• Title/Summary/Keyword: Radical composition

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Combustion Characteristics of Model Gas Turbine Combustor -Radical Luminous Intensity and Local Equivalence Ratio Measurement- (모형 가스터빈 연소기의 연소특성 -라디칼 자발광강도와 국소당량비계측에 대하여-)

  • 최병륜;김태한
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.4
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    • pp.1064-1071
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    • 1994
  • There are three active radicals which become to the scale of flame diagnostics at the flame front. They are OH, CH and $C_2$ radical. For this, optical measurement system which could monitor simultaneously the luminous waves of three radicals, was constructed. These were analyzed statistically into the cross correlation, coherence and phase. Through such an statistical treatment, combustion characteristics was investigated at the primary zone of gas turbine combustor. The local equivalence ratio was predicted with the ratio of luminuous intensity between CH and $C_2$ radical. This result was matched up to the equivalence ratio calculated from gas composition within 5% error. In general, equivalence ratio was said to be 1.0 at flame front, but it could be increased up to about 1.2 depending on the degree of swirl intensity in case of changing properly the air amount of primary zone.

Anti-aging Effect on Skin with 9 Repetitive Steaming and Fermenting Process Herbal Composition Extract (구증구포(九蒸九炮) 발효(醱酵) 한약(韓藥) 혼합물(混合物)이 피부(皮膚) 노화(老化)에 미치는 영향(影響))

  • Choi, Jae-Hwan;Hwang, Seung-Jin;Jeong, Su-Na;Lee, Yun-Kyung;Jin, Mu-Hyun;Park, Sun-Gyoo;Lee, Cheon-Koo
    • The Korea Journal of Herbology
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    • v.24 no.4
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    • pp.101-106
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    • 2009
  • Objectives : We investigated the anti-aging effects on skin with 9 Repetitive steaming and fermenting herbal composition extract (FHE). Methods : Herbal composition is comprised of Panax Ginseng, Rehmannia glutinosa, Polygonum multiflorum and Polygonatum Sibiricum. They steamed and fermented with Saccharomyces cerevisiae and Lactobacillus brevis by turns at 9 times. We measured various effects related to skin aging such as scavenging activity against free radical, cell proliferation, collagen synthesis and toxicity of 9 repetitive steaming and fermenting herbal composition extract were evaluated and compared with herbal composition extract (HE). Results : As the number of steaming and fermenting cycle increased free-radical scavenging activity were increased. But cell proliferating ratio was not increased when the number of steaming and fermenting cycle. The FHE could significantly increase the collagen synthetic ratio compared with HE treated group. And, FHE was showed no toxicity at all tested concentrations. Conclusions : The results of our study propose that FHE has good anti-aging effects on skin.

In Vitro Evaluation for Antioxidant Activities of Culture Broth of Tremella fuciformis (흰목이 버섯 배양액의 항산화 활성 규명)

  • Ra, Kyung-Soo;Choi, Jang-Won
    • KSBB Journal
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    • v.25 no.1
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    • pp.55-61
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    • 2010
  • To investigate antioxidant activity of the culture broth from submerged culture of Tremella fuciformis, we preferentially analyzed the chemical composition of culture broth, which was mainly composed of carbohydrate (296.39 mg/g) and protein (9.24 mg/g), respectively. Also, contents of polyphenols, flavonoids and flavonols were 16.63 mg/g, 9.19 mg/g and 83.74 ${\mu}/g$, respectively. Next, we examined the scavenging abilities on DPPH (1,1-diphenyl-2-picrylhydrazyl) radical, ABTS (2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid) radical, the reducing power, and chelating ability on ferrous ions. All antioxidant activities of the culture broth were increased in proportion to its concentrations. The $IC_{50}$ values were in order as follows ABTS radical scavenging activity < OPPH radical scavenging activity < chelating power. Accordingly, these results suggest that pharmacological function of T. fuciformis might be due to, at least partially, their protective effects against oxidation and the culture broth of T. fuciformis was free radical inhibitors or scavengers at low concentration, involving possibly in termination of free radical reaction as primary antioxidants.

Radical Scavenging Activity of Sea Buckthorn Oils from Different Parts of Sea Buckthorn Berry

  • Xu, Xiang;Gao, Yanxiang
    • Food Science and Biotechnology
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    • v.18 no.2
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    • pp.312-316
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    • 2009
  • Antioxidant-rich oils were extracted from different parts of sea buckthorn berry with supercritical $CO_2$ (SC-$CO_2$) and n-hexane. The functional components were analyzed and the extracts were screened for their potential as radical scavengers in 1,1-diphenyl-2-picrylhydrazyl radical (DPPH), 2,2'-azinobis-3-ethylbenzotiazoline-6-sulphonic acid (ABTS), galvinoxyl systems. Minor differences were found in fatty acid composition of oils extracted by the two methods. Seed oil contains the highest content of tocopherols while pulp oil and whole berry oil possessed higher concentration of carotenoids. Whole berry oil, pulp oil, and seed oil extracted by SC-$CO_2$ showed 91.7, 90.9, and 93.5% radical scavenging activity (RSA) at 6 mg/mL towards DPPH and 74.3, 54.3, and 74.8% towards galvanoxyl radical at 10 mg/mL. The hexane-extracted oils showed similar scavenging ability. However, the oils obtained by hexane showed significantly higher RSA (p<0.05) than those obtained by SC-$CO_2$ while whole berry oil has the highest RSA towards ABTS among 3 oil samples.

Polyphenol Contents of Rumex crispus Root Extract with Hot Water and its Antioxidative Effect (소리쟁이 뿌리 열수 추출물의 폴리페놀 함량 및 추출물의 항산화 효과)

  • Yun, Young-Sim;Jeong, Kap-Seop
    • Journal of Environmental Science International
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    • v.21 no.10
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    • pp.1265-1274
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    • 2012
  • This study was conducted to investigate the extraction characteristics including total polyphenol compound content (TPC) and the antioxidative effect of Rumex crispus root extract on commercial corn oil. Extraction yield was increased with extraction temperature but decreased with extraction ratio. No significant differences in aromatics content were found among the extracts prepared with various extraction conditions; extraction ratio, extraction temperature, extraction pH and composition of extractant. Total flavonoid content of the extract was increased with extraction temperature and extraction pH, and highest value of it was found when extractant composition of ethanol in water was 75%. Total polyphenol compound content (TPC) of the extract with 10 fold extraction ratio showed the highest value, but no significant difference in TPC was found with extraction temperature. Reducing power and DPPH (${\alpha}$,${\alpha}$-diphenyl-${\beta}$-picrylhydrazyl) radical scavenging ability (RSA) of the extract in spectrophotometric absorbance were decreased with extraction ratio but increased with extraction temperature and showed 63.1%~98.4% and 67.6%~86.7% of those of ascorbic acid in reducing power and DPPH RSA, respectively. The antioxidative effects of the extract on corn oil were 84.8~93.0% of that of commercial butylated hydroxytoluene, the antioxidant index value was highest when the ethanol composition to water in extractant was equal ratio.

Effect of Polymerization Condition on Atom Transfer Radical Copolymerization Behaviors of Styrene with Methyl Acrylate (스티렌과 메틸아크릴레이트의 원자 이동 라디칼 공중합에서 중합조건에 따른 중합 특성 연구)

  • Song, Seon-Ja;Ko, Young Soo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.676-680
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    • 2011
  • Investigated was the effect of the crucial polymerization conditions such as methyl acrylate(MA) mole fraction in feed, polymerization temperature and time on Atom Radical Transfer Polymerization(ATRP) behavior of styrene and methyl acrylate(MA). As MA mole fraction in feed increased, molecular weight(MW) of the resulting copolymer increased. At polymerization time of 3 hrs the composition of MA in the resulting copolymer was shown to have a linear relationship with the mole fraction of MA in feed. MW was increased and the composition of MA in copolymer was decreased as the polymerization time increased, showing the characteristics of ATRP. MW was also increased as polymerization temperature increased, and the composition of MA in copolymer was shown to be increased drastically at polymerization temperature of $110^{\circ}C$.

Analysis of Chemical Composition and Antioxidant Activity of Suaeda japonica (칠면초의 성분 분석 및 추출물의 항산화 효과)

  • Lee, Kyung-Seok;Kim, Ae-Jung;Lee, Ki-Young
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.4
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    • pp.521-526
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    • 2012
  • This study was conducted in order to analyze the ingredients and antioxidant activity of Suaeda japonica (turkey), which is abundantly present in Korea where mud flats are well formed due to the characteristics of halophytes. In the analysis of general composition, contents of carbohydrates, proteins, ash, and moisture were 10.7%, 8.3%, 7.6%, and 72.5% respectively. Among minerals, sodium was measured as 5.4%, which means that most ash was made of sodium. Heavy metal contents of lead, cadmium, arsenic, and mercury were 0.86 ppm, 0.04 ppm, 0.39 ppm, and 0.01 ppm, meaning Suaeda japonica satisfied standard food values. The 70% ethanol extract from Suaeda japonica was evaluated for its free radical scavenging activity and compared with a commercial antioxidant, BHA (butylated hydroxyanisole). As a result, the scavenging activities of hydroxyl radical, hydrogen peroxide, and xanthine oxidase of the extracts were equivalent to 30~50% of that of BHA.

Chemical Composition and Antioxidative Activities of Platycodon grandiflorum Leaves and Stems (도라지 잎과 줄기의 화학성분 및 항산화활성)

  • Jeong, Chang-Ho;Shim, Ki-Hwan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.5
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    • pp.511-515
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    • 2006
  • The chemical composition and antioxidative activities of Platycodon grandiflorum leaves and stems was investigated in order to evaluate the potential as functional food material. The moisture contents of leaves and stems were 84.31% and 75.91%, respectively. The Ca content was the highest in leaves (351.49 mg%) and stems (217.56 mg%). The major free sugar of leaves was glucose (1,729.87 mg%) However major free sugar of stems was fructose (734.91 mg%). Glutamic acid (242.91 mg%) and arginine (228.60 mg%) in leaves were major amino acids, lysine (110.08 mg%) and glutamic acid (80.40 mg%) in stems were major amino acids. Oleic acid and linoleic acid were major fatty acids in crude fat of both leaves and stems. DPPH free radical scavenging activities of fractions from leaves and stems were rising with increasing amount of fractions. Like antioxidant activity, the reducing power of fractions from leaves and stems was also dependent on concentration while butanol fraction of stems showed the highest reducing power.

Chemical Composition and Antioxidant Activities of Prunus salicina Formosa Produced in Gimcheon (김천산 자두 후무사의 화학적 성분과 항산화 활성)

  • Yoon, Ok-Hyun;Jeong, Bo-Young;Kim, Eun-Kyoung;Jeong, Yoon-Hwa
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.3
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    • pp.379-384
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    • 2011
  • The present study was designed to investigate the chemical composition and antioxidant activities of Prunus salicina Formosa produced in Gimcheon. The free sugar amounts in Prunus salicina Formosa were fructose>glucose>sucrose>maltose, and malic acid contents in Prunus salicina Formosa were the highest among all the organic acids found in the present study. Each Prunus salicina Formosa extract was obtained by treating Prunus salicina Formosa with distilled water, 80% ethanol, 60% acetone, and 80% methanol at 25 and $50^{\circ}C$. The highest contents of total polyphenol and flavonoid were observed in the 60% acetone extract and 80% ethanol extract, respectively. The 60% acetone extract exhibited the greatest DPPH radical scavenging ability, reducing power, and nitrite scavenging ability. However, SOD-like activity was not considerably different for all the extracts studied. The results from the present study could be helpful for developing antioxidant products using Prunus salicina Formosa produced in Gimcheon.

Optimization of Hydroxyl Radical Scavenging Activity of Exopolysaccharides from Inonotus obliquus in Submerged Fermentation Using Response Surface Methodology

  • Chen, Hui;Xu, Xiangqun;Zhu, Yang
    • Journal of Microbiology and Biotechnology
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    • v.20 no.4
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    • pp.835-843
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    • 2010
  • The objectives of this study were to investigate the effect of fermentation medium on the hydroxyl radical scavenging activity of exopolysaccharides from Inonotus obliquus by response surface methodology (RSM). A two-level fractional factorial design was used to evaluate the effect of different components of the medium. Corn flour, peptone, and $KH_2PO_4$ were important factors significantly affecting hydroxyl radical scavenging activity. These selected variables were subsequently optimized using path of steepest ascent (descent), a central composite design, and response surface analysis. The optimal medium composition was (% w/v): corn flour 5.30, peptone 0.32, $KH_2PO_4$ 0.26, $MgSO_4$ 0.02, and $CaCl_2$ 0.01. Under the optimal condition, the hydroxyl radical scavenging rate (49.4%) was much higher than that using either basal fermentation medium (10.2%) and single variable optimization of fermentation medium (35.5%). The main monosaccharides components of the RSM optimized polysaccharides are rhamnose, arabinose, xylose, mannose, glucose, and galactose with molar proportion at 1.45%, 3.63%, 2.17%, 15.94%, 50.00%, and 26.81%.