• Elastomers and Composites
• /
• v.37 no.2
• /
• pp.99-106
• /
• 2002

In this work, the surface properties and mechanical interfacial properties of the carbon blacks treated by oxygen plasma were investigated. The surface properties of carbon black by oxidation process of oxygen plasma were studied in acid-base surface value, zeta potential, and X-ray photoelectron spectroscopy (XPS). And their mechanical interfacial properties of the carbon black/rubber composites were evaluated by the composite tearing energy ($G_{III}c$). As a result, it was found that the introduction rate of oxygen-containing polar functional groups, such as carboxyl, hydroxyl, lactone, and carbonyl groups, onto the carbon black surfaces was increased by increasing the plasma treatment time. It revealed that the polar rubber, such as acrylonitrile butadiene rubber (NBR), showed relatively a high degree of interaction with oxygen-containing functional groups of the carbon black surfaces, resulting in improving the tearing energy ($G_{III}c$) of the carbon black/acrlyonitrile butadiene rubber composites.

• Elastomers and Composites
• /
• v.44 no.1
• /
• pp.47-54
• /
• 2009

EPDM(Ethylene-propylene-diene-terpolymer) compound reinforced with carbon black having four different particle size, acetylene black(thermal conductivity carbon black), and silica were manufactured by internal mix and open mill. To investigate the effect of particle size of filler and filler type on far-infrared vulcanization, intermal temperature of compound, degree of curing, infrared spectroscopy, and thermal analysis were measured. The thermal conductivity of far-infrared vulcanized EPDM compound increased with increasing particle size of carbon filler, but hot air vulcanized EPDM compound is not affected by particle size. The thermal conductivity was increased in the order of carbon black < silica < acetylene black(thermal conductivity carbon black).

• Elastomers and Composites
• /
• v.53 no.3
• /
• pp.175-180
• /
• 2018

Solution-styrene-butadiene rubber (SSBR) composites were manufactured using four kinds of fillers: silica-silane coated carbon black (SC-CB) hybrid, starch-SC-CB hybrid, pure silica, and pure starch. The influence of filler type on the mechanical properties of the rubber matrix was studied in this work. SC-CB was prepared by silane-graft-coating using vinyl triethoxy silane and carbon black, which enhanced the dispersion effect between the rubber matrix and the filler, and improved the mechanical properties of the compounds. The morphology of the composites was observed by field-emission scanning electron microscopy (FE-SEM). The thermal decomposition behavior of the composites was determined by thermogravimetric analysis (TGA), and the crosslinking behavior of the composites was tested using a rubber process analyzer (RPA). The hardness, tensile strength, swelling ratio, and gas transmittance rate of the composites were evaluated according to ASTM. The test results revealed that with the addition of SC-CB, the hybrid fillers, especially those blended with silica, showed a better reinforcement effect, the highest hardness and tensile strength, and stable thermal decomposition behavior. This implies that the silica-SC-CB hybrid filler has a notable mechanical reinforcement effect on the SSBR matrix. Because of self-crosslinking during its synthesis, the starch-SC-CB hybrid filler produced the most dense matrix, which improved the anti-gas transmittance property. The composites with the hybrid fillers had better anti-swelling properties as compared to the neat SSBR composite, which was due to the hydrophilicity of silica and starch.

• Elastomers and Composites
• /
• v.40 no.1
• /
• pp.59-65
• /
• 2005

Zinc methacrylate(ZMA) was incorporated into ethylene-propylene diene rubber(EPDM) by direct mixing of the metal salt with the rubber or was in-situ prepared in the rubber matrix through neutralization reaction of zinc oxide(ZnO) and methacrylic acid(MAA). Tensile and tear tests showed that ZMA had a great reinforcing effect for the EPDM. It was also found that ZMA reinforced EPDM vulcanizates can retain their mechanical properties under thermo-oxidative aging. Moreover the incorporation of ZMA induces a substantial improvement in the adhesive strength of the EPDM onto aluminum substrate. The reinforcing effect and an enhancement in adhesion was greatly manifested when the ZMA is in-situ formed with an excess amount of ZnO. The extraordinary improvement in the properties is supposed to be related with the formation of ionic crosslink as well as the degree of dispersion or ZMA domain in the rubber matrix.

• Elastomers and Composites
• /
• v.43 no.1
• /
• pp.1-7
• /
• 2008

Far-infrared vulcanization of ethylene-propylene-diene terpolymer(EPDM) compounds has been studied in comparison with hot air vulcanization. Vulcanization characteristics of EPDM compounds were measured by degree of curing and temperature of specimens in vulcanization process. As a result, degree of curing by far-infrared of EPDM compounds was shown to be higher value than that by hot air at the same vulcanization temperature. Especially, degree of curing by far-infrared on 3 mm thickness of EPDM compounds was increased by two times compared to that by hot air. While the increase of thermal conductivity of EPDM compounds highly improved degree of curing by far-infrared, that hardly improved degree of curing by hot air.

• Composites Research
• /
• v.22 no.3
• /
• pp.35-43
• /
• 2009

In this study, for a radiator hose made of carbon black filled EPDM(ethylene-propylene diene monomer) rubber, a measuring method of crosslink density was established to analyze the aging behaviors under thermo-oxidative stresses. At $125^{\circ}C$, the crosslink density of the rubber specimens decreased slightly in the initial stage, but increased with increasing the aging time. Such variation in crosslink density was similar to that of tensile strength. This might be due to the formation of sulphoxide crosslinks as well as to additional crosslinks made by the reaction of unvalcunized sulfurs. A high temperature aging of rubber specimens at $180^{\circ}C$ caused a slight increase in crosslink density while it did a large decrease in tensile strength and elongation. With aging at high temperature, the formation of carbonyl groups in EPDM molecule chain and formation of sulphoxide crosslink, rather than the crosslink density variation itself, had a large influence on such changes in mechanical property.

• Composites Research
• /
• v.19 no.6
• /
• pp.16-22
• /
• 2006

The puncture properties under various conditions were investigated for the optimum conditions to yield the best properties. Fiber aspect ratio(AR: length of fiber/diameter of fiber), interphase condition and fiber content were considered as variables which impact the puncture force and friction force. The puncture force of short-fiber reinforced rubber increases up to 3.4 times compared to the virgin material. The better interphase condition shows the higher puncture force at given fiber AR and fiber content. The friction force of the matrix and reinforced rubber with a fiber AR below 155 does not exist. The friction force of the reinforced rubber with the good interphase condition and high fiber AR is higher than puncture force of matrix. Overall, it was found that the interphase condition, fiber AR and fiber content have an important effect on the puncture properties.

• Composites Research
• /
• v.20 no.6
• /
• pp.28-33
• /
• 2007

The puncture properties of short-fiber reinforced rubber were investigated as functions of fiber aspect ratio(AR: length of fiber/diameter of fiber), fiber content, specimen size and testing velocity. The puncture stresses of the matrix and short-fiber reinforced rubber decreased with specimen size, and increased with testing velocity at same specimen size. As the fiber AR increased the puncture stress at given fiber content also increased. The problem of the specimen shape was investigated by the comparison of the tensile strength with puncture stress. The forces acting in the membrane wall of the matrix and the short-fiber reinforced rubber showed a similar data regardless of specimen size. And those increased with testing velocity at same specimen size. As the fiber AR increased the force acting in the wall at given fiber content also increased. Overall, it was found that the specimen size, testing velocity had an important effects on the puncture properties.

• Steel and Composite Structures
• /
• v.51 no.3
• /
• pp.337-349
• /
• 2024

The growing quantity of tires and building trash piling up in landfills poses a serious threat to the stability of the ecosystem. Researchers are exploring ways to reduce and use such byproducts of the construction industry in an effort to promote greener building practices. Thus, using recycled crumb rubber from scrap tires in concrete manufacturing is important for the industry's long-term viability. This study examines the proportion of waste rubber in fiber form, specifically at weight percentages of 5%, 10%, and 15%. Moreover, the study examines the shear behavior of reinforced concrete beams. A total of twelve RC beam specimens, each sized 100 mm by 150 mm by 1000 mm (w × d × L), were constructed and positioned to the test. Various mixtures were designed with different levels of scrap tire rubber content (0%, 5%, 10%, and 15%) and Stirrup Vol. Ratio (2.10, 2.80, and 3.53) in reinforced concrete beams. The findings indicate that the inclusion of scrap rubber in concrete leads to a decrease in both the mechanical characteristics and weight of the material. This is mostly attributed to the lower strength and stiffness of the rubberized concrete. Furthermore, estimations generated by a variety of design codes were examined alongside the obtained data. In order to make a comparison between the estimates provided by the different codes such as ACI 318-14, CEB-FIB and Iranian national building codes, a calculation was done to determine the ratio of the experimental shear strength to the anticipated shear strength for each code.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.16 no.2
• /
• pp.65-72
• /
• 2012

A defect analysis program for a composite motor case was developed to apply the ultrasonic signal processing method, based on the ultrasonic pulse-echo method. With the proposed defect analysis program, defects of FRP delamination and FRP/Rubber disbond in the composite motor case could be quantitatively measured. The defects detected in the composite motor case were in good agreement with the results measured with the computed tomography and video microscope. This paper described the development process of the defect analysis program to convert the ultrasonic test data into the C-Scan images.