• Title/Summary/Keyword: ROSs

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Copolymerization of 4′-vinylbenzo-15-crown-5 with Di(ethylene glycol) Ethyl Ether Acrylate

  • Jin, Long Yi;Mah, Soukil
    • Fibers and Polymers
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    • v.3 no.2
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    • pp.49-54
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    • 2002
  • Radical copolymerization behavior of 4'-vinylbenzo-15-crown-5, a vinyl monomer having a pendant 15-membared crown ether unit (VCE) with di(ethylene glycol) ethyl ether acrylate (DEGEEA) was carried out in toluene solution using 2,2-azobisisobutyronitrile (AIBN) as an initiator. The copolymers were characterized by means of FT-IR, $^1{H-NMR}$, and $^{13}{C-NMR}$ . The reactivity ratio of VCE and DEGEEA, determined by Fineman-Ross and Kelen-Tudos method, gave values 0.55 for VCE, and 0.11 for DEGEEA respectively.

해양에서 분리한 Arylsulfatase 생산 균주의 특성

  • 서해점;윤재희;한순재;김두상;변대석;김형락
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2001.05a
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    • pp.222-223
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    • 2001
  • Arylsulfatase (EC 3.1.6.1)는 arylsulfate의 황산 ester 결합을 비가역적으로 가수분해하는 효소이다. 이러한 효소는 토양에서 처음 발견된 이래 동식물 및 미생물에서 검출되어졌으며, 주로 토양 중 황화합물의 recycle에 관여하여 토양 환경에 영향을 미치는 요인으로 보고되었다 (Spei. and Ross, 1978). Arylsulfatase에 대한 연구는 주로 토양으로부터 분리된 세균에 국한된 실정이다. (중략)

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Influence of Chronic Low-Level Exposure to Toluene on Cell-Mediated Immunity (만성적인 저 농도 톨루엔 노출이 세포성면역 기능에 미치는 영향)

  • Jang, SeungHee;Choi, Yun-Jung;Kim, Ki-Woong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.3
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    • pp.266-272
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    • 2013
  • Objectives: This study aimed to evaluate the effects of low-level exposure to toluene on T lymphocytes subpopulations.s. Methods: The study lasted from April to October 2010. The subjects were 390 male workers, among whom 137 were chronically exposed to toluene in video-tape manufacturing factories and 253 were controls had never been occupationally exposed to hazardous chemicals. The subpoupulations of CD4+, CD8+, CD16+ (natural killer cells) and total (CD3+) T lymphocytes were examined by two-color staining using monoclonal antibodies. The general and job characteristics of subjects were assessed through a self-administered questionnaire. Results: There was no significant difference in general and job characteristics between both groups. No significant difference in lipid peroxide level was observed between the control and exposed workers, but the concentration of hydrogen peroxide was significantly higher in the exposed workers. The numbers of CD16+ T lymphocytes in controls were significantly higher than those in exposed workers, but no significant differences were found in CD4+, CD8+ and CD3+ T lymphocytes. Hydrogen peroxide levels showed a significantly negative correlation with CD8+ (r = -0.29, p < 0.01), CD16+ (r = -0.56, p < 0.01) and CD3+(r = -0.22. p < 0.01), and toluene levels was significantly negative correlated with CD3+ (r = -0.29, p < 0.05). Conclusions: Our results suggest that chronic low-level exposure to toluene affects cell-mediated immunity and the effects might mediate through ROSs (Reactive Oxygen Species) such as hydrogen peroxide.

Effects of heat stress on growth performance, selected physiological and immunological parameters, caecal microflora, and meat quality in two broiler strains

  • Awad, Elmutaz Atta;Najaa, Muhamad;Zulaikha, Zainool Abidin;Zulkifli, Idrus;Soleimani, Abdoreza Farjam
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.5
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    • pp.778-787
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    • 2020
  • Objective: This study was conducted to investigate the effects of normal and heat stress environments on growth performance and, selected physiological and immunological parameters, caecal microflora and meat quality in Cobb 500 and Ross 308 broilers. Methods: One-hundred-and-twenty male broiler chicks from each strain (one-day-old) were randomly assigned in groups of 10 to 24 battery cages. Ambient temperature on day (d) 1 was set at 32℃ and gradually reduced to 23℃ on d 21. From d 22 to 35, equal numbers of birds from each strain were exposed to a temperature of either 23℃ throughout (normal) or 34℃ for 6 h (heat stress). Results: From d 1 to 21, strain had no effect (p>0.05) on feed intake (FI), body weight gain (BWG), or the feed conversion ratio (FCR). Except for creatine kinase, no strain×temperature interactions were observed for all the parameters measured. Regardless of strain, heat exposure significantly (p<0.05) reduced FI and BWG (d 22 to 35 and 1 to 35), immunoglobulin Y (IgY) and IgM, while increased FCR (d 22 to 35 and 1 to 35) and serum levels of glucose and acute phase proteins (APPs). Regardless of temperature, the Ross 308 birds had significantly (p<0.05) lower IgA and higher finisher and overall BWG compared to Cobb 500. Conclusion: The present study suggests that the detrimental effects of heat stress are consistent across commercial broiler strains because there were no significant strain×temperature interactions for growth performance, serum APPs and immunoglobulin responses, meat quality, and ceacal microflora population.

Biochemical and Histopathological Study of Aflatoxicosis on Ross 308 Broiler Chicks

  • Ko, Myung-Soon;Ahn, Meejung;Shin, Dong-Jin;Son, Youngho
    • Korean Journal of Poultry Science
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    • v.44 no.4
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    • pp.283-290
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    • 2017
  • Totally, one hundred and sixty 1-day-old Ross 308 broiler chicks were fed with a diet containing 0, 0.5, 1.0, and 2.0 mg of aflatoxin $B_1(AFB_1)/kg$ of feed for 21 days. Body weight was lower for the $AFB_1$-treated broilers than for the control group. At 14 and 21 DPF, the broilers fed with 2.0 mg of $AFB_1/kg$ of feed weighed significantly lower than those of the other groups (p<0.05). Relative liver weights increased significantly in a dose-dependent manner, and relative spleen weights were significantly high in the chicks fed with 2.0 mg of $AFB_1/kg$ of feed at 21 DPF (p<0.001). Biochemical analyses showed that total protein and albumin levels decreased significantly at 7 and 14 DPF for the chicks of the group fed with 2.0 of mg $AFB_1/kg$ of feed, compared with those fed with 0.5 and 1.0 mg of $AFB_1/kg$ of feed (p<0.05). AST and ALT levels increased significantly at 14 and 21 DPF (p<0.05), and the AST levels, particularly, increased dose-dependently (p<0.05). Histopathological analyses showed that the liver tissues of the $AFB_1$-treated chicks showed significant lesions, including hemorrhage, hepatocyte necrosis, inflammatory cell infiltration, and fatty degeneration. The severity of both hepatocyte necrosis and inflammatory cell infiltration appeared to increase dose- and time-dependently. Similarly, hepatic fibrosis increased dose-dependently (p<0.05). The results of this study could improve our understanding of parameters used for evaluating aflatoxicosis in poultry.

A Study on Selection and Measures of the Apprehensive Areas of Soil Loss in the So-ok Stream Watershed (소옥천유역 토양유실 우심지역 선정 및 대책에 관한 연구)

  • Jeong, Dong-Hwan;Kim, Haejung;Lee, Young Joon;Hong, Sunhwa;Yoon, Johee;Choi, Heelak;Cho, Hong-Lae
    • Journal of Environmental Impact Assessment
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    • v.21 no.5
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    • pp.617-629
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    • 2012
  • This study aims to find out critical areas of a soil loss and propose feasible measures to reduce the water quality deterioration by a soil lose. As a study area, the So-ok stream catchment locating at the upper area of Daecheong Reservoir is selected and intensive field observation was carried out. RUSLE model is applied to assess the impact of the pollution migration by a soil ross from the critical areas during storms on the water quality of Chusori embayment. As results, total amount of the soil ross assessed against to the critical area on which major type of land use is a orchard for fruits is 54.3 ton/ha/yr and that of an abandoned mine site is about 200 ton/ha/year. In particular as effective measures, a plantation of an appropriate species of fruit trees and an application of ecologic restoration schemes are proposed against to the orchard and the abandoned mine site, respectively.

Preparation and Behavior of High Performance Alkaline Cleaning Agents for Steel (철강용 고성능 알칼리세정제의 제조 및 세정거동)

  • Park, Hong-Soo;Jo, Hye-Jin;Shim, Il-Woo;You, Hyuk-Jae;Kim, Myung-Soo;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.1
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    • pp.15-20
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    • 2005
  • $Na_2CO_3$. Sodium orthosilicate (Na-OSi), Tetronix T-701 (T-701), Na-dioctyl sulfosuccinate (303C), Newpol PE-68 (PE-68), MJU-100A, and tetrasodium pyrophosphate were blended to prepare high performance alkaline cleaning agents (ACASs). The results of cleaning test with steel specimen showed that ACAS-6 ($Na_2CO_3$ 50g/Na-OSi 35g/T-701 20g/303C 18g/PE-68 17g/MJU-100A 10g/TSPP 20g/ water 180g mixture) had a good cleaning power. The cleaning power for press-rust preventing oil was 98% and 99% degreasing at 4wt%, $70^{\circ}C$ and $90^{\circ}C$, respectively ; for quenching oil, the cleaning power of ACAS-6 was 91% degreasing at 4wt% and $70^{\circ}C$. The foam heights measured immediately after foaming by Ross & Miles method and Ross & Clark method at 6wt%, $60^{\circ}C$ were 18mm and 65mm, respectively. It was concluded that ACAS-6 had a good low foaming cleaning agent.

Synthesis and Monomer Reactivity Ratio of PNIPAAM-PMMA Random Copolymer (PNIPAAM-PMMA Random Copolymer의 합성 및 단량체 반응성비 측정)

  • 이창배;조창기
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.168-173
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    • 2000
  • Radical copolymerization of N-isopropylacrylamide (NIPAAM) with methyl methacrylate (MMA) was carried out in 1,4-dioxane using 2,2'-azobisisobutyronitrile (AIBN). To investigate the reactivity ratios of NIPAAM and MMA at different reaction temperatures, the copolymerization was allowed to proceed to low conversion (less than 10 wt%), and the reaction temperatures were 50, 60, and 7$0^{\circ}C$. The monomer reactivity ratios of NIPAAM and MMA were estimated by the graphical methods according to the Finemann-Ross equation. The ${\gamma}$$_1$ and ${\gamma}$$_2$ values for NIPAAM-MMA were 0.259 and 2.782 at 5$0^{\circ}C$, 0.271 and 2.819 at 6$0^{\circ}C$, and 0.286 and 2.915 at 7$0^{\circ}C$, respectively. As the reaction temperature increased, the ${\gamma}$$_1$ and ${\gamma}$$_2$ values increased. The activation energy difference was estimated by comparing the reactivity ratios at different reaction temperatures.

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The Kinetics of Solution Copolymerization of styrene and n-Butylmethacrylate in a Continuous Stirred Tank Reactor(CSTR) (연속반응기에서 Styrene과 n-Butylmethacrylate의 용액 공중합의 속도론)

  • Kim, Nam Seok;Seul, Soo Duk
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.347-356
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    • 1997
  • Solution copolymerization of Styrene(St) and n-Butylmethacrylate(BMA) was carried out with Benzoylperoxide (BPO) as an initiator in toluene at $80^{\circ}C$ in a continuous stirred tank reactor. Reaction volume and residence time were 0.6 liters, 3 hours respectively. The monomer reactivity ratios, $r_1$(St) and $r_2$(BMA) were determined by both the Kelen-Tlidos method and the Fineman-Ross method ; $r_1$=0.75(0.67), $r_2$=0.61(0.56). The cross-termination factor, $\phi$ factor of the copolymer over the entire St compositions ranged from 0.44 to 0.78. The $\phi$ factors of St-BMA copolymer increased with increasing St compositions. Our present system showed that the continuous copolymerization of St with BMA followed second-order kinetic behavior. The simulated conversions and copolymerization rates were compared with the experimental results. The average time to reach dynamic steady-state was three times and half of the residence time.

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Comparison of Quality Traits of Thigh Meat from Korean Native Chickens and Broilers

  • Jung, Yeon-Kuk;Jeon, Hee-Jun;Jung, Samooel;Choe, Jun-Ho;Lee, Jun-Heon;Heo, Kang-Nyeong;Kang, Bo-Seok;Jo, Cheo-Run
    • Food Science of Animal Resources
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    • v.31 no.5
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    • pp.684-692
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    • 2011
  • The quality attributes of thigh meat from a certified meat-type commercial Korean native chicken (WoorimatdagTM, WM) and a commercial broiler (Ross, CB) raised under the same environmental conditions, were compared. One-d-old, mixedsex WM (200), and 200 broilers (Ross, CB) each were randomly assigned to floor pens (20 chickens per pen). The production stages (I, II, and III) were selected based on similar live weight. The crude fat contents of WM thigh meat were lower than those of CB. WM thigh meat contained higher stearic and arachidonic acid contents but lower palmitoleic and oleic acid contents compared to those of CB. The thigh meat color CIE $L^*$- and CIE $b^*$-values of WM were lower, but inosine-5'-monophosphate content was higher in WM than CB in whole production stages. WM thigh meat showed higher collagen content, hardness, springiness, gumminess, and chewiness than CB. In sensory evaluation, odor, taste, and overall acceptance were higher while color was lower in WM. Based on these results, it can be concluded that even if commercial broilers are raised under the same environmental conditions as WM, the unique quality attributes of WM thigh meat are distinctively unique.