• Title/Summary/Keyword: Radical composition

Search Result 433, Processing Time 0.019 seconds

Review : The Advanced Inkjet Printing Technology - UV curable Jet Ink - (총설 : 최신 잉크제트 인쇄기술 - UV 경화형 제트잉크 -)

  • Jeong, Kyoung Mo;Won, Jong Myung;Lee, Yong Kyu;Koseki, Ken'ichi
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.46 no.2
    • /
    • pp.46-56
    • /
    • 2014
  • The aim of this reviews is to introduce the information concerning design of the UV-curable jet ink composition in order to provide a good adhesive property on non-porous surface. In order to clarify the viscosity dependence of flying speed for the UV curable jet ink, rheological analysis and observation of the flying state of the ink were carried out. The relationship between ink formulas and adhesive property on non-porous surface was investigated. It was examined the adhesive property of radical polymerization type UV curable jet ink included hydrogen abstraction type photo-initiator, it was expected that the strong adhesive strength can be obtained between the ink and non-porous surface in this study. UV curable jet ink with a slight amount of water was prepared. Optimum ratio of the cationic polymerization type UV curable jet ink shows an adequate adhesive strength towards two kinds of non-porous surface such as glass, poly(vinyl chloride) when tests were conducted on the ink jet-printing test machine.

Composition Analysis and Antioxidative Activity of Maengjong-juk (Phyllostachys pubescence) Leaves Tea (맹종죽잎차의 성분 분석 및 항산화 활성)

  • In, Man-Jin;Park, Min-Kyung;Kim, So-Young;Chae, Hee-Jeong;Chae, Moon-Whoan;Sone, Jin;Ji, Ho-Seon;Han, Kwang-Sik;Kim, Dong-Chung
    • Journal of Applied Biological Chemistry
    • /
    • v.53 no.2
    • /
    • pp.116-119
    • /
    • 2010
  • A Maengjong-juk (Phyllostachys pubescence) leaves tea was prepared by using a series of drying/roasting and rolling processes. The produced tea contained abundant dietary fibers (60.42%), $\beta$-carotenes (7.9 mg RE%), and calcium (437.1 mg%). Also the polyphenol content ($155.33\;{\mu}g/g$-tea) and DPPH free radical scavenging activity ($IC_{50}=212\;{\mu}g/mL$) of Maengjong-juk leaves tea were greatly higher than those of simply dried leaves. These results imply that the tea preparation is effective to utilize the useful components of Maengjong-juk leaves.

Preparation of Al@Fe2O3 Core-Shell Composites Using Amphiphilic Graft Copolymer Template

  • Patel, Rajkumar;Kim, Sang Jin;Kim, Jin Kyu;Park, Jung Su;Kim, Jong Hak
    • Korean Chemical Engineering Research
    • /
    • v.52 no.2
    • /
    • pp.209-213
    • /
    • 2014
  • A graft copolymer of poly(vinyl chloride)-g-poly(oxyethylene methacrylate) (PVC-g-POEM) was synthesized via atom transfer radical polymerization (ATRP) and used as a structure-directing agent to prepare $Al@Fe_2O_3$ core-shell nanocomposites through a sol-gel process. The amphiphilic property of PVC-g-POEM allows for good dispersion of Al particles and leads to specific interaction with iron ethoxide, a precursor of $Fe_2O_3$. Secondary bonding interaction in the sol-gel composites was characterized by Fourier transform-infrared (FT-IR) spectroscopy. The well-organized morphology of $Al@Fe_2O_3$ core-shell nanocomposites was observed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Energy dispersive X-ray (EDX) and X-ray diffraction (XRD) were used to analyze the elemental composition and crystallization structure of the composites.

Antioxidant and Angiotensin I Converting Enzyme Inhibitory Activities of Red Snow Crab Chionoecetes japonicas Shell Hydrolysate by Enzymatic Hydrolysis

  • Yoon, Na Young;Shim, Kil-Bo;Lim, Chi-Won;Kim, Sang-Bo
    • Fisheries and Aquatic Sciences
    • /
    • v.16 no.4
    • /
    • pp.237-242
    • /
    • 2013
  • We investigated the antioxidant and angiotensin I converting enzyme (ACE) inhibitory activities of red snow crab Chionoecetes japonicas shell (RSCS) hydrolysate by enzymatic hydrolysis and its molecular weight cut-off fractions. The RSCS hydrolysate was fractionated through two ultrafiltration membranes of 3 and 10 kDa cut-offs. Three fractions (<3 kDa, 3-10 kDa, and >10 kDa) were evaluated for total amino acid composition, antioxidant activities using 2'-azino-bis[3-ethylbenzthiazoline-6-sulfonic acid] ($ABTS^+$) radical scavenging and superoxide dismutase (SOD)-like activities and reducing power assays, and ACE inhibitory activity using Hou's method. Although all fractions showed activity, the <3 kDa fraction of RSCS hydrolysate exhibited the greatest $ABTS^+$ radical scavenging, SOD-like and ACE inhibitory activities. However, these fractions exhibited low reducing power. These results suggest that the low-molecular-weight enzymatic hydrolysate of RSCS could be used as a functional ingredient to control oxidative stress and ACE activity.

Optimization of Muffin with Dropwort Powder Using Response Surface Methodology (반응표면분석법을 이용한 미나리 분말 첨가 머핀 제조 조건의 최적화)

  • Park, Geum-Soon;Kim, Ji-Young
    • Journal of the Korean Society of Food Culture
    • /
    • v.29 no.6
    • /
    • pp.623-636
    • /
    • 2014
  • This study was performed to determine the optimal composition of muffins added with dropwort powder, egg and sugar. The experiment was designed based on BBD (Box-behnken design), and evaluation was carried out by means of RSM (response surface methodology), consisting of 13 experimental points with three replicates each for three independent variables dropwort powder, eggs and sugar. Using F-test, height, moisture, 1,1-diphenyl-2picriylhydrazyl (DPPH) radical scavenging activity, L-value, a-value, springiness, cohesiveness, chewiness, brittleness, color, and appearance acceptability were expressed as a linear model, whereas pH, b-value, flavor, taste, and texture were expressed as a quadratic model. After swallow and overall acceptability were expressed as a 2FI model. As dropwort powder content increased, 1,1-diphenyl-2picriylhydrazyl (DPPH) radical scavenging activity increased. Increasing amounts of dropwort powder led to reduction of sensory scores for color, appearance, flavor, taste, and texture quality. The optimum formulation determined by the numerical and graphical methods were similar: dropwort powder 6 g, egg 77 g, and sugar 60 g.

Antioxidant Activities and Quality Characteristics Sulgidduk Prepared with Yangha Buds (Zingiber Miogar R) (양하꽃대의 항산화 활성 및 설기떡 제조)

  • Lee, Hyun-Ju;Woo, Naruyah;Kim, Ae-Jung
    • Journal of the Korean Society of Food Culture
    • /
    • v.29 no.6
    • /
    • pp.615-622
    • /
    • 2014
  • This study investigated the antioxidative properties of Yangha Buds (Zingiber Mioga R) and quality characteristics of Korean steamed-rice cake, Sulgidduk, prepared with Yangha Buds juice. Antioxidative activities were measured based on DPPH radical and ABTS radical scavenging activities, total phenol content, and total flavonoid content in Yangha Buds (water extract and juice). Sulgidduk was prepared by adding Yangha buds at concentrations of 0, 1, 2, 3, and 4% of juice. To analyze quality characteristics, proximate composition, color, texture profiles, and sensory evaluations were measured. As content of Yangha buds juice increased, L-value significantly decreased while a-value and b-value increased (p<0.05). For texture profiles, control group scored higher score for hardness as compared to groups added with Yangha buds juice. Springiness, chewiness, and adhesiveness were not significantly different among the groups. In the sensory evaluation, samples containing 3% Yangha buds juice showed better results for attitude. Based on these results, we suggest that Yangha buds are a good ingredient for increasing consumer acceptability and functionality of Sulgidduk.

Quality Characteristics and Antioxidant Activity of Cookies with Stevia Powder (스테비아 분말을 첨가한 쿠키의 품질특성과 항산화 활성)

  • Yoo, Seung-Seok;Hong, Yeo-Joo
    • Korean journal of food and cookery science
    • /
    • v.28 no.6
    • /
    • pp.665-673
    • /
    • 2012
  • The purpose of this study was to propose optimal mixing proportion by adding stevia in powder form, which are low caloric and high intensity sweetener to cookies, and to determine the characteristic of product. It reduced the average sugar content of cookies to 50%, processed stevia powder, add them in 2, 4, 6, and 8% to make cookies and measured various product characteristics, including anti-oxidant activity. The antioxidant activity was highly correlated with the total phenolic composition of stevia cookies (r=0.967). Total phenolic contents and DPPH free radical scavenging activity of cookies significantly increased with increasing stevia powder. The bulk density of the dough, spread factor and the hardness, total polyphenol contents and DPPH free radical scavenging activity of cookies significantly increased with increasing stevia powder, while the pH of the dough, and L values of the cookies decreased with increasing stevia powder content (p<0.001). Additionally, the consumer acceptability scores for the 4% stevia cookie groups ranked significantly (p<0.001) higher than those of the other groups in color, taste, flavor, sweetness and overall preference. All the take together, the results of this study suggest that stevia powder is a good ingredient for increasing the consumer acceptability and the functionality of cookies.

Humidity Sensor of Polymethacrylate with 4th Ammonium Salt (4차 암모늄 염을 포함하는 폴리메타크릴레이트 습도센서)

  • Hong, Chae-Hwan;Kim, Se-Hoon;Nam, Byeong-Uk
    • Polymer(Korea)
    • /
    • v.31 no.3
    • /
    • pp.255-262
    • /
    • 2007
  • In this work, two types of copolymers are manufactured by a radical polymerization to develop a material for humid membrane. Each copolymer contains three monomers that have functions to improve humid-resistance, membrane stability, flexibility, impedance, and adhesion to the electrode. MDBAB (N,N'-dimethyl-2-methacryloxyethyl-3-bromopropyl ammonium bromide) having a salt form decreases the impedance of the humid membrane and reacts with amines to produce a cross-linking structure. HEMA (2-hydroxyethyl methacrylate) has an important role which reduces the impedance and increases the adhesion strength to the electrode. The other monomers are DAEMA (N,N'-dimethylamino ethyl methacrylate), 4-VP(4-vinyl pyridine), and 2-EHA(2-ethylhexyl acrylate) and all the monomers are formulated with several compositions to make a humid membrane. At specific composition, we could attain a satisfactory results having good performance and long term durability.

Excimer Studies on Copolymer of Styrene-Acrylic Acid (스티렌-아크릴산 공중합체의 들뜬이합체 연구)

  • Lee, Yeon Hui;Gang, Seong Cheol;Kim, Gang Jin
    • Journal of the Korean Chemical Society
    • /
    • v.34 no.1
    • /
    • pp.91-97
    • /
    • 1990
  • Copolymers (PSAA) of styrene-acrylic acid were prepared through a free radical mechanism using azobisisobutyronitrile as an initiator. The fluorescence emission spectra of PSAA and the styrene-acrylic acid copolymers complexed with $Eu^{3+}$ (PSAA-Eu) were studied. The excimer fluorescence, centered at 330 nm, increases when the styrene mole fraction increases. Since the excimer fluorescence intensities of PSAA-EU, PSAA-Tb and PSAA-Eu-Tb were almost same, it appears that the kind of metal ion does not affect the excimer fluorescence. An interpretation of the results which takes into account the statistical composition of the copolymers, indicates that energy migration can occur from isolated to non-isolated styrene units.

  • PDF

Studies on the etching characteristics of PZT thin films using inductively coupled plasma (고밀도 플라즈마에 의한 PZT 박막의 식각특성 연구)

  • 안태현;김창일;장의구;서용진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.13 no.3
    • /
    • pp.188-192
    • /
    • 2000
  • In this study PZT etching was performed using planar inductively coupled Ar/Cl$_2$/BCI$_3$ plasma. The etch rate of PZT film was 2450 $\AA$/min at Ar(20)/BCl$_3$(80) gas mixing ratio and substrate temperature of 8$0^{\circ}C$. X-ray photoelectron spectroscopy(XPS) analysis for films composition of etched PZT surface was utilized. The chemical bond of PbO is broken by ion bombardment and Cl radical, and the peak of metal Pb in a Pb 4f narrow scan begins to appear upon etching. As increasing additive BCl$_3$content the relative content of oxygen decreases rapidly in contrast with etch rate of PZT thin film. So we though that the etch rate of PZT thin film increased because abundant B and BCl radicals made volatile oxy-compound such as B$_{x}$/O$_{y}$ and/or BClO$_{x}$ bond. We achieved etch profile of about 80$^{\circ}$ at Ar(20)/BCl$_3$(80) gas mixing condition and substrate temperature of 8$0^{\circ}C$TEX>X>.

  • PDF