• 제목/요약/키워드: Radiation degradation

검색결과 285건 처리시간 0.035초

전자스핀공명을 이용한 저밀도 폴리에틸렌의 방사선 열화 검지 (Detection of Radiation Degradation of LDPE by ESR Spectroscopy)

  • 김기엽;이청;류부형
    • 한국안전학회지
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    • 제20권1호
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    • pp.81-86
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    • 2005
  • This study has investigated radiation degradation of low density polyethylene(LDPE). Samples were irradiated up to 800kGy using a $Co^{60}\;\gamma-ray$ at a dose rate of 5kGy/hr in the presence of air atmosphere at room temperature. After irradiation, storing for 2 weeks, free radical measurement of LDPE has established by electron spin resonance(ESR). ESR measurement showed that free radical concentration(FRC) was increased with radiation dose and decreased with the time. The radical types showed alkyl, allyl, and peroxy radical with the irradiation, these changed to peroxy radical with the time.

PVDF의 내방사선 특성 향상을 위한 산화방지제 첨가효과 (The Effect on Antioxidant for Improving to Radiation Resistance on Irradiated PVDF)

  • 김기엽;이청;류부형;임기조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.252-253
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    • 2005
  • The dielectric relaxation properties of $^{60}Co$ gamma-ray irradiated Poly(vinylidene fluoride) (PVDF) containing various antioxidants have been investigated for radiation degradation. Cole-Cole's circular arcs were induced from the results of temperature and frequency dependency of dielectric properties with radiation dose. The magnitude of polarization of PVDF was decreased by adding antioxidants. The values of dielectric relaxation intensity calculated by using the Cole-Cole's circular arcs showed a certain tendency for radiation degradation.

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방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구 (Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation)

  • 이선영;송주명;손준용;신준화
    • 방사선산업학회지
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    • 제6권2호
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    • pp.171-176
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    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

감마선 조사에 의한 목재성질 변화에 관한 연구 (Study of the Changes in Wood Properties by Gamma Irradiation)

  • 윤민철;박병수;김익주;최종일
    • Journal of the Korean Wood Science and Technology
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    • 제40권4호
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    • pp.229-236
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    • 2012
  • 본 연구는 감마선 조사가 소나무(Pinus densiflrora), 느티나무(Zelkovas serrenata), 오동나무(Paulownia tomentosa)의 세포벽 열화, 셀룰로오스 결정화도, 휨 강도에 미치는 영향을 구명하기 위해 수행되었다. 각 목재 시편들을 100 kGy 선량의 감마선 조사 후 주사전자현미경(scanning electron microscope; SEM) 관찰 결과, 목재 세포벽 열화는 관찰되지 않았으며 휨 강도 역시 현저한 변화가 나타나지 않았다. 감마선 조사에 의한 셀룰로오스 결정화도 역시 유의한 변화가 관찰되지 않았다. 이러한 감마선에 대한 목재의 높은 안전성은 감마선 조사 기술을 재질손상 없이 목재를 가해 중인 균류와 충류 구제를 위해 적용할 수 있음을 의미한다.

TiO$_2$가 담지된 활성탄을 이용한 Methylene Blue의 광분해 (Photocatalytic Degradation of Methylene Blue using $TiO_2$ Supported on Activated Carbon)

  • 이종대;이태준;조경태
    • 한국응용과학기술학회지
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    • 제23권2호
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    • pp.153-159
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    • 2006
  • The photocatalytic degradation of methylene blue(MB) was investigated using $TiO_2$ as photocatalyst and UV radiation. $TiO_2$ supported with activated carbon(AC) was prepared by SOL-GEL method and depended on several parameters such as the mass ratio of $TiO_2/AC$, pH and experimental time. The presence of the anatase and rutile crystal phase was determined by XRD analyses of the prepared $TiO_2$. The degradation of MB with $TiO_2/AC$ was about 20% higher than that of AC alone. A variation of photodegradation was negligible under UV radiation conditions ( ${\geq}$ 40W). It was experimentally showed that the photodegradation rate was increased with increasing the amount of photocatalyst. The optimal catalyst was prepared by impregmation of $5wt%-TiO_2$ with AC and was calcined at $300^{\circ}C$, and showed about 99% removal efficiency for 3hrs.

EPR 케이블의 잔류전압에 미치는 방사선의 영향 (Effect of Radial Rays on Residual Voltage for EPR cable)

  • 이성일;류성림;김용추
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.518-521
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    • 1999
  • This paper describes the properties of discharge current and the residual voltage for $^{60}$ C$_{0}$ -${\gamma}$ irradiated cables using in nuclear power generating station. As these properties related with $^{60}$ C$_{0}$ -${\gamma}$ -irradiatiation dose, it is suggested that these properties can be utilized as a index of irradiation degradation. As the ratio of degradation increases, the residual voltage in the initial time range increases and the peak moves to the shorter time. Therefore, I know the degree of radiation degradation from the position of the peak.

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클로로프렌 고무의 난연성 및 내방사선 특성 향상 (The Improvements for Fire Retardancy and Radiation Resistance of Chloroprene Rubber)

  • 김기엽;이청;류부형
    • 한국전기전자재료학회논문지
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    • 제17권11호
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    • pp.1205-1211
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    • 2004
  • This study has investigated radiation degradation of chloroprene rubber in the presence of some fire retardant. Ammonium polyphosphate, aluminium trihydroxide, magnesium hydroxide, calcium carbonate and antimony trioxide were selected as flame retardant. Samples were irradiated using a Co$^{60}$ ${\gamma}$ -ray and ray up to 2000 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, samples were assessed fire retardancy with electrical properties and mechanical properties. Some considerations concerning the effects of the fire retardants added to chloroprene rubber on the radiation and thermal stability of chloroprene rubber are presented. From fire retardancy with electrical and mechanical property measurements, it was found that addition of magnesium hydroxide resulted in maximum fire retardant effect.

On the Degradation of a UWB System Due to a Realistic TX-RX Antenna System

  • Jun, Min-Sik;Oh, Tae-Won
    • ETRI Journal
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    • 제27권4호
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    • pp.453-456
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    • 2005
  • The ultra-wideband (UWB) signal radiation process in an antenna is different from that of a narrowband signal. In this paper, we study the degradation of the desired signal component according to the antenna structure and location of a receiver in a bipolar time-hopping UWB system. And we propose a receiver structure with an adaptive template waveform generator to compensate for the degradation caused by a realistic TX-RX antenna system.

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