;하종률;정성식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.19-26
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    • 2004
  • A prior fundamental study was executed using a constant volume chamber to improve the burning properties of lean pre-mixture by the injection of active radicals generated in the sub-chamber. In consequence, RI method shows remarkable progress in the aspects of burning velocity and combustible lean limit compared with SI method. In this study, the necessary additional works have been performed to be based on the former results. We changed parameters as the initial temperature and the initial pressure of mixture. And the effects of residual gas at issue in a real engine were investigated. As a result, the effects of initial temperature were significant, but on the other hand, those of initial pressure were slight. The correlation of passage hole number between overall passage hole area was grasped. And the more detailed analysis is required on residual gas.

An Experimental Study on the Measurement of Radicals in Flame for Real Time Combustion Control (실시간 연소제어를 위한 화염 내 라디칼 계측기법 연구)

  • Shin, Myung-Chul;Kim, Se-Won;Yu, Tae-U;Kwon, Seung-Jin
    • Journal of the Korean Society of Combustion
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    • v.11 no.3
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    • pp.18-25
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    • 2006
  • The present studying is aimed to establish the relationship between flame chemiluminescence$(OH^*,\;CH^*,\;C_2^*)$ intensities and combustion conditions such as $NO_x$ emission characteristics. Measurements are made for $OH^*,\;CH^*,\;C_2^*$ radicals in gas & light oil diffusion flames. At turbulent nonpremixed combustion mode, the equivalence ratio is varied. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The experimental results showed that the ratio of radicals and $NO_x$ emission characteristics have exponential correlations and equivalence ratio characteristics have linear correlations at this experimental conditions.

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Free radical scavenging phenolic compounds of the leaves of Juglans sinensis

  • Kim, Mi-Hee;Ko, Eun-Kyung;Jun, Jung-Yang;Li-Xun;Oh, Myung-Hun;An, Nyeon-Hyoung;Kim, Youn-Chul
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.381.3-382
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    • 2002
  • Free radical-mediated cell damage and free radical attack on polyunsaturated fatty acids result in the formation of lipid radicals. These lipid radicals react readily with molecular oxygen to produce peroxy radicals responsible for initiating lipid peroxidation. The peroxidation of cellular membrane lipid can lead to cell necrosis and considered to be implicated in a number of pathophysiological conditions as well as in the toxicity of many xenobiotics. DPPH is known to abstract labile hydrogen and the ability to scavenge the DPPH radical is related to the inhibition of lipid peroxidation. (omitted)

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Spectroscopic Identification of Isomeric 2,3- and 2,6-Dimethylbenzyl Radicals in Corona Discharge

  • Yoon, Young Wook;Lee, Sang Kuk
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.763-767
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    • 2013
  • We resolved the controversial assignments of the visible vibronic bands observed from corona discharge of 1,2,3-trimethylbenzene. The vibronic bands belonging to the jet-cooled 2,6-dimethylbenzyl radical were clearly identified from the spectrum observed from corona discharge of 2,6-dimethylbenzyl chloride. After subtracting the bands of the 2,6-isomer from the spectrum observed from corona discharge of 1,2,3-trimethylbenzene, the vibronic bands of the 2,3-isomer were also identified. By comparing data with the known vibrational data of 1,2,3-trimethylbenzene and the results of ab initio calculations, we determined the electronic energies of the $D_1{\rightarrow}D_0$ transitions and vibrational mode frequencies in the ground electronic states of the 2,3-and 2,6-dimethylbenzyl radicals.

Neuronal Cytotoxicity of Oxygen Radical in Newborn Mouse Forebrain Culture

  • Lim, Kye-Taek;Park, Seung-Taeck;Choi, Min-Kyu;Chung, Yeun-Tai
    • Toxicological Research
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    • v.11 no.2
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    • pp.187-192
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    • 1995
  • The cytotoxic effects of hydrogen peroxide and neuroprotective effects of a variety of agents were investigated in newborn mouse forebrain tissue culture. In our experiments, oxygen radical was generated enzymatically by glucose oxidase and the values were expressed as a percentage of number of living cells by 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) assay. Cytotoxicity of oxygen radicals was prevented by catalase and (N, N, N', N', -tetrakis (2-pyridylmethyl) ethylenediamine (TPEN), but N-tetra-ot-butyl-phenylnitrone (PBN), and deferoxamine (DFX), failed to show protective effects against oxygen radicals. Antagonists of the N-methyl-D-aspartate (NMDA) receptor, D-2-amino-5-phosphonovaleric acid (APV), 7-chlorokynurenic acid (CKA), and MK801 (a non-competitive NMDA antagonist) were also not effective in blocking neurotoxicity induced by glucose oxidase generated oxygen radicals.

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Antioxidant effect of myricetin with other antioxidants, taurine and $\beta$-carotene on mouse melanoma cell

  • Yu, Ji-Sun;Kim, An-Keun
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2003.11a
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    • pp.69-69
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    • 2003
  • There are now increasing evidences that free radicals and reactive oxygen species are involved in a variety of pathological events. Reactive Oxygen Species (ROS) are produced during normal cellular function. ROS lead to lipid peroxidation, massive protein oxdiation and degradation. Under normal conditions, antioxidant are substnaces that either directly or indirectly protect cell against adverse effect of ROS. several biologically important compound include ${\beta}$-carotene, taruine and flavonoids reported have antioxidant function. The various antioxidant either scavange superoxide and free radicals or stimulate the detoxification mechanisms within cells resulting in increased detoxification of free radicals formation and thus in prevention of many pathophysiologic processes. This study carried out to investigate the antioxidant activity of flavonoids, myricetin with other antioxidants, ${\beta}$-carotene and taurine on B16Fl0. In order to investigate the efficacy of antioxidant activity, we measured cell viability, antioxidant enzyme activity (SOD, GPX, CAT) and intracellular reactive oxygen intermediate (ROI). In this results, we show that these flavonoids with other antioxidant substrates are increased antioxidant activity level.

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